高性能邻苯二甲腈树脂分子结构调控研究进展

doi:10.11896/cldb.23030102

材料导报

2023, Vol. 37

Issue (S1): 23030102-10 https://doi.org/10.11896/cldb.23030102

高分子与聚合物基复合材料

高性能邻苯二甲腈树脂分子结构调控研究进展

吉贝贝, 吴楠^*, 刘姣, 廖维, 吕家杰, 尹昌平, 邢素丽

国防科技大学空天科学学院,长沙 410073

Research Progress in Molecular Structure Regulation of High-performance Phthalonitrile Resin

JI Beibei, WU Nan^*, LIU Jiao, LIAO Wei, LYU Jiajie, YIN Changping, XING Suli

College of Aerospace Science and Engineering, National University of Defense Technology, Changsha 410073, China

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摘要邻苯二甲腈树脂是以邻苯二甲腈结构封端的一类热固性树脂的统称,固化后形成的芳杂环体型网络结构赋予邻苯二甲腈树脂优异的热稳定性、耐化学腐蚀性、阻燃性、低介电常数等,其在航空航天、船舶和电子封装等领域具有广阔的应用前景。然而,苛刻的成型工艺制约着邻苯二甲腈树脂的发展和应用。因此,在邻苯二甲腈树脂的工艺改善、性能提升和功能开发上存在着诸多机遇和挑战。本文综述了近几年国内外对邻苯二甲腈树脂分子结构调控和高性能固化剂设计的相关研究报道,探讨了分子结构对邻苯二甲腈树脂加工性、耐热性和介电性能的影响,并对该材料的研究进展和发展趋势进行总结与展望。

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关键词: 邻苯二甲腈树脂分子结构耐高温高性能固化剂

Abstract: Phthalonitrile resin is a thermosetting resin that exhibits exceptional thermal stability, chemical corrosion resistance, flame retardancy, and low dielectric constant due to its aromatic heterocyclic network structure formed after curing. The resin holds significant potential in various industries such as aerospace, shipbuilding, and electronic packaging. Therefore, there are many opportunities and challenges in the process improvement, performance enhancements, and functional development of phthalonitrile resin. However, the rigorous molding process of phthalonitrile resin poses challenges for its development and application. This paper provides a comprehensive review of recent research reports on molecular structure regulation and the design of high-performance curing agents for phthalonitrile resin, both domestically and internationally. The influence of the molecular structure on the processability, heat resistance, and dielectric properties of phthalonitrile resin was discussed. Moreover, this review summarizes the current research progress and future development trends of phthalonitrile resin.

Key words: phthalonitrile resin molecular structure high-temperature resistance high-performance curing agent

发布日期: 2023-09-06

ZTFLH:

TB323

基金资助: 国防科技大学自主创新科学基金(2022-076;23-22CX-22GC-01-10)

通讯作者: *吴楠,国防科技大学空天科学学院副教授、硕士研究生导师。2018年6月获国防科技大学材料科学与工程专业博士学位。主要从事极端服役环境树脂基复合材料、功能复合材料等方面的研究工作。获授权国家发明专利13项,发表论文30余篇,入选中国科协青年人才托举工程。lierenwn@nudt.edu.cn

作者简介: 吉贝贝,2017年6月获河南工业大学工学学士学位。现为国防科技大学空天科学学院硕士研究生,主要研究领域为耐高温树脂基体。

引用本文:

吉贝贝, 吴楠, 刘姣, 廖维, 吕家杰, 尹昌平, 邢素丽. 高性能邻苯二甲腈树脂分子结构调控研究进展[J]. 材料导报, 2023, 37(S1): 23030102-10.
JI Beibei, WU Nan, LIU Jiao, LIAO Wei, LYU Jiajie, YIN Changping, XING Suli. Research Progress in Molecular Structure Regulation of High-performance Phthalonitrile Resin. Materials Reports, 2023, 37(S1): 23030102-10.

链接本文:

http://www.mater-rep.com/CN/10.11896/cldb.23030102 或 http://www.mater-rep.com/CN/Y2023/V37/IS1/23030102

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