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材料导报  2022, Vol. 36 Issue (14): 20110066-9    https://doi.org/10.11896/cldb.20110066
  无机非金属及其复合材料 |
非钙基土壤固化剂加固机理及其应用性能研究进展
钟玉健1,2, 张晓超1,2, 袁锐1,2, 吴学敏1, 陈林万1
1 成都理工大学地质灾害防治与地质环境保护国家重点实验室,成都 610059
2 成都理工大学国家环境保护水土污染协同控制与联合修复重点实验室,成都 610059
Research Progress in the Stabilization Mechanism of Non-calcium-based Soil Stabilizer and Its Application Performance
ZHONG Yujian1,2, ZHANG Xiaochao1,2, YUAN Rui1,2, WU Xuemin1, CHEN Linwan1
1 State Key Laboratory of Geohazard Prevention and Geoenvironment Protection, Chengdu University of Technology, Chengdu 610059, China
2 State Environmental Protection Key Laboratory of Synergetic Control and Joint Remediation for Soil & Water Pollution, Chengdu University of Technology, Chengdu 610059,China
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摘要 土地退化是危及人类生存与发展的重大问题,对土壤进行加固处理一直是国内外学者的研究热点。通过强夯、纤维加筋、土工格构等物理加固措施可以实现土体加固。然而,与物理加固相比,利用土壤固化剂对土壤进行化学加固具有强度高、成本低、污染小等优点,受到了众多研究者的关注。土壤固化剂可分为钙基固化剂和非钙基固化剂:传统的钙基固化剂(水泥、粉煤灰、石灰等)存在污染大、凝结时间长、破坏土壤功能等缺点,多用于道路、建筑等领域;而应用于荒漠化治理、边坡修复、水土保持等领域的土壤固化剂,除了要具有良好的固化性能以外,还需具备较好的生态性能,因此非钙基固化剂是这些应用领域的首要选择。
按照化学成分,非钙基固化剂可分为聚合物类固化剂、生物酶类固化剂和离子类固化剂。各类固化剂的固化机理不同:聚合物类固化剂主要通过凝胶吸附、包裹、填充作用对土壤进行加固;生物酶类固化剂主要通过酶催化土壤颗粒表面阳离子与土壤有机质的离子交换反应进行加固;而离子类固化剂则是通过加速离子交换反应速率,降低土壤颗粒亲水性,以实现土壤加固。非钙基固化剂的应用性能分为工程性能和生态性能两个方面:工程性能主要体现为改善土壤的力学性质、提高土壤的抗侵蚀能力和抗变形能力;而生态性能主要体现在提高土壤的保水能力和间接促进植物生长的能力。
本文总结了非钙基固化剂的研究进展,分类介绍了非钙基固化剂的固化机理,总结了非钙基固化剂的工程性能与生态性能的应用研究,并对非钙基固化剂未来的发展方向进行了展望。
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钟玉健
张晓超
袁锐
吴学敏
陈林万
关键词:  非钙基土壤固化剂  加固机理  工程性能  生态性能    
Abstract: Land degradation is a major problem threatening human survival and development. Soil stabilization has been hotspots for scholars at home and abroad. Physical stabilization measures such as dynamic compaction, fiber stabilization and geotextile can reinforce the soil. However, compared with physical stabilization measures, the chemical stabilization of soil with soil stabilizer has the advantages of high strength, low cost and low pollution, which has attracted the attention of many researchers. Soil stabilizers are divided into calcium-based soil stabilizers and non-calcium-based soil stabilizers. Traditional calcium-based stabilizers (such as cement, fly ash, and lime) have the disadvantages of serious pollution, long curing time and damage to soil functions, which are mostly used in roads and construction fields. Non-calcium-based soil stabilizers are the best choice in the application fields of desertification control, slope restoration, soil and water conservation and others, required to not only have excellent solidification performance, but also have good ecological properties.
Non-calcium-based stabilizers can be divided into polymer stabilizers, biological enzyme stabilizers and ionic stabilizers, according to the chemical composition. The curing mechanisms of various stabilizers are different. The polymer stabilizers mainly strengthen the soil through gel adsorption, wrapping and filling. The biological enzyme stabilizers mainly reinforce the soil by enzyme-catalyzed ion exchange reaction between cations on the surface of soil particles and soil organic matter. The ionic stabilizers accelerate the ion exchange reaction rate and reduce the hydrophilicity of soil particles to achieve soil stabilization. The application performance of non-calcium-based stabilizers is divided into engineering performance and ecological performance. The engineering performance is reflected in improving the mechanical properties of soil and strengthening the anti-erosion ability and anti-deformation ability of soil, while the ecological performance is mainly manifested in improving soil water holding capacity and indirectly promoting plant growth.
In this paper, the research progress of non-calcium-based stabilizers is summarized. The curing mechanisms of non-calcium-based stabilizers are introduced. The engineering and ecological performance of non-calcium-based stabilizers is combed. In addition, the future development of non-calcium-based stabilizers is also prospected.
Key words:  non-calcium-based soil stabilizer    stabilization mechanism    engineering property    ecological property
发布日期:  2022-07-26
ZTFLH:  P642.16  
  TU44  
基金资助: 国家自然科学基金重大专项(41790445);国家重点研发项目(2018YFC1504702)
通讯作者:  31685032@qq.com   
作者简介:  钟玉健,2019年6月毕业于成都理工大学,获得工学学士学位。现为成都理工大学生态环境学院硕士研究生,在张晓超副教授的指导下进行研究。目前主要研究领域为边坡水土保持与生态环境修复。
张晓超,成都理工大学生态环境学院副教授、硕士研究生导师。2001年7月毕业于西北农林科技大学,获得工学学士学位;2015年6月毕业于成都理工大学地质资源与地质工程专业,获得博士学位。承担国家级、省部级及其他项目20余项,主要从事地质灾害防治与生态环境修复、水-土-植互馈作用机制及其孕灾机理方向的研究工作。近年来在国内外重要期刊发表学术论文20余篇。
引用本文:    
钟玉健, 张晓超, 袁锐, 吴学敏, 陈林万. 非钙基土壤固化剂加固机理及其应用性能研究进展[J]. 材料导报, 2022, 36(14): 20110066-9.
ZHONG Yujian, ZHANG Xiaochao, YUAN Rui, WU Xuemin, CHEN Linwan. Research Progress in the Stabilization Mechanism of Non-calcium-based Soil Stabilizer and Its Application Performance. Materials Reports, 2022, 36(14): 20110066-9.
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http://www.mater-rep.com/CN/10.11896/cldb.20110066  或          http://www.mater-rep.com/CN/Y2022/V36/I14/20110066
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