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材料导报  2022, Vol. 36 Issue (20): 21020082-7    https://doi.org/10.11896/cldb.21020082
  高分子与聚合物基复合材料 |
双马来酰亚胺树脂增韧改性研究进展
赵立伟, 杨海冬, 王德志*, 曲春艳, 冯浩, 李洪峰, 肖万宝
黑龙江省科学院石油化学研究院,哈尔滨 150040
Research Progress in Toughness Modification of Bismaleimide Resin
ZHAO Liwei, YANG Haidong, WANG Dezhi*, QU Chunyan, FENG Hao, LI Hongfeng, XIAO Wanbao
Institute of Petrochemistry Heilongjiang Academy of Sciences, Harbin 150040, China
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摘要 双马来酰亚胺(BMI)树脂以其优异的耐高温性能而被广泛应用于航空航天等领域,尤其是BMI树脂基复合材料和BMI结构胶黏剂制造领域。未经增韧改性的BMI树脂存在熔点高、溶解性差、固化物脆性大等缺点,特别是脆性大这一缺点严重限制了BMI树脂的应用,因此在使用之前需要对BMI进行增韧改性。本文从内增韧改性、外增韧改性以及协同增韧改性三个主要方面综述了BMI树脂增韧改性的研究进展。其中,内增韧改性方法包括采用扩链剂对BMI进行扩链增韧改性、在BMI分子结构中引入柔性基团进行分子内增韧改性以及采用烯丙基化合物和丙烯基化合物对BMI进行共聚合增韧改性等;外增韧改性方法主要是通过在BMI树脂中引入增韧剂来达到增韧效果,增韧剂包括橡胶弹性体、无机功能材料、热塑性树脂及热固性树脂等;协同增韧改性是利用多种增韧方法产生的协同效应来达到BMI强增韧目的。本文最后对BMI树脂增韧改性研究方向进行了展望。
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赵立伟
杨海冬
王德志
曲春艳
冯浩
李洪峰
肖万宝
关键词:  双马来酰亚胺  增韧改性  耐高温  复合材料    
Abstract: Bismaleimide (BMI) resin is widely used in the aerospace field owing to its excellent high-temperature resistance, especially in the BMI resin-based composite materials and BMI structural adhesive manufacturing fields. However, BMI resins without toughening modification have shortcomings of high melting point, poor solubility and high brittleness in cured products. For example, high brittleness severely limits the BMI resin application. Therefore, it is necessary to toughen and modify BMI before use. This paper reviews the research progress of toughening modification of BMI resin from three main aspects: internal toughening, external toughening and synergistic toughening modifications. The internal toughening modification methods include using chain extenders for chain extension and toughening modification of BMI, introducing flexible groups into BMI molecular structure for intramolecular toughening modification, and using allyl and propenyl compounds for BMI toughening modification through copolymerization. The external toughening modification method mainly achieves the toughening effect by introducing a toughening agent into the BMI resin. The external toughening agent includes rubber elastomers, inorganic functional materials, thermoplastic resins and thermosetting resins. The synergistic toughening modification utilizes the synergistic effect of various toughening methods to strengthen and toughen BMI. The paper ends with a brief discussion about the future research trends of this field.
Key words:  bismaleimide    toughening modification    high-temperature resistance    composites
发布日期:  2022-10-26
ZTFLH:  TB332  
基金资助: 黑龙江省杰出青年科学基金(JC2017015);黑龙江省自然科学基金(TD2020E003);国家自然科学基金(21875054);黑龙江省科学院预研基金(YY2021SH01)
通讯作者:  *jim603@163.com   
作者简介:  赵立伟,工学博士,黑龙江省科学院石油化学研究院助理研究员,2019年7月博士毕业于哈尔滨工业大学,2019年9月进入哈尔滨工程大学/黑龙江省科学院石油化学研究院联合博士后工作站开展博士后研究工作,主要从事功能高分子材料、高性能结构胶黏剂以及复合材料粘接理论研究。主持黑龙江省博士后面上基金、中国博士后科学基金及国防基础科研项目等,已发表SCI收录学术论文13篇,授权中国发明专利3项。
王德志,工学博士,黑龙江省科学院石油化学研究院研究员,硕士研究生导师,享受国务院特殊津贴专家,黑龙江省杰出青年科学基金获得者,黑龙江省级领军人才梯队后备带头人,北京粘接学会理事。1997年7月毕业于黑龙江大学化学化工学院,获学士学位,同年到黑龙江省科学院石油化学研究院参加工作至今;其间于2013年12月毕业于哈尔滨理工大学材料科学与工程学院,获硕士学位,2018年6月毕业于哈尔滨理工大学材料科学与工程学院,获工学博士学位。现任黑龙江省科学院石油化学研究院结构与耐热材料研究中心主任,主要从事高温结构胶黏剂、橡胶金属胶黏剂和复合材料预浸料研究。主持和参加国家级、省部级科研项目20余项,发表学术论文60余篇,其中SCI、EI收录论文22篇;获得中国发明专利22项;科研成果广泛应用于航空航天、轨道交通和大型舰船等高技术领域。
引用本文:    
赵立伟, 杨海冬, 王德志, 曲春艳, 冯浩, 李洪峰, 肖万宝. 双马来酰亚胺树脂增韧改性研究进展[J]. 材料导报, 2022, 36(20): 21020082-7.
ZHAO Liwei, YANG Haidong, WANG Dezhi, QU Chunyan, FENG Hao, LI Hongfeng, XIAO Wanbao. Research Progress in Toughness Modification of Bismaleimide Resin. Materials Reports, 2022, 36(20): 21020082-7.
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http://www.mater-rep.com/CN/10.11896/cldb.21020082  或          http://www.mater-rep.com/CN/Y2022/V36/I20/21020082
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