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材料导报  2023, Vol. 37 Issue (24): 22030010-12    https://doi.org/10.11896/cldb.22030010
  无机非金属及其复合材料 |
两电子氧还原电催化合成过氧化氢的研究进展
徐文杰, 刘丹*, 屈德宇, 李曦*
武汉理工大学化学化工与生命科学学院,武汉 430070
Research Progress on Electrocatalytic Synthesis of Hydrogen Peroxide by Two-electron Oxygen Reduction
XU Wenjie, LIU Dan*, QU Deyu, LI Xi*
School of Chemistry, Chemical Engineering and Life Science, Wuhan University of Technology, Wuhan 430070, China
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摘要 过氧化氢(H2O2)是一种环境友好的通用氧化剂,被广泛应用于化学合成、废水处理以及纸浆和纺织品漂白等领域。当前工业大量合成H2O2主要采用蒽醌法,该方法能耗高,工艺步骤多,三废排放大且产物储运过程中存在安全隐患。利用电催化剂将氧气在阴极侧进行两电子氧还原反应(2e-ORR)可实现按需现场合成H2O2,是近年来广受关注的一种方法。电催化剂的活性、选择性和稳定性直接决定了2e-ORR的反应效率。本文简要介绍了2e-ORR机理及催化剂性能评价方法,主要综述了用于2e-ORR合成H2O2的贵金属基和碳基催化剂在结构优化、组成掺杂、活性位点调控和表/界面设计等方面的重要研究进展,在此基础上就电催化合成H2O2存在的挑战和未来需要解决的关键问题进行了展望。
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徐文杰
刘丹
屈德宇
李曦
关键词:  过氧化氢  氧还原反应  电催化合成  催化剂    
Abstract: Hydrogen peroxide (H2O2) is a versatile and environmental-friendly oxidant, which is widely used in chemical synthesis, wastewater treatment, and pulp/textile bleaching. Current industrial manufacturing of H2O2 is mainly based on an anthraquinone method, which has disadvantages such as high energy consumption, tedious process, and potential safety concern for its storage and transportation. Electrocatalytic H2O2 production through two-electron oxygen reduction reaction (2e-ORR) has recently emerged as an intriguing alternative, enabling on-site H2O2 generation according to practical demands. The efficiency of 2e-ORR directly depends on electrocatalysts’ activity, selectivity, and stability. This review would briefly introduce the ORR mechanism and performance evaluation methods of 2e-ORR catalysts. Then, an overview of the recent advance in precious metal and carbon-based electrocatalysts for 2e-ORR is provided, emphasizing structure optimization, compositional doping, active site regulation, and surface/interface design of these catalysts. Furthermore, the present challenges and critical issues to be solved in the future are prospected to guide further development toward the electrocatalytic synthesis of H2O2.
Key words:  hydrogen peroxide    oxygen reduction reaction    electrocatalytic synthesis    catalyst
发布日期:  2023-12-19
ZTFLH:  O646  
基金资助: 国家自然科学基金(21401145)
通讯作者:  *刘丹,武汉理工大学化学化工与生命科学学院副教授、硕士研究生导师。2002年本科毕业于武汉理工大学化学系,2011年获武汉理工大学材料物理与化学博士学位。主要从事多孔材料、碳材料的合成方法学研究以及超级电容器、碱金属离子电池、锂硫电池、固态电池等储能器件及材料的研究,在Nano Energy、J. Mater. Chem. A、ACS Appl. Mater. Interfaces、J. Power Source、Carbon、J. Phys. Chem. C等期刊发表SCI研究论文80余篇。
李曦,武汉理工大学化学化工与生命科学学院副教授、硕士研究生导师。1989年本科毕业于武汉大学化学系,1992年获武汉大学材料物理与化学博士学位。主要从事电化学、功能高分子材料的研究,主持和参加了国家自然科学基金、973、科技部重大专项子课题、湖北省自然科学基金及武汉市晨光计划等多项科研项目;已发表科研论文100余篇,其中SCI收录90余篇;获湖北省科技进步一等奖和二等奖各1项。daniellliu@whut.edu.cn;chemlixi@whut.edu.cn   
作者简介:  徐文杰,2019年6月毕业于武汉理工大学,获得理学学士学位。现为武汉理工大学化学化工与生命科学学院硕士研究生,在刘丹副教授的指导下进行研究。目前主要研究领域为电催化氧还原。
引用本文:    
徐文杰, 刘丹, 屈德宇, 李曦. 两电子氧还原电催化合成过氧化氢的研究进展[J]. 材料导报, 2023, 37(24): 22030010-12.
XU Wenjie, LIU Dan, QU Deyu, LI Xi. Research Progress on Electrocatalytic Synthesis of Hydrogen Peroxide by Two-electron Oxygen Reduction. Materials Reports, 2023, 37(24): 22030010-12.
链接本文:  
http://www.mater-rep.com/CN/10.11896/cldb.22030010  或          http://www.mater-rep.com/CN/Y2023/V37/I24/22030010
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