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材料导报  2023, Vol. 37 Issue (S1): 22080121-11    https://doi.org/10.11896/cldb.22080121
  无机非金属及其复合材料 |
硼/磷掺杂电解水析氢金属催化剂的研究现状与进展
庄明兴1,2,†, 卡盖·索音图1,†, 付文英1,2, 司司1, 余添玉1, 杨俊东1, 章剑1, 梁宇欣1, 赵新生1, 魏永生1,*
1 江苏师范大学物理与电子工程学院,江苏 徐州 221116
2 徐州徐工新能源汽车有限公司,江苏 徐州 221116
Progress of Metal Catalysts Doping with Boron, Phosphorus Elements for Hydrogen Evolution Reaction in Water Electrolysis
ZHUANG Mingxing1,2,†, KA GAI·Suoyintu1,†, FU Wenying1,2, SI Si1, YU Tianyu1, YANG Jundong1, ZHANG Jian1, LIANG Yuxin1, ZHAO Xinsheng1, WEI Yongsheng1,*
1 School of Physics and Electronic Engineering, Jiangsu Normal University, Xuzhou 221116, Jiangsu, China
2 Xuzhou XCMG New Energy Vehicle Co.,Ltd., Xuzhou 221116, Jiangsu,China
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摘要 氢能是一种绿色低碳、高能量利用率的二次能源,是国家实现“双碳”战略的重要技术途径之一。目前电解水制氢研究广泛,贵金属催化剂催化活性高,但是由于储量稀少、价格昂贵,无法大规模推广应用。因此,开发低成本催化剂迫在眉睫。本文综述了金属催化剂、硼元素掺杂催化剂、磷元素掺杂催化剂和硼/磷元素共掺杂催化剂用于电解水析氢的研究进展。在金属催化剂中掺杂B可以增加电子缺陷、提高催化剂电化学表面积和降低反应电阻来提高析氢性能;掺杂P有利于水解离、中间体Hads的形成,有效改善催化剂的析氢催化反应动力学;而B/P共掺杂催化剂中B、P元素间及其与金属之间的协同效应进一步提高了催化活性。本文还分析了B掺杂催化剂、P掺杂催化剂和B/P共掺杂催化剂电解水析氢的催化反应机理,对硼/磷元素掺杂催化剂在电解水析氢上的应用前景和发展趋势进行了讨论。
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庄明兴
卡盖·索音图
付文英
司司
余添玉
杨俊东
章剑
梁宇欣
赵新生
魏永生
关键词:  电解水  析氢反应  电催化剂  B/P共掺杂催化剂    
Abstract: Hydrogenhas higher energy density with low-carbon, and is regarded as one of green energy technology for China ‘Double Carbon' plan. Hydrogen production by water electrolysis is called Green Hydrogen, which is an important hydrogen source for fuel cells. At present, precious metal catalyst is mainly used in hydrogen evolution reaction. Its high price has prevented the large-scale application of electrolytic water. Therefore, it is extremely urgent to develop low-cost catalysts. In this paper, non-precious metal catalysts, B doped catalysts, P doped catalysts and B/P co-doped catalysts for the hydrogen evolution are reviewed. The main role of B element doping in metal catalysts can increase the electron defects, the electrochemical surface area, and decrease the reaction resistance to improve the catalytic activity of hydrogen evolution. Doping P element facilitates the formation of intermediate Hads, and effectively improves the catalytic kinetics of the hydrogen evolution. B/P co-doped catalysts show better catalytic activity even than B doping and P doping non-noble metal catalysts due to the synergistic effect between them and mental catalyst. The reaction mechanism of B doping and P doping non-noble metal catalysts are discussed. Finally, the prospect of B/P co-doped catalysts for the hydrogen evolution is looked forward.
Key words:  water electrolysis    HER    electrocatalysts    B/P co-doped catalysts
发布日期:  2023-09-06
ZTFLH:  TK91  
基金资助: 国家自然科学基金(21606115);江苏省科技计划项目(BE2020759);江苏省高校基础科学(自然科学)研究项目(23KJA480001);徐州市科技计划项目(KC20195);江苏师范大学研究生科研与实践创新计划项目(2021XKT1225;2022XKT1324)
通讯作者:  *魏永生,江苏师范大学物理与电子工程学院副教授、硕士研究生导师。2006年7月本科毕业于中国矿业大学,2011年7月在北京交通大学取得博士学位,2008—2009年在美国迈阿密大学进行博士联合培养。2013年北京化工大学博士后出站。主要从事氢燃料电池、电解水制氢催化剂、电化学还原制备硼氢化钠的研究工作。先后主持国家自然科学基金青年项目、江苏省自然科学基金青年项目等科研课题,参与国家863项目、国际合作项目、国家自然科学基金面上项目等项目。迄今在ACS Applied Materials & Interface、Journal of Power Sources、International Journal of Hydrogen Energy等国内外学术期刊发表论文80余篇,他引1 000余次。weiys@jsnu.edu.cn   
作者简介:  庄明兴,中级工程师,徐州徐工新能源汽车有限公司技术总监、江苏师范大学储制氢技术研究企业专家顾问。2008年7月本科毕业于山东交通学院车辆工程专业,2016年12月在长安大学取得硕士学位,从事新能源汽车行业十四年,主要从事氢燃料汽车、纯电动汽车的研究工作。先后主持开发新能源客车、新能源重卡六十多款,国家专利二十多项,参与省科技厅项目、国际合作等项目。
卡盖·索音图,2017年 6月毕业于西南民族大学,获得理学学士学位。现为江苏师范大学物理与电子工程学院硕士研究生,在魏永生副教授的指导下进行研究。目前主要研究领域为电解水制氢催化剂。
†共同第一作者
引用本文:    
庄明兴, 卡盖·索音图, 付文英, 司司, 余添玉, 杨俊东, 章剑, 梁宇欣, 赵新生, 魏永生. 硼/磷掺杂电解水析氢金属催化剂的研究现状与进展[J]. 材料导报, 2023, 37(S1): 22080121-11.
ZHUANG Mingxing, KA GAI·Suoyintu, FU Wenying, SI Si, YU Tianyu, YANG Jundong, ZHANG Jian, LIANG Yuxin, ZHAO Xinsheng, WEI Yongsheng. Progress of Metal Catalysts Doping with Boron, Phosphorus Elements for Hydrogen Evolution Reaction in Water Electrolysis. Materials Reports, 2023, 37(S1): 22080121-11.
链接本文:  
http://www.mater-rep.com/CN/10.11896/cldb.22080121  或          http://www.mater-rep.com/CN/Y2023/V37/IS1/22080121
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