锰基低温NH3-SCR催化剂脱除NOx的研究综述

doi:10.11896/cldb.22010173

材料导报

2023, Vol. 37

Issue (22): 22010173-13 https://doi.org/10.11896/cldb.22010173

无机非金属及其复合材料

锰基低温NH₃-SCR催化剂脱除NO_x的研究综述

梁李斯^1,†,*, 马洪月^1,†, 郭文龙¹, 张宇², 弥晗², 张自恒³, 邢相栋³

1 西安建筑科技大学冶金工程学院,西安 710055
2 陕西省黄金与资源重点实验室,西安 710055
3 陕西省冶金工程技术研究中心,西安 710055

A Review of Manganese Based Low Temperature NH₃-SCR Catalysts for NO_x Removal

LIANG Lisi^1,†,*, MA Hongyue^1,†, GUO Wenlong¹, ZHANG Yu², MI Han², ZHANG Ziheng³, XING Xiangdong³

1 School of Metallurgical Engineering, Xi’an University of Architecture and Technology, Xi’an 710055, China
2 Shaanxi Provincial Key Laboratory of Gold and Resources, Xi’an 710055, China
3 Shaanxi Metallurgical Engineering Technology Research Center, XI’an 710055, China

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摘要目前工业上使用的氨选择性催化还原(NH₃-SCR)脱硝催化剂存在一定的缺陷,如易中毒、稳定性差、反应温度高等,在使用中受到限制。因此,开发低温高效、稳定性好、抗中毒性好的催化剂成为当前的研究热点,锰基催化剂具有较高的催化活性,在脱硝领域有广阔的应用前景,研究者们对此进行了大量研究。本文基于锰基低温氨选择性催化剂去除氮氧化物的最新研究进展,介绍了从催化剂添加助剂、制备方法、载体以及催化剂形貌结构等因素对锰基催化剂NH₃-SCR脱硝性能的影响,深入分析了锰基催化剂脱硝的反应机理(包括Eley-Rideal和Langmuir-Hinshelwood机理)以及催化剂中毒机理,并指出研发低温NH₃-SCR脱硝效果好、抗中毒性能好的锰基催化剂是未来的主要研究方向。

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	梁李斯
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	邢相栋

关键词: SCR 催化剂脱硝低温反应机理

Abstract: Due to the NH₃-SCR (ammonia selective catalytic reduction) denitrification catalysts currently used in industry have certain defects, such as easy poisoning, poor stability and high reaction temperature, they are restricted in use. Therefore, the development of catalysts with high efficiency at low temperature, good stability and good resistance to neutrality has become a current research hotspot. Manganese-based catalysts have high catalytic activity and have broad application prospects in the denitrification field, and researchers have conducted a lot of research on them. In this paper, based on the latest research progress of manganese-based low-temperature ammonia selective catalysts for NO_x removal, the effects of catalyst additive, preparation method, carrier and catalyst morphology structure on the denitrification performance of manganese-based catalysts for NH₃-SCR are introduced. The reaction mechanism (including Eley-Rideal and Langmuir-Hinshelwood mechanisms) and catalyst poisoning mechanism, and pointed out that the development of manganese-based catalysts with good denitrification effect and poisoning resistance for low-temperature NH₃-SCR is the main research direction in the future.

Key words: SCR catalyst denitrification low temperature reaction mechanism

出版日期: 2023-11-25 发布日期: 2023-11-21

ZTFLH:	X51
	TQ426

基金资助: 陕西省教育厅重点实验室项目(Z202 00151)

通讯作者: * 梁李斯,西安建筑科技大学冶金工程学院副教授、硕士研究生导师。2006年毕业于东北师范大学环境科学专业,获学士学位。2008年毕业于东北大学有色金属专业,获硕士学位。2011年东北大学有色金属专业博士毕业。研究方向为有色金属冶金、冶金节能环保与资源综合利用、泡沫金属与吸声材料。发表论文30余篇,出版专著1部,获得专利7项。

作者简介: †共同第一作者
马洪月,2019年7月毕业于西安建筑科技大学环境科学专业,获得学士学位。现为西安建筑科技大学冶金工程学院硕士研究生,在梁李斯副教授的指导下进行研究。目前主要研究方向为烟气中氮氧化物的处理。44406200@qq.com

引用本文:

梁李斯, 马洪月, 郭文龙, 张宇, 弥晗, 张自恒, 邢相栋. 锰基低温NH₃-SCR催化剂脱除NO_x的研究综述[J]. 材料导报, 2023, 37(22): 22010173-13.
LIANG Lisi, MA Hongyue, GUO Wenlong, ZHANG Yu, MI Han, ZHANG Ziheng, XING Xiangdong. A Review of Manganese Based Low Temperature NH₃-SCR Catalysts for NO_x Removal. Materials Reports, 2023, 37(22): 22010173-13.

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http://www.mater-rep.com/CN/10.11896/cldb.22010173 或 http://www.mater-rep.com/CN/Y2023/V37/I22/22010173

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