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材料导报  2022, Vol. 36 Issue (18): 21050128-6    https://doi.org/10.11896/cldb.21050128
  无机非金属及其复合材料 |
Er3+/Yb3+共掺杂Ca0.5Gd(WO4)2荧光粉的发光性能和温度特性
于晓晨*, 李华健, 高博扬, 蒋银林, 李小杰, 郑荣芳, 吴涵, 宋泽钰, 樊继斌, 赵鹏
长安大学材料科学与工程学院,西安 710061
Luminescence Properties and Temperature Characteristics of Er3+/Yb3+ Co-doped Ca0.5Gd(WO4)2 Phosphor
YU Xiaochen*, LI Huajian, GAO Boyang, JIANG Yinlin, LI Xiaojie, ZHENG Rongfang, WU Han, SONG Zeyu, FAN Jibin, ZHAO Peng
School of Materials Science and Engineering, Chang'an University, Xi'an 710061, China
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摘要 上转换发光材料由于具备独特的热敏特性而被应用于非接触式光学温度传感技术,其中Ca0.5Gd(WO4)2具有良好的热稳定性和光学特性,非常适合作为温度传感器的基质材料。本工作采用高温固相法成功制备了Er3+、Yb3+共掺杂Ca0.5Gd(WO4)2荧光粉,研究了不同Yb3+掺杂浓度对样品物相结构、微观形貌和发光性能的影响。随着Yb3+掺杂浓度的增加,Ca0.5Gd(WO4)2∶Er3+/Yb3+荧光粉的上转换和近红外发光强度先增加后减小,在Yb3+掺杂浓度为10％(摩尔分数,下同)时,发光强度均出现最大值。根据泵浦功率与发光强度的依赖关系可以得出,Er3+的上转换发光属于双光子吸收过程。此外,测量了样品Ca0.5Gd(WO4)2∶0.5%Er3+/10%Yb3+在313~573 K温度范围内的上转换发射光谱,发现其相对灵敏度在548 K时达到最大值0.014 2 K-1。综上,Ca0.5Gd(WO4)2∶Er3+/Yb3+荧光粉在光电材料领域,特别是非接触式光学温度传感器方面具有潜在的应用价值。
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于晓晨
李华健
高博扬
蒋银林
李小杰
郑荣芳
吴涵
宋泽钰
樊继斌
赵鹏
关键词:  复式钨酸盐  上转换  近红外  温度传感  荧光强度比(FIR)    
Abstract: Up-conversion luminescent materials have been applied in non-contact optical temperature sensing technology due to their unique thermal sensitivity characteristics. Ca0.5Gd(WO4)2, with good thermal stability and optical properties, is suitable for the preparation of temperature-sensitive sensors. In this work, the Er3+/Yb3+ co-doped Ca0.5Gd(WO4)2 phosphors were successfully prepared by high-temperature solid-phase method, and the influences of different Yb3+ doping concentrations on the phase structure, morphology and luminescence properties of the samples were studied. With the increase of Yb3+ doping concentration, the up-conversion and near-infrared luminescence intensity of Ca0.5-Gd(WO4)2∶Er3+/Yb3+ sample first increased and then decreased, and achieved a maximum value when the Yb3+ doping concentration is 10 mol%. According to the relationship between pump power and luminescence intensity, it can be concluded that the up-conversion luminescence of Er3+ is a two-photon absorption process. In addition, the up-conversion luminescence of Ca0.5Gd(WO4)2∶0.5%Er3+/10%Yb3+ was measured in the temperature range of 313—573 K, and it was found that the relative sensitivity reached the maximum value of 0.014 2 K-1 at 548 K. In conclusion, the Ca0.5Gd(WO4)2∶Er3+/Yb3+ phosphor has potential application value in the field of optoelectronic materials, especially in non-contact optical temperature sensors.
Key words:  tungstate    up-conversion    near infrared    temperature sensing    fluorescence intensity ratio
收稿日期:  2202-09-25      出版日期:  2022-09-25      发布日期:  2022-09-26
ZTFLH:  O482  
基金资助: 中国博士后科学基金(2016M602746);中国大学生创新创业训练计划(201910710572);国家自然科学基金(61604016)
通讯作者:  *yuxc2009@163.com   
作者简介:  于晓晨,2009年毕业于南开大学,获凝聚态物理专业理学博士学位。现为长安大学副教授,已在国内外学术期刊上发表论文30余篇,授权国家发明专利5项。研究方向为光电材料与器件,主要包括稀土发光材料、光催化材料及钙钛矿太阳能电池的基础理论和应用研究。
引用本文:    
于晓晨, 李华健, 高博扬, 蒋银林, 李小杰, 郑荣芳, 吴涵, 宋泽钰, 樊继斌, 赵鹏. Er3+/Yb3+共掺杂Ca0.5Gd(WO4)2荧光粉的发光性能和温度特性[J]. 材料导报, 2022, 36(18): 21050128-6.
YU Xiaochen, LI Huajian, GAO Boyang, JIANG Yinlin, LI Xiaojie, ZHENG Rongfang, WU Han, SONG Zeyu, FAN Jibin, ZHAO Peng. Luminescence Properties and Temperature Characteristics of Er3+/Yb3+ Co-doped Ca0.5Gd(WO4)2 Phosphor. Materials Reports, 2022, 36(18): 21050128-6.
链接本文:  
http://www.mater-rep.com/CN/10.11896/cldb.21050128  或          http://www.mater-rep.com/CN/Y2022/V36/I18/21050128
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