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材料导报  2022, Vol. 36 Issue (18): 21050119-6    https://doi.org/10.11896/cldb.21050119
  高分子与聚合物基复合材料 |
以Nafion和离子液体作为软模板合成聚苯胺及其在超级电容器中的应用
周海云1,2,3, 何明基1,2,3, 张磊4, 王红强1,2,3, 梁华彬1,2,3, 杨健华1,2,3, 钟新仙1,2,3,*
1 广西师范大学化学与药学学院,广西 桂林 541004
2 省部共建药用资源化学与药物分子工程国家重点实验室,广西 桂林 541004
3 广西低碳能源材料重点实验室,广西 桂林 541004
4 广西师范大学资产管理处,广西 桂林 541004
Synthesis of Polyaniline with Nafion and Ionic Liquid as Soft Template and Its Application in Supercapacitors
ZHOU Haiyun1,2,3, HE Mingji1,2,3, ZHANG Lei4, WANG Hongqiang1,2,3, LIANG Huabin1,2,3, YANG Jianhua1,2,3, ZHONG Xinxian1,2,3,*
1 School of Chemistry and Pharmaceutical Sciences, Guangxi Normal University, Guilin 541004, Guangxi, China
2 Key Laboratory for the Chemistry and Molecular Engineering of Medicinal Resources, Ministry of Education of China, Guilin 541004,Guangxi, China
3 Guangxi Key Laboratory of Low Carbon Energy Materials, Guilin 541004, Guangxi, China
4 Asset Management Service, Guangxi Normal University, Guilin 541004,Guangxi, China
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摘要 室温下,以全氟磺酸溶液(Nafion)和离子液体1-乙基-3-甲基咪唑三氟甲烷磺酸盐([Emim]OTF)为软模板、过硫酸铵(APS)为氧化剂,制备聚苯胺材料(NL-PANI)。SEM结果表明,NL-PANI为尺寸均一、孔隙分布均匀的三维纳米纤维状结构。以NL-PANI 为活性物质,1.0 mol·L-1 H2SO4为电解液,组装成对称性超级电容器,在0.1 A·g-1电流密度下,NL-PANI的比容量为650.49 F·g-1,当电流密度从0.1 A·g-1增大到1.0 A·g-1时,比容量保持率为82.46%,说明NL-PANI具有优异的电容性能和倍率性能。
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周海云
何明基
张磊
王红强
梁华彬
杨健华
钟新仙
关键词:  超级电容器  聚苯胺(PANI)  软模板  表面活性剂  离子液体    
Abstract: Polyaniline (NL-PANI) was prepared with ammonium sulfate (APS) as oxidant, and Nafion and 1-ethyl-3-methylimidazolium trifluoromethanesulfonate ([Emim]OTF) as soft template at room temperature. SEM results show that NL-PANI is 3D nanofibrous structure with uniform size and pore distribution. The symmetric supercapacitor was assembled with NL-PANI as active substance and 1.0 mol·L-1 H2SO4 as electrolyte. At a current density of 0.1 A·g-1, the specific capacitance of NL-PANI is 650.49 F·g-1. When the current density increases from 0.1 A·g-1 to 1.0 A·g-1, the specific capacity retention rate is 82.46%. NL-PANI has excellent capacitance performance and rate performance.
Key words:  supercapacitor    polyaniline    soft template    surface active agent    ionic liquid
收稿日期:  2202-09-25      出版日期:  2022-09-25      发布日期:  2022-09-26
ZTFLH:  O633.21  
  TM53  
基金资助: 国家自然科学基金(51964006;51474110);广西自然科学基金(2018GXNSFAA138136)
通讯作者:  *zhongxx2004@163.com   
作者简介:  周海云,2018年7月于广西民族师范学院获得学士学位。从2019年9月起,在钟新仙教授的指导下,在广西师范大学攻读硕士研究生学位。主要从事导电聚合物材料的研究。钟新仙,广西师范大学化学与药学学院教授、硕士研究生导师。1994年6月在广西师范大学化学与药学学院取得化学学士学位,1999年6月在广西师范大学化学与药学学院取得有机化学理学硕士学位,2008年12月在湖南大学化学与化工学院取得应用化学博士学位。主要从事新能源材料的研究工作。已在国内外重要期刊发表论文近50篇。
引用本文:    
周海云, 何明基, 张磊, 王红强, 梁华彬, 杨健华, 钟新仙. 以Nafion和离子液体作为软模板合成聚苯胺及其在超级电容器中的应用[J]. 材料导报, 2022, 36(18): 21050119-6.
ZHOU Haiyun, HE Mingji, ZHANG Lei, WANG Hongqiang, LIANG Huabin, YANG Jianhua, ZHONG Xinxian. Synthesis of Polyaniline with Nafion and Ionic Liquid as Soft Template and Its Application in Supercapacitors. Materials Reports, 2022, 36(18): 21050119-6.
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http://www.mater-rep.com/CN/10.11896/cldb.21050119  或          http://www.mater-rep.com/CN/Y2022/V36/I18/21050119
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