混凝土气泡调控型表面活性剂的研究进展

doi:10.11896/cldb.20090232

材料导报

2022, Vol. 36

Issue (18): 20090232-7 https://doi.org/10.11896/cldb.20090232

无机非金属及其复合材料

混凝土气泡调控型表面活性剂的研究进展

乔敏^1,2,*, 单广程¹, 高南箫¹, 陈健^1,2, 吴井志², 朱伯淞¹, 冉千平^1,3

1 江苏苏博特新材料股份有限公司,高性能土木工程材料国家重点实验室,南京 211103
2 博特新材料泰州有限公司,江苏泰州 225474
3 东南大学材料科学与工程学院,江苏省土木工程材料重点实验室,南京 211189

Research Progress of Concrete Air Controlled Surfactants

QIAO Min^1,2,*, SHAN Guangcheng¹, GAO Nanxiao¹, CHEN Jian^1,2, WU Jingzhi², ZHU Bosong¹, RAN Qianping^1,3

1 State Key Laboratory of High Performance Civil Engineering Materials,Jiangsu Sobute New Materials Co., Ltd., Nanjing 211103, China
2 Bote New Materials Taizhou Co., Ltd., Taizhou 225474, Jiangsu, China
3 Jiangsu Key Laboratory of Construction Materials, School of Material Science and Engineering, Southeast University, Nanjing 211189, China

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摘要随着我国基础设施建设的大力发展,目前在建的高速公路、铁路、大型桥梁、隧道、大型水利水电工程、高层建筑、地下工程的数量均居世界首位。这些重大工程的发展无一不与混凝土材料息息相关,因此对混凝土的耐久性提出了更高的要求。如何提高现代工程混凝土的耐久性、延长混凝土构筑物的安全服役年限是混凝土研究面临的重大问题。
混凝土气孔结构直接影响混凝土的抗冻融、抗介质渗透以及结构稳定等耐久性性能,在混凝土搅拌过程中掺入气泡调控型表面活性剂,可以在新拌混凝土中引入适量细小、均匀、密闭的气泡,大大改善拌合物的和易性,从而提高混凝土的抗冻、抗渗、抗碳化等耐久性。因此,混凝土气泡调控型表面活性剂的研究和生产逐渐成为外加剂领域的热点。
本文根据表面活性剂的定义、类型和特点,分别从表面活性剂的作用机理及其在混凝土中的失效原因等方面介绍了混凝土气泡调控表面活性剂的最新研究成果,主要讨论了新型双子表面活性剂在混凝土中的应用和表面活性剂的分子自组装行为及泡沫行为的作用机理,并分析了混凝土中的盐效应及吸附效应等对表面活性剂的影响,以期为将来研发性能优良的混凝土气泡调控型表面活性剂提供参考。

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	乔敏
	单广程
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	吴井志
	朱伯淞
	冉千平

关键词: 表面活性剂分类气泡作用机理失效机理

Abstract: With the rapid development of our country's infrastructure construction, the number of highways, railways, large bridges, tunnels, large water conservancy and hydropower projects, high-rise buildings, and underground projects currently under construction ranks first in the world. The development of these major projects is closely related to concrete materials, which puts forward higher requirements for the durability of concrete. Improving the durability of modern engineering concrete and extending the safe service life of concrete structures are the major issues faced by concrete research.
The pore structure of concrete directly affects the durability of concrete, such as freeze-thaw resistance, medium penetration resistance and structural stability. Adding air controlled surfactants during concrete mixing can introduce small and uniform bubbles into the fresh concrete, which greatly improve the workability of the mixture and the durability of concrete, such as the freeze-thaw resistance, anti-permeability and carbonation resistance. Therefore, the research and production of air controlled surfactants gradually become a hot spot in the field of admixtures.
According to the definition, types and characteristics of surfactants, this paper introduces the latest research results of concrete air controlled surfactants from the perspective of the action mechanism and the failure reasons of surfactants in concrete. The application of new gemini surfactants in concrete and the molecular self-assembly behavior and foam behavior of surfactants are mainly discussed, and the influence of salt and adsorption effects in concrete on the failure of surfactants is analyzed. This paper is expected to provide a reference for the research of air controlled surfactants with better physiochemical properties in concrete.

Key words: surfactant classification bubble action mechanism failure mechanism

收稿日期: 2202-09-25 出版日期: 2022-09-25 发布日期: 2022-09-26

ZTFLH:

TU528

基金资助: 国家重点研发计划(2020YFC1909900);国家自然科学基金杰出青年基金项目(51825203);国家自然科学基金(52178213);江苏省自然科学基金项目(BK20211030;BK20211031);中国国家铁路集团有限公司科技研究开发计划(N2020G046;K2020G035)

通讯作者: ^*qiaomin@cnjsjk.cn

作者简介: 乔敏,高级工程师,江苏苏博特新材料股份有限公司研究所所长,博特新材料泰州有限公司总工程师,本硕博毕业于南京大学高分子化学与物理专业。主持完成国家自然科学基金等国家及省部级项目2项,参与完成了国家自然科学基金等国家及省部级项目9项。一直围绕高性能混凝土化学外加剂的研发及产业化开展了深入的研究,开发出功能性混凝土化学外加剂十余种,产品成功应用于港珠澳跨海大桥、乌东德水电站等国家重特大工程,并出口到海外。在Cement and Concrete Research等知名期刊共计发表论文75篇,其中SCI收录 25篇,EI收录41篇;授权发明专利49项,授权国际专利3项;参编协会标准2项。

引用本文:

乔敏, 单广程, 高南箫, 陈健, 吴井志, 朱伯淞, 冉千平. 混凝土气泡调控型表面活性剂的研究进展[J]. 材料导报, 2022, 36(18): 20090232-7.
QIAO Min, SHAN Guangcheng, GAO Nanxiao, CHEN Jian, WU Jingzhi, ZHU Bosong, RAN Qianping. Research Progress of Concrete Air Controlled Surfactants. Materials Reports, 2022, 36(18): 20090232-7.

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http://www.mater-rep.com/CN/10.11896/cldb.20090232 或 http://www.mater-rep.com/CN/Y2022/V36/I18/20090232

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