镁合金氧化机理研究进展

doi:10.11896/cldb.20120108

材料导报

2023, Vol. 37

Issue (1): 20120108-9 https://doi.org/10.11896/cldb.20120108

金属与金属基复合材料

镁合金氧化机理研究进展

李多娇, 程春龙, 乐启炽^*, 陈亮, 闫家仕

东北大学材料电磁过程研究教育部重点实验室,沈阳 110819

Research Progress on Oxidation Mechanism of Magnesium Alloys

LI Duojiao, CHENG Chunlong, LE Qichi^*, CHEN Liang, YAN Jiashi

Key Laboratory of Electromagnetic Processing of Materials, Ministry of Education, Northeastern University, Shenyang 110819, China

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摘要镁及镁合金是最轻的结构工程金属,符合当今减重、节能、环保等要求。镁合金还具有高阻尼能力、良好的铸造性和焊接性、较高的导热性和导电性以及可回收特性。对比目前应用广泛的铝合金,镁合金的使用在满足力学性能要求的同时可以达到减重的效果,并减小对环境的压力。
镁合金应用前景广阔,但其对氧的高亲和力导致其在加工或使用过程中极易被氧化,且生成的氧化膜疏松多孔,不具有保护性,导致镁合金的加工与应用受到极大限制。因此,镁合金高温抗氧化性能研究是一个重要的研究方向。
目前,国内外镁合金高温氧化研究主要集中在以下几个方面:(1)不同温度下镁合金的氧化行为研究;(2)合金化对镁合金高温氧化性能的影响;(3)不同状态(液态/固态)镁合金的氧化行为。虽然镁合金氧化性研究已经较为深入,但至今仍缺乏综述性的总结。
因此,本文旨在综述并分析国内外镁合金高温氧化的研究现状,主要关注不同温度下镁合金的氧化行为、合金化对镁合金高温氧化性能的影响及其机理、镁合金氧化机理及保护性氧化膜失效的原因。

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关键词: 镁合金高温氧化合金化氧化膜氧化机理

Abstract: Magnesium and its alloys are the lightest structural metals, which meet requirements for weight loss, energy saving and emission reduction. Magnesium alloys exhibits advantages of high damping capacity, perfect castability and weldability, positive thermal and electrical conductivity, and recyclability. Compared with aluminum alloys widely used at present, the use of magnesium alloys can meet the requirements of mechanical properties at the same time achieves effect of weight reduction and is beneficial to environment.
Magnesium alloys have broad application prospects,however, the widespread usage of magnesium alloys is limited by the characteristics of high affinity with oxygen and prone to form porous oxide scales on surface. Thus, it is of great significance to research the high temperature oxidation resistance of magnesium alloys.
Nowadays, investigations on high temperature oxidation of magnesium alloys mainly concentrate in the following aspects: (1) research on the oxidation behaviors of magnesium alloys at different temperatures; (2) effect of alloy-elements on high temperature oxidation resistance of magnesium alloys; (3) oxidation behaviors of magnesium alloys at different states (liquid/solid). So, in order to broaden the application of magnesium alloys, it is necessary to show a comprehensive summary on oxidation resistance and mechanism of magnesium alloys.
The present paper aims to review the research of home and abroad on high temperature oxidation of magnesium alloys. The oxidation beha-viors, effect of alloy-elements on high temperature oxidation resistance, oxidation mechanism of magnesium alloys,and reasons for failure of protective oxide film are discussed.

Key words: magnesium alloy high temperature oxidation alloying oxide film oxidation mechanism

出版日期: 2023-01-10 发布日期: 2023-01-31

ZTFLH:

TG146.2

基金资助: 国家自然科学基金(52274377)

通讯作者: * 乐启炽,东北大学材料电磁过程研究教育部重点实验室教授、博士研究生导师。1990年本科毕业于东北大学有色金属冶金专业,并于2001年获得材料加工专业获博士学位,主要从事镁合金凝固与外场调控、镁合金成形理论与工艺、高性能镁合金与镁基复合材料以及镁合金电化学与表面工程的研究工作。在Journal of Power Sources、Ultrasonics Sonochemistry、Corrosion Science、《金属学报》等国内外重要学术期刊和国际会议上发表学术论文300余篇,其中SCI收录180余篇;主编教材1部,合作撰写专著4部;已授权专利50余项。qichil@mail.neu.edu.cn

作者简介: 李多娇,2019年6月毕业于沈阳理工大学,获得工学学士学位。现为东北大学材料科学与工程学院硕士研究生,目前主要从事镁合金的高温氧化研究。

引用本文:

李多娇, 程春龙, 乐启炽, 陈亮, 闫家仕. 镁合金氧化机理研究进展[J]. 材料导报, 2023, 37(1): 20120108-9.
LI Duojiao, CHENG Chunlong, LE Qichi, CHEN Liang, YAN Jiashi. Research Progress on Oxidation Mechanism of Magnesium Alloys. Materials Reports, 2023, 37(1): 20120108-9.

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http://www.mater-rep.com/CN/10.11896/cldb.20120108 或 http://www.mater-rep.com/CN/Y2023/V37/I1/20120108

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