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材料导报  2022, Vol. 36 Issue (10): 20100188-10    https://doi.org/10.11896/cldb.20100188
  无机非金属及其复合材料 |
金属硫化物/g-C3N4异质结的构建及其光催化性能改善与应用
甘建昌1,2, 胡海平1,2, 苏明1,2, 陈锋1,2, 王辉虎1,2,*
1 湖北工业大学绿色轻工材料湖北省重点实验室,武汉 430068
2 湖北工业大学材料与化学工程学院,武汉 430068
Construction, Photocatalytic Performance Improvement and Application of Metal Sulfide/g-C3N4 Heterojunctions
GAN Jianchang1,2, HU Haiping1,2, SU Ming1,2, CHEN Feng1,2, WANG Huihu1,2,*
1 Hubei Provincial Key Laboratory of Green Materials for Light Industry, Hubei University of Technology, Wuhan 430068, China
2 School of Materials and Chemical Engineering, Hubei University of Technology, Wuhan 430068, China
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摘要 金属硫化物和石墨相g-C3N4是两类具有可见光活性的典型光催化半导体材料,两者复合形成的异质结因具有高效可见光活性受到了研究者的广泛关注,在环境污染治理与新能源开发方面具有重要意义。然而,金属硫化物与g-C3N4复合后所形成的异质结仍存在电子-空穴复合率高、催化活性差和能量转换效率低等问题。本文从金属硫化物/g-C3N4异质结的构建、光催化剂性能改善及应用三个方面对近年来的研究进行了综述。在金属硫化物/g-C3N4异质结的构建方面,分别从Ⅱ型异质结、Z型异质结(直接Z型和间接Z型)、P-N型异质结和S型异质结进行总结;从异质结形貌调控、表/界面改性等方面对异质结光催化性能改善进行了归纳,同时概述了金属硫化物/g-C3N4异质结在水解产氢、CO2还原、降解有机污染物、光催化固氮以及光催化杀菌等方面的应用,并提出了金属硫化物/g-C3N4异质结在光催化过程中所面临的诸多挑战,指出利用能带匹配来合理构建异质结是提高金属硫化物与g-C3N4光催化剂活性的有效方法,金属硫化物/g-C3N4异质结大规模的廉价制备是实际应用中需要解决的问题。
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甘建昌
胡海平
苏明
陈锋
王辉虎
关键词:  金属硫化物  g-C3N4  异质结  有机污染物降解  水解产氢    
Abstract: Metal sulfides and graphite phase g-C3N4 are two kinds of typical photocatalytic semiconductor materials with visible light activity. The heterojunctions formed by the combination of metal sulfides and g-C3N4 have been widely concerned by researchers due to its excellent photocatalytic performance, which has important application prospect in environmental pollution control and new energy development. However, the hete-rojunctions still suffer from high electron-hole recombination rate, poor catalytic activity and low energy conversion efficiency. In this paper, the recent research progress in the construction of metal sulfide/g-C3N4 heterojunctions, improvement of photocatalytic performance and application are reviewed. In the aspect of metal sulfide/g-C3N4 heterojunctions construction, the type Ⅱ heterojunction, Z-scheme heterojunction (direct Z-shceme and indirect Z-scheme), P-N heterojunction and S-scheme heterojunction are summarized respectively, and the improvement of hete-rojunctions photocatalytic performance is concluded from the aspects of heterojunctions morphology control and surface/interface modification. At the same time, the applications of metal sulfide/g-C3N4 heterojunctions in hydrogen production, CO2 reduction, organic pollutants degradation, photocatalytic nitrogen fixation and photocatalytic sterilization are also summarized. The challenges faced by metal sulfide/g-C3N4 heterojunctions in the process of photocatalysis are put forward. It is pointed out that the reasonable construction of heterojunctions by using energy band matching is the key to improving the photocatalytic activity of metal sulfides and g-C3N4. Large-scale and cheap fabrication of metal sulfide/g-C3N4 heterojunctions is a problem to be solved in practical application.
Key words:  metal sulfides    g-C3N4    heterojunction    degradation of organic pollutants    hydrogen production
发布日期:  2022-05-24
ZTFLH:  Q643  
基金资助: 湖北省教育厅重点项目(D20171405)
通讯作者:  wanghuihu@hbut.edu.cn   
作者简介:  甘建昌,2018年6月毕业于湖北工业大学,获得工学学士学位。现为湖北工业大学硕士研究生,在王辉虎教授的指导下进行研究。目前主要研究领域为半导体光催化。
王辉虎,湖北工业大学材料与化学工程学院教授、硕士研究生导师, 2006年12月在华中科技大学材料科学与工程学院取得博士学位,2007—2010年分别在韩国延世大学和葡萄牙波尔图大学进行博士后研究工作。研究方向为新能源材料制备与应用。近年来,在半导体光催化以及储氢材料领域发表论文50余篇,包括Chemical Engineering Journal、Journal of Hazardous Materials、Energy、ChemcatChem、Catalysis Science & Technology、International Journal of Hydrogen Energy等。
引用本文:    
甘建昌, 胡海平, 苏明, 陈锋, 王辉虎. 金属硫化物/g-C3N4异质结的构建及其光催化性能改善与应用[J]. 材料导报, 2022, 36(10): 20100188-10.
GAN Jianchang, HU Haiping, SU Ming, CHEN Feng, WANG Huihu. Construction, Photocatalytic Performance Improvement and Application of Metal Sulfide/g-C3N4 Heterojunctions. Materials Reports, 2022, 36(10): 20100188-10.
链接本文:  
http://www.mater-rep.com/CN/10.11896/cldb.20100188  或          http://www.mater-rep.com/CN/Y2022/V36/I10/20100188
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