Recent Research Progress of Metal Sulfides as Anode Materials for Sodium Ion Batteries
XIA Guanghui, WANG Ding*, LI Xuebao, DONG Peng, ZHANG Yingjie, WANG Haoyi
Key Laboratory of Advanced Battery Materials of Yunnan Province, National and Local Joint Engineering Laboratory for Lithium-ion Batteries and Materials Pre-paration Technology, School of Metallurgy and Energy Engineering, Kunming University of Science and Technology, Kunming 650093, China
Abstract: The huge discrepancy between the worldwide supply-both existent and potential-and the tremendous energy market demand for sodium resources has been motivating the attempts of seeking substitutes for lithium-based electrochemical energy storage systems, in which sodium ion batteries are now expected to become one of the promising candidates. Belonging to the same main group in the periodic table, sodium element boasts excellent chemical properties similar to lithium element, and is even more competitive in reserves and cost. But, on the other side, sodium ion batteries also have its disadvantages: (1) higher ion weight which renders its theoretical energy density lower than that of lithium ion battery; (2) larger radius which makes sodium ions more difficult to be intercalated and deintercalated during the charge and discharge processes. Thus reasonable design and efficient synthesis of electrode materials are the key factors to increase the electrochemical performance and reduce the cost of sodium ion batteries. At present the global researches on sodium ion batteries are mainly concentrated on the mechanism of sodium ion insertion and the improvement in energy density as well as cycle performance. The large variety of metal sulfides have been proved to possess large theoretical capacity and high energy density and suitable to serve as anode material of sodium ion batteries, though they still have obvious deficiencies such as poor conductivity, severe volume expansion, low first coulomb efficiency, and slowly diffusion coefficient. Moreover, systematical works on the structural regulation and corresponding mechanisms are also necessary, because the performance of battery depends on, besides chemical composition, morphology, structure and particle size of the electrode material. This paper provides mainly a summary of the latest research progress on metal sulfides from the aspects of nano-structure regulation and material compounding, as well as a prospective discussion of the future development trends.
夏广辉, 王丁, 李雪豹, 董鹏, 张英杰, 王皓逸. 钠离子电池金属硫化物负极材料的研究进展[J]. 材料导报, 2021, 35(13): 13041-13051.
XIA Guanghui, WANG Ding, LI Xuebao, DONG Peng, ZHANG Yingjie, WANG Haoyi. Recent Research Progress of Metal Sulfides as Anode Materials for Sodium Ion Batteries. Materials Reports, 2021, 35(13): 13041-13051.
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2021, Vol. 35 
