Please wait a minute...
材料导报  2021, Vol. 35 Issue (8): 8001-8006    https://doi.org/10.11896/cldb.20010021
  无机非金属及其复合材料 |
新型薄层氮化碳/氧化石墨烯复合材料的制备及在锌-空气电池中的应用
孙晓玲1,2, 弓巧娟2, 梁云霞2, 巩鹏妮2
1 山西师范大学化学与材料科学学院,临汾 041004
2 运城学院应用化学系,运城 044000
Preparation of Novel and Thin Layer Carbon Nitride/Graphene Oxide Composites and Their Application in Zinc-Air Battery
SUN Xiaoling1,2, GONG Qiaojuan2, LIANG Yunxia2, GONG Pengni2
1 College of Chemistry and Materials Sciences, Shanxi Normal University, Linfen 041004, China
2 Department of Applied Chemistry, Yuncheng College, Yuncheng 044000, China
下载:  全 文 ( PDF ) ( 8884KB ) 
输出:  BibTeX | EndNote (RIS)      
摘要 本研究通过简单的自上而下的方法成功改进了氮化碳材料,并通过引入氧化石墨烯制备出薄层的石墨烯复合材料(CoOx/PCN/RGO),该复合材料在氧还原反应和氧析出反应中表现出良好的双功能电催化活性(ΔE=0.95 V)和稳定性。CoOx/PCN/RGO复合物作为锌-空气电池的阴极材料时,显示出优于Pt/C+Ir/C的充放电性能。CoOx/PCN/RGO复合材料的优异催化性能主要归因于其薄层结构、大的比表面积和充分暴露的活性中心。
服务
把本文推荐给朋友
加入引用管理器
E-mail Alert
RSS
作者相关文章
孙晓玲
弓巧娟
梁云霞
巩鹏妮
关键词:  CoOx  氮化碳  氧化石墨烯  双功能催化剂  锌-空气电池    
Abstract: In this work, carbon nitride materials have been successfully improved by a simple top-down method and thin-layer graphene composites (CoOx/PCN/RGO) have been prepared by introducing graphene oxide, showing good bifunctional electrocatalytic activity (ΔE=0.95 V) and stability in the oxygen reduction and oxygen evolution reactions. The zinc-air battery with the CoOx/PCN/RGO composites exhibited greater charge/discharge performance than Pt/C+Ir/C which are mainly attributed to the structure of the thin layer, the large surface area and the fully exposed active sites.
Key words:  CoOx    carbon nitride    graphene oxide    bifunctional catalyst    zinc-air battery
               出版日期:  2021-04-25      发布日期:  2021-05-10
ZTFLH:  TM911.41  
基金资助: 国家自然科学基金(U1810110);山西省重点研发项目(201803D121030);山西省盐湖区省教科局项目
通讯作者:  sun18835731017@163.com   
作者简介:  孙晓玲,山西师范大学化学与材料科学学院,在读硕士。主要从事氧还原反应与氧析出反应双功能催化剂以及其在锌空电池中的应用的研究。
弓巧娟,2007年获西北工业大学博士学位,现为运城学院应用化学系教授,山西师范大学和山西大学研究生导师。主要从事功能碳材料、超级电容器、锌空电池等的研究。
引用本文:    
孙晓玲, 弓巧娟, 梁云霞, 巩鹏妮. 新型薄层氮化碳/氧化石墨烯复合材料的制备及在锌-空气电池中的应用[J]. 材料导报, 2021, 35(8): 8001-8006.
SUN Xiaoling, GONG Qiaojuan, LIANG Yunxia, GONG Pengni. Preparation of Novel and Thin Layer Carbon Nitride/Graphene Oxide Composites and Their Application in Zinc-Air Battery. Materials Reports, 2021, 35(8): 8001-8006.
链接本文:  
http://www.mater-rep.com/CN/10.11896/cldb.20010021  或          http://www.mater-rep.com/CN/Y2021/V35/I8/8001
1 Yang X H, Wang Y C, Zhang G X, et al. Applied Catalysis B: Environmental,2020,264,118523.
2 Du J, Liu L, Wu H X, et al. Nanoscale,2019,11(47),22796.
3 Sun Y T, Liu X R, Jiang Y M, et al. Journal of Materials Chemistry A,2019,7(31),18183.
4 Meng F L, Liu K H, Zhang Y, et al. Small,2018,14(32),1703843.
5 Wang H F, Tang C, Zhang Q. Advanced Functional Materials,2018,28(46),1803329.
6 Li H F, Ma L T, Han C P, et al. Nano Energy,2019,62,550.
7 Li T T, Lu Y X, Zhao S S, et al. Journal of Materials Chemistry A,2018,6(8),3730.
8 Shinde S S, Lee C H, Jung J Y, et al. Energy & Environmental Science,2019,12(2),727.
9 Gao L, Zhu M C, Zhang Z Y, et al. Electrochimica Acta,2019,327,134980.
10 Chen D, Yu J H, Cui Z X, et al. Electrochimica Acta,2020,331,135394.
11 Cao Z Q, Wu M Z, Hu H B, et al. NPG Asia Materials,2018,10,670.
12 Wang Z C, Xu W J, Chen X K, et al. Advanced Functional Materials,2019,29(33),1902875.
13 Ji D X, Fan L, Tao L, et al. Angewandte Chemie,2019,58(39),13840.
14 Guo J H, Li Q F, Hou H T, et al. International Journal of Hydrogen Energy,2019,44(57),30348.
15 Huang Z X, Qin X P, Li G Z, et al. ACS Applied Energy Materials,2019,2(6),4428.
16 Chakrabarty S, Mukherjee A, Su W N, et al. International Journal of Hydrogen Energy,2018,44(3),1565.
17 Zhang T W, Li Z F, Wang L K, et al. International Journal of Hydrogen Energy,2019,44(3),1610.
18 Niu W H, Li Z, Marcus K, et al. Advanced Energy Materials,2017,8(1),1701642.
19 Wang W, Chen W H, Miao P Y, et al. ACS Catalysis,2017,7(9),6144.
20 Xu C Y, Han Q, Zhao Y, et al. Journal of Materials Chemistry A,2015,3(5),1841.
21 Wu J, Wang J X, Lv Y, et al. Inorganic Chemistry Communications,2019,106,128.
22 Su Y L, Xiao Y T, Li Y, et al. Materials Chemistry and Physics,2011,126(3),761.
23 Wang X P, Lim T T. Applied Catalysis B: Environmental,2010,100(1-2),355.
[1] 胡绍争, 王菲, 李政, 马宏飞, 李萍. 新型全光谱响应W18O49/g-C3N4异质结催化剂的构建及光催化降解有机染料性能研究[J]. 材料导报, 2021, 35(8): 8011-8016.
[2] 索鑫磊, 刘艳, 张立来, 苏杭, 李婉, 李国龙. 基于氧化石墨烯空穴传输层的平面异质结钙钛矿太阳能电池[J]. 材料导报, 2021, 35(6): 6015-6019.
[3] 姜鹏程, 王周福, 王玺堂, 刘浩, 马妍. 不同气氛下类石墨相氮化碳的合成及热稳定性能[J]. 材料导报, 2021, 35(6): 6048-6053.
[4] 他进国, 黄一凡, 甄小娟. 500 keV质子辐照对氧化石墨烯薄膜材料的影响研究[J]. 材料导报, 2020, 34(Z1): 39-42.
[5] 方敏, 王璐, 侯佳欣, 南晓茹, 赵彬. 丝素蛋白复合石墨烯类材料在生物医学领域中的研究进展[J]. 材料导报, 2020, 34(Z1): 511-515.
[6] 刘宇程, 祝梦, 陈明燕, 涂雯雯, 甘冬. 氧化石墨烯/金属有机框架材料复合膜在有机废水处理中的研究进展[J]. 材料导报, 2020, 34(7): 7003-7009.
[7] 俞坤, 刘金香, 谢水波, 刘迎九, 葛玉杰. 聚吡咯/石墨相氮化碳复合材料吸附铀(Ⅵ)的性能与机制[J]. 材料导报, 2020, 34(23): 23020-23026.
[8] 肖帅, 王振飞, 张萍, 何岗, 洪建和. 还原氧化石墨烯/碳纸空气电极的电化学制备及性能[J]. 材料导报, 2020, 34(20): 20005-20009.
[9] 杨玥, 赵斌, 张友魁, 李敏, 段涛. g-C3N4光催化还原净化重金属离子的研究进展[J]. 材料导报, 2020, 34(17): 17132-17138.
[10] 姚庆达, 温会涛, 杨长凯, 梁永贤, 王小卓, 但卫华. 多层氧化石墨烯膜的结构、性能及在水处理中的应用进展[J]. 材料导报, 2020, 34(15): 15047-15058.
[11] 余慧丽, 杭祖圣, 怀旭, 黄玉安, 张春祥, 张金泉. 基于催化活性提升的g-C3N4的表面活化、敏化及功能化研究进展[J]. 材料导报, 2020, 34(11): 11121-11128.
[12] 王鸣, 黄海旭, 齐鹏涛, 刘磊, 王学雷, 杨绍斌. 还原氧化石墨烯(RGO)/硅复合材料的制备及用作锂离子电池负极的电化学性能[J]. 材料导报, 2019, 33(6): 927-931.
[13] 张迪, 杨迪, 徐翠, 周日宇, 李浩, 李靖, 王朋. 还原氧化石墨烯高效吸附双酚F的机理研究[J]. 材料导报, 2019, 33(6): 954-959.
[14] 冯妙, 刘燕, 邓会宁, 王子霞. 层层自组装法制备氧化石墨烯复合单价选择性离子交换膜[J]. 材料导报, 2019, 33(6): 1057-1060.
[15] 范海波, 任启芳, 余淼, 王苏蕾, 曹镜宇, 金震, 丁益. 磷酸银/类石墨氮化碳-硅藻土复合材料的制备及可见光催化性能[J]. 材料导报, 2019, 33(20): 3383-3389.
[1] Wei ZHOU, Xixi WANG, Yinlong ZHU, Jie DAI, Yanping ZHU, Zongping SHAO. A Complete Review of Cobalt-based Electrocatalysts Applying to Metal-Air Batteries and Intermediate-Low Temperature Solid Oxide Fuel Cells[J]. Materials Reports, 2018, 32(3): 337 -356 .
[2] Yanzhen WANG, Mingming CHEN, Chengyang WANG. Preparation and Electrochemical Properties Characterization of High-rate SiO2/C Composite Materials[J]. Materials Reports, 2018, 32(3): 357 -361 .
[3] Yimeng XIA, Shuai WU, Feng TAN, Wei LI, Qingmao WEI, Chungang MIN, Xikun YANG. Effect of Anionic Groups of Cobalt Salt on the Electrocatalytic Activity of Co-N-C Catalysts[J]. Materials Reports, 2018, 32(3): 362 -367 .
[4] Dongyong SI, Guangxu HUANG, Chuanxiang ZHANG, Baolin XING, Zehua CHEN, Liwei CHEN, Haoran ZHANG. Preparation and Electrochemical Performance of Humic Acid-based Graphitized Materials[J]. Materials Reports, 2018, 32(3): 368 -372 .
[5] Huanchun WU, Fei XUE, Chengtao LI, Kewei FANG, Bin YANG, Xiping SONG. Fatigue Crack Initiation Behaviors of Nuclear Power Plant Main Pipe Stainless Steel in Water with High Temperature and High Pressure[J]. Materials Reports, 2018, 32(3): 373 -377 .
[6] Miaomiao ZHANG,Xuyan LIU,Wei QIAN. Research Development of Polypyrrole Electrode Materials in Supercapacitors[J]. Materials Reports, 2018, 32(3): 378 -383 .
[7] Qingshun GUAN,Jian LI,Ruyuan SONG,Zhaoyang XU,Weibing WU,Yi JING,Hongqi DAI,Guigan FANG. A Survey on Preparation and Application of Aerogels Based on Nanomaterials[J]. Materials Reports, 2018, 32(3): 384 -390 .
[8] Yunzi LIU,Wei ZHANG,Zhanyong SONG. Technological Advances in Preparation and Posterior Treatment of Metal Nanoparticles-based Conductive Inks[J]. Materials Reports, 2018, 32(3): 391 -397 .
[9] Bingwei LUO,Dabo LIU,Fei LUO,Ye TIAN,Dongsheng CHEN,Haitao ZHOU. Research on the Two Typical Infrared Detection Materials Serving at Low Temperatures: a Review[J]. Materials Reports, 2018, 32(3): 398 -404 .
[10] Lanyan LIU,Jun SONG,Bowen CHENG,Wenchi XUE,Yunbo ZHENG. Research Progress in Preparation of Lignin-based Carbon Fiber[J]. Materials Reports, 2018, 32(3): 405 -411 .
Viewed
Full text


Abstract

Cited
  Shared   
  Discussed