Study on Mechanism of Highly Effective Adsorption of Bisphenol F by Reduced Graphene Oxide
ZHANG Di1, YANG Di1, XU Cui2, ZHOU Riyu3, LI Hao1, LI Jing1, WANG Peng1
1 Faculty of Environmental Science and Engineering, Kunming University of Science & Technology, Kunming 650500 2 Economic Development Division of Weifang Environmental Protection Bureau, Weifang 261000 3 School of Environment and Resource, Southwest University of Science and Technology, Mianyang 621010
Abstract: The mechanism of highly efficient adsorption of endocrine disruptor bisphenol F (BPF) by reduced graphene oxide (RGO) was investigated in this study. Compared with similar carbonaceous adsorbents (such as GP and GO), RGO exhibit great potential as an efficient adsorbent for removing BPF from waste water. The adsorption isotherm of BPF on the surface of RGO can be well fitted by Freundlich model, which indicated the occurrence of multilayer adsorption of BPF on RGO surface. The results of thermodynamic studies showed that the adsorption of BPF on RGO surface was a spontaneous endothermic process. The adsorption capacity of RGO to BPF increased slowly with the increase of solution pH value from 2.0 to 11.0. After pH exceeded the pKa1 of BPF, there was a rapid raise in the adsorption capacity and interaction affinity until the maximum was achieved. Once the secondary dissociation of BPF occurred, the adsorption capacity and affinity of RGO decreased dramatically, due to the strong electrostatic repulsion. The primary mechanism of highly efficient adsorption of BPF by RGO included π-π interaction, hydrophobic interaction and charge-assisted hydrogen bonding. The different pH value of the solution could lead to significant difference in adsorption capacity of RGO to BPF. This study provided a theoretical basis for the new graphene-based adsorbents used for removing dissociable endocrine disruptors in contaminated water.
作者简介: 张迪,博士,美国University of Massachusetts Amherst博士后,副教授,博士研究生导师,云南省中青年学术和技术带头人后备人才.王朋,2013年6月毕业于昆明理工大学,获得工学硕士学位。
引用本文:
张迪, 杨迪, 徐翠, 周日宇, 李浩, 李靖, 王朋. 还原氧化石墨烯高效吸附双酚F的机理研究[J]. 材料导报, 2019, 33(6): 954-959.
ZHANG Di, YANG Di, XU Cui, ZHOU Riyu, LI Hao, LI Jing, WANG Peng. Study on Mechanism of Highly Effective Adsorption of Bisphenol F by Reduced Graphene Oxide. Materials Reports, 2019, 33(6): 954-959.
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