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材料导报  2021, Vol. 35 Issue (6): 6048-6053    https://doi.org/10.11896/cldb.20010111
  无机非金属及其复合材料 |
不同气氛下类石墨相氮化碳的合成及热稳定性能
姜鹏程, 王周福, 王玺堂, 刘浩, 马妍
武汉科技大学省部共建耐火材料与冶金国家重点实验室,武汉 430081
Synthesis of Graphite-like Carbon Nitride in Different Atmospheres and Its Thermal Stability
JIANG Pengcheng, WANG Zhoufu, WANG Xitang, LIU Hao, MA Yan
The State Key Laboratory of Refractories and Metallurgy, Wuhan University of Science and Technology, Wuhan 430081, China
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摘要 本研究以三聚氰胺为原料,采用热聚合法分别在空气气氛和氩气气氛下进行不同温度的热处理,制备片层状类石墨相氮化碳(g-C3N4)。运用XRD、SEM、TEM、FT-IR和Raman等对产物进行了表征分析,采用TG-DSC对三聚氰胺的热解行为和生成的g-C3N4的热稳定性能进行了分析。结果表明:通过热聚合法可以将三聚氰胺合成高聚合度、具有片层状结构的纯相g-C3N4。氩气气氛下热聚合生成的g-C3N4表面光滑,片层状g-C3N4紧密堆积程度较空气气氛下热聚合生成的g-C3N4更高。热处理温度是影响g-C3N4的重要因素,500 ℃热处理即能生成片层状g-C3N4,且在700 ℃仍能稳定存在。氩气气氛下合成的g-C3N4的热稳定性能比空气气氛下合成的g-C3N4更好。
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姜鹏程
王周福
王玺堂
刘浩
马妍
关键词:  热聚合法  三聚氰胺  类石墨相氮化碳  热稳定性    
Abstract: Graphite-like carbon nitride(g-C3N4) with lamellar structure was prepared using melamine as raw material via a facile thermal polymerization method at different temperatures in air and argon atmosphere. The effects of melamine pyrolysis in different atmospheres and the thermal stability of g-C3N4 products were studied by TG-DSC, X-ray diffraction (XRD), scanning electron microscope (SEM), transmission electron microscopy (TEM), fourier transform infrared spectroscopy (FT-IR) and Raman. The results showed that the pure phase g-C3N4 with high crystallinity and lamellar structure could be synthesized via the pretreated melamine by thermal polymerization method.In argon atmosphere, g-C3N4 with smooth and compact surface is more favorable than air atmosphere. g-C3N4 with lamellar structure could be observed at 500 ℃, and it could still exist stably at 700 ℃. The thermal stability of g-C3N4 synthesized in argon atmosphere was better than g-C3N4 in air atmosphere.
Key words:  thermal polymerization    melamine    graphite-like carbon nitride    thermal stability
               出版日期:  2021-03-25      发布日期:  2021-03-23
ZTFLH:  TQ115  
基金资助: 国家自然科学基金(516772195;51474166);湖北省高等学校优秀中青年科技创新团队计划(T201602);湖北省中央引导地方科技发展专项(2019ZYYD076)
通讯作者:  whwangzf@126.com   
作者简介:  姜鹏程,2015年6月毕业于武汉科技大学,获得工学学士学位。于2015年6月至今在武汉科技大学硕博连读,主要从事碳材料催化改性和碳复合耐火材料领域的研究。
王周福,武汉科技大学教授,博士研究生导师。其中2007—2008年到英国谢菲尔德大学材料研究所进行访问、合作研究。在国内外学术期刊上发表论文80余篇,申请国家发明专利41项,其中授权22项。其团队主要研究方向包括:高技术陶瓷粉体;耐火材料微结构设计与性能调控;冶炼新技术用耐火材料;先进隔热材料。主持完成科研项目40多项,包括国家“863”项目、国家科技支撑计划等。获国家科技进步二等奖一项,省科技进步一等奖两项、科技进步二等奖三项。已培养博士5名,硕士50余名。
引用本文:    
姜鹏程, 王周福, 王玺堂, 刘浩, 马妍. 不同气氛下类石墨相氮化碳的合成及热稳定性能[J]. 材料导报, 2021, 35(6): 6048-6053.
JIANG Pengcheng, WANG Zhoufu, WANG Xitang, LIU Hao, MA Yan. Synthesis of Graphite-like Carbon Nitride in Different Atmospheres and Its Thermal Stability. Materials Reports, 2021, 35(6): 6048-6053.
链接本文:  
http://www.mater-rep.com/CN/10.11896/cldb.20010111  或          http://www.mater-rep.com/CN/Y2021/V35/I6/6048
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