表面疏油Al2O3陶瓷膜的制备及表征

doi:10.11896/cldb.22120002

材料导报

2024, Vol. 38

Issue (13): 22120002-6 https://doi.org/10.11896/cldb.22120002

无机非金属及其复合材料

表面疏油Al₂O₃陶瓷膜的制备及表征

李伟¹, 王洪利¹, 刘学琰¹, 范智禹¹, 吴怡逸¹, 聂登攀^1,*, 陶文亮^1,2

1 贵州民族大学化学工程学院,贵阳 550025
2 贵州省科学技术协会,贵阳 550003

Preparation and Characterization of Al₂O₃ Ceramic Membrane with Hydrophobic Surface

LI Wei¹, WANG Hongli¹, LIU Xueyan¹, FAN Zhiyu¹, WU Yiyi¹, NIE Dengpan^1,*, TAO Wenliang^1,2

1 School of Chemical Engineering, Guizhou Minzu University, Guiyang 550025, China
2 Guizhou Association for Science and Technology, Guiyang 550003, China

摘要
参考文献
相关文章
推荐阅读
Metrics

下载:

全文 ( PDF ) ( 23327KB )
输出: BibTeX | EndNote (RIS)

摘要以氨水和无水氯化铝为原料,采用溶胶-凝胶法在SiC基体上制备了Al₂O₃陶瓷膜,以氟碳表面活性剂Capstone FS-50为改性剂,通过真空浸渍法对所制备的Al₂O₃膜进行疏油改性。结果表明,制备的膜孔径分布均匀,表面无裂纹和针孔缺陷,Capstone FS-50改性前后膜通量和孔结构几乎不变。Capstone FS-50能均匀附载在Al₂O₃膜表面,使其展现出良好的疏油性能(表面接触角最大为130°),在温度低于200 ℃时,改性陶瓷膜仍具有较好的疏油性和良好的耐磨性能。

	服务
	把本文推荐给朋友
	加入引用管理器
	E-mail Alert
	RSS
	作者相关文章
	李伟
	王洪利
	刘学琰
	范智禹
	吴怡逸
	聂登攀
	陶文亮

关键词: 溶胶-凝胶法 Al₂O₃陶瓷膜疏油改性陶瓷膜制备

Abstract: Al₂O₃ ceramic membrane was prepared on SiC matrix by sol-gel method with ammonia and anhydrous aluminum chloride as raw materials. The prepared Al₂O₃ membrane was olephophoric modified by vacuum impregnation with Capstone FS-50 as a fluorocarbon surfactant. The results show that the pore size distribution of the prepared membrane is uniform, there is no crack and pinhole defect on the surface, and the flux and pore structure of the membrane are almost unchanged before and after Capstone FS-50 modification. Capstone FS-50 can be uniformly attached to the surface of Al₂O₃ membrane, so that it shows good oil hydrophobicity (the maximum surface contact angle is 130°). When the temperature is lower than 200 ℃, the modified ceramic membrane still has good oil hydrophobicity and good wear resistance.

Key words: sol-gel method Al₂O₃ ceramic membrane oleophobic modification preparation method

出版日期: 2024-07-10 发布日期: 2024-08-01

ZTFLH:

TQ174

基金资助: 贵州省教育厅创新群体重大科研项目(黔教合KY[2018]016);贵州省科技计划项目(黔科合支撑[2020]4Y014);贵州省科技计划项目(黔科合支撑[2021]一般484)

通讯作者: ^*聂登攀,贵州民族大学化学工程学院副研究员、硕士研究生导师。2000年贵州大学过程装备与控制专业本科毕业,2004年贵州大学材料学专业硕士毕业,2018年贵州大学矿物学、岩石学、矿床学专业博士毕业。目前主要从事矿物材料加工方面的研究工作。发表论文30余篇。ndpz@sina.com

作者简介: 李伟,2020年6月于怀化学院获得理学学士学位。现为贵州民族大学化学工程学院硕士研究生,在聂登攀副研究员的指导下进行研究。目前主要研究领域为气固分离陶瓷膜材料。

引用本文:

李伟, 王洪利, 刘学琰, 范智禹, 吴怡逸, 聂登攀, 陶文亮. 表面疏油Al₂O₃陶瓷膜的制备及表征[J]. 材料导报, 2024, 38(13): 22120002-6.
LI Wei, WANG Hongli, LIU Xueyan, FAN Zhiyu, WU Yiyi, NIE Dengpan, TAO Wenliang. Preparation and Characterization of Al₂O₃ Ceramic Membrane with Hydrophobic Surface. Materials Reports, 2024, 38(13): 22120002-6.

链接本文:

http://www.mater-rep.com/CN/10.11896/cldb.22120002 或 http://www.mater-rep.com/CN/Y2024/V38/I13/22120002

1 Liang D H, Huang J G, Zhang H, et al. Ceramics International, 2020, 47(8), 10464.
2 Hubadillah S, Othman M, Matsuura T, et al. Ceramics International, 2018, 44(5), 4538.
3 Micka B, Etoungh D, Martin D, et al. Journal of Membrane Science, 2018, 555(1), 88.
4 Song X Y, Jian B H, Jin J. Ceramics International, 2018, 44(16), 20361.
5 Din Z, Zainal Z. Journal of Cleaner Production, 2018, 184(20), 1.
6 Zhou Q. Coal Quality Technology, 2021, 36(1), 69 (in Chinese).
周琦. 煤质技术, 2021, 36(1), 69.
7 Liu C L, Gan X Y. Coal Processing & Comprehensive Utilization, 2016, 1(6), 51(in Chinese).
刘春雷, 甘晓雁. 煤炭加工与综合利用, 2016, 1(6), 51.
8 Yang S Q, Du L, Li S G, et al. Clean Coal Technology, 2021, 27(1), 193(in Chinese).
杨帅强, 都林, 李松庚, 等. 洁净煤技术, 2021, 27(1), 193.
9 Sidharam P, Evan S, Martien A, et al. ACS Publications, 2012, 28(51), 17690.
10 Gao N W, Li M, Jing W H, et al. Journal of Membrane Science, 2011, 375(1-2), 276.
11 Zhou L J, Gao K, Jiao Z W, et al. Applied Surface Science, 2018, 440(15), 113.
12 Xu P, Jin Z H, Zhang T Y, et al. Industrial & Engineering Chemistry Research, 2021, 60(6), 2492.
13 Hiroki N, Takuya O, Takuya A, et al. Journal of Membrane Science, 2020, 610(1), 118210.
14 Martin S, Bharat B. Journal of Colloid and Interface Science, 2017, 488(15), 118.
15 Han L, Li X J, Li F L, et al. Journal of the Chinese Ceramic Society, 2022, 50(9), 2388(in Chinese).
韩磊, 李孝建, 李发亮, 等. 硅酸盐学报, 2022, 50(9), 2388.
16 Zhang D Y, Liu Y Z, Xie W X. Membrane Science and Technology, 2007, 1(2), 34(in Chinese).
章德玉, 刘有智, 谢五喜. 膜科学与技术, 2007, 1(2), 34.

[1]	杜金晶, 孙晔, 朱军, 李倩, 王斌, 刘景田, 孟晓荣. 五氧化二钒薄膜材料制备方法研究进展[J]. 材料导报, 2024, 38(5): 22100297-9.
[2]	王雪怡, 王智远, 余伟, 周冰鑫, 徐榕, 杨兴东, 何辉超, 贾碧. 高压辅助溶胶-凝胶法制备La掺杂TiO₂光催化剂及其可见光降解甲基橙研究[J]. 材料导报, 2024, 38(2): 22080236-5.
[3]	霍丽霞, 苟世宁, 郭芳君, 贺颖, 冯凯, 周晖, 张凯锋. 溶胶-凝胶法制备聚酰胺-酰亚胺粘结MoS₂/SiO_x固体润滑涂层及其真空摩擦学性能研究[J]. 材料导报, 2022, 36(22): 22050078-5.
[4]	贾玉娜, 梁可可, 焦秀玲, 陈代荣, 张剑, 吕毅, 赵英民. Al₂O₃-SiO₂-B₂O₃连续纤维的制备及力学性能[J]. 材料导报, 2021, 35(14): 14025-14029.
[5]	王蓝青, 钟溢健, 陈南春, 解庆林. 溶胶-凝胶法制备离子印迹聚合物及其用于选择性吸附重金属离子的综述[J]. 材料导报, 2020, 34(5): 5016-5022.
[6]	胡玉林, 李永进, 谢燕春, 阳生红, 张曰理. 掺Ni铁酸铋纳米粉的制备及光催化性能[J]. 材料导报, 2020, 34(18): 18009-18013.
[7]	胡文宇, 王笑乙, 袁欢, 刘禹彤, 陈雨, 张秋平, 张嘉羲, 罗凯怡, 李靖, 徐明. Ag沉积CuO-ZnO纳米复合材料的溶胶-凝胶合成及光催化性能研究[J]. 材料导报, 2020, 34(10): 10018-10023.
[8]	王海风, 王若轩, 董云谷, 刘鑫. 溶胶-凝胶法制备Euⁿ⁺_x∶SiO₂薄膜及其性能研究[J]. 材料导报, 2019, 33(Z2): 165-168.
[9]	杨立, 汪鹏生, 张浩, 王丰, 杨雄刚, 冯江涛, 华堃池, 胡永成. 生物活性玻璃骨材料力学性能及成骨作用改性的研究进展[J]. 材料导报, 2019, 33(Z2): 553-558.
[10]	占昌朝, 曹小华, 金文雄, 叶志刚, 谢宝华, 徐建兴, 周荣辉. 以水杨酸为模板分子的Nd掺杂分子印迹TiO₂的制备及光催化性能[J]. 材料导报, 2019, 33(6): 947-953.
[11]	周亚,李萍,左迎峰,袁光明,李贤军,吴义强. 无机质增强木材研究进展与发展趋势[J]. 材料导报, 2019, 33(17): 2989-2996.
[12]	张化福,沙浩,吴志明,蒋亚东,王操,孙艳,景强. 太赫兹波段二氧化钒薄膜的研究进展[J]. 材料导报, 2019, 33(15): 2513-2523.
[13]	山世浩, 王庆国, 曲兆明, 成伟, 李昂. 二氧化钒薄膜材料相变临界场强调控方法研究[J]. 材料导报, 2018, 32(6): 870-873.
[14]	许连强,唐志雄,唐少龙,都有为. 新型溶胶-凝胶法制备CoPd合金纳米颗粒及其磁性能表征[J]. 《材料导报》期刊社, 2018, 32(10): 1587-1591.
[15]	郭思彤,吴会军,杨丽修,刘燕妮,杨建明. 制备参数对SiO2气凝胶结构与性能影响的研究进展*[J]. 《材料导报》期刊社, 2017, 31(7): 38-44.

[1]	Huanchun WU, Fei XUE, Chengtao LI, Kewei FANG, Bin YANG, Xiping SONG. Fatigue Crack Initiation Behaviors of Nuclear Power Plant Main Pipe Stainless Steel in Water with High Temperature and High Pressure[J]. Materials Reports, 2018, 32(3): 373 -377 .
[2]	Miaomiao ZHANG,Xuyan LIU,Wei QIAN. Research Development of Polypyrrole Electrode Materials in Supercapacitors[J]. Materials Reports, 2018, 32(3): 378 -383 .
[3]	Congshuo ZHAO,Zhiguo XING,Haidou WANG,Guolu LI,Zhe LIU. Advances in Laser Cladding on the Surface of Iron Carbon Alloy Matrix[J]. Materials Reports, 2018, 32(3): 418 -426 .
[4]	Huaibin DONG,Changqing LI,Xiahui ZOU. Research Progress of Orientation and Alignment of Carbon Nanotubes in Polymer Implemented by Applying Electric Field[J]. Materials Reports, 2018, 32(3): 427 -433 .
[5]	Xiaoyu ZHANG,Min XU,Shengzhu CAO. Research Progress on Interfacial Modification of Diamond/Copper Composites with High Thermal Conductivity[J]. Materials Reports, 2018, 32(3): 443 -452 .
[6]	Anmin LI,Junzuo SHI,Mingkuan XIE. Research Progress on Mechanical Properties of High Entropy Alloys[J]. Materials Reports, 2018, 32(3): 461 -466 .
[7]	Qingqing DING,Qian YU,Jixue LI,Ze ZHANG. Research Progresses of Rhenium Effect in Nickel Based Superalloys[J]. Materials Reports, 2018, 32(1): 110 -115 .
[8]	Yaxiong GUO,Qibin LIU,Xiaojuan SHANG,Peng XU,Fang ZHOU. Structure and Phase Transition in CoCrFeNi-M High-entropy Alloys Systems[J]. Materials Reports, 2018, 32(1): 122 -127 .
[9]	Changsai LIU,Yujiang WANG,Zhongqi SHENG,Shicheng WEI,Yi LIANG,Yuebin LI,Bo WANG. State-of-arts and Perspectives of Crankshaft Repair and Remanufacture[J]. Materials Reports, 2018, 32(1): 141 -148 .
[10]	Xia WANG,Liping AN,Xiaotao ZHANG,Ximing WANG. Progress in Application of Porous Materials in VOCs Adsorption During Wood Drying[J]. Materials Reports, 2018, 32(1): 93 -101 .

Viewed

Full text

Abstract

Cited

Shared

Discussed