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《材料导报》期刊社  2017, Vol. 31 Issue (7): 38-44    https://doi.org/10.11896/j.issn.1005-023X.2017.07.006
  材料综述 |
制备参数对SiO2气凝胶结构与性能影响的研究进展*
郭思彤1,吴会军1,2,杨丽修2,刘燕妮1,2,杨建明1
1 广州大学土木工程学院,广州510006;
2 广州大学广东省建筑节能及应用技术重点实验室,广州510006
Influence of Preparation Parameters on Structure and Performance of Silica Aerogel: A Review
GUO Sitong1, WU Huijun1,2, YANG Lixiu2, LIU Yanni1,2, YANG Jianming1
1 School of Civil Engineering, Guangzhou University, Guangzhou 510006;
2 Guangdong Key Laboratory of Building Efficiency and Application Techniques, Guangzhou University, Guangzhou 510006
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摘要 SiO2气凝胶是具有优异性能的新型多孔纳米材料,是国内外热学、光学、声学及电学等学科的研究和发展热点。SiO2气凝胶的制备包括凝胶形成、凝胶老化及后处理3个阶段,其结构和性能与制备参数有关。对3个阶段制备参数的影响规律进行了综述。针对凝胶形成阶段,从硅源种类、化学配比、pH值、反应温度及水解时间5个参数进行概述;针对凝胶老化阶段,从老化温度与时间两个参数进行概述;针对后处理阶段,从干燥剂种类、改性剂种类和浓度及改性温度与时间5个参数进行概述。通过进一步探索制备参数对SiO2气凝胶结构与性能影响的规律,不断优化生产制备工艺,对推动SiO2气凝胶规模化生产及推广应用有指导意义。
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郭思彤
吴会军
杨丽修
刘燕妮
杨建明
关键词:  气凝胶  制备  影响因素  溶胶-凝胶法    
Abstract: Silica aerogels are a new type of nanoporous materials with excellent properties. It has been the hot spot of research and development in thermal, optical, acoustic and electrical and other disciplines at home and abroad. The preparation of silica aerogels can be divided into three general steps: gel preparation, aging of the gel and post-processing. Its structure and properties are associated with the preparation parameters. In this paper, the influence of preparation parameters on structure and performance of silica aerogel are reviewed. For the gel preparation, the silicon source type, sol proportion, pH value, reaction temperature and hydrolysis time are summarized. For aging of the gel, aging temperature and time are summarized. For post-processing, drying solvent species, modifier types and concentrations, modified temperature and time are summarized. Through exploring the preparation parameters which affect structure and performance of silica aerogels, and constantly optimizing the preparation technology, it will have great guiding significance for promoting scale production and applications of silica aerogels.
Key words:  aerogels    preparation    factors    sol-gel method
               出版日期:  2017-04-10      发布日期:  2018-05-08
ZTFLH:  TQ127.2  
  TB383.1  
基金资助: *广东省自然科学杰出青年基金(S2013050014139);广州市羊城学者科研项目(1201561560)
通讯作者:  吴会军,男,1978年生,博士,研究员,主要从事新型纳米多孔材料新技术方面的研究E-mail:wuhuijun@tsinghua.org.cn   
作者简介:  郭思彤:女,1992年生,硕士研究生,主要从事新型纳米多孔材料方面的研究E-mail:1003305263@qq.com
引用本文:    
郭思彤,吴会军,杨丽修,刘燕妮,杨建明. 制备参数对SiO2气凝胶结构与性能影响的研究进展*[J]. 《材料导报》期刊社, 2017, 31(7): 38-44.
GUO Sitong, WU Huijun, YANG Lixiu, LIU Yanni, YANG Jianming. Influence of Preparation Parameters on Structure and Performance of Silica Aerogel: A Review. Materials Reports, 2017, 31(7): 38-44.
链接本文:  
http://www.mater-rep.com/CN/10.11896/j.issn.1005-023X.2017.07.006  或          http://www.mater-rep.com/CN/Y2017/V31/I7/38
1 Liao Y,Wu H,Ding Y,et al. Engineering thermal and mechanical properties of flexible fiber-reinforced aerogel composites[J]. J Sol-Gel Sci Technol,2012,63(3):445.
2 Pierre A C,Rigacci A. SiO2 aerogels,in aerogels handbook [M].New York:Springer,2011.
3 Wu H,Chen Y,Chen Q,et al. Synthesis of flexible aerogel compo-sites reinforced with electrospun nanofibers and microparticles for thermal insulation[J]. J Nanomater,2013,2013(1-2):1.
4 Gurav J L,Jung I K,Park H H,et al. Silica aerogel:Synthesis and applications[J]. J Nanomater,2010,2010(24):139.
5 Rao A P,Rao A V,Pajonk G M. Hydrophobic and physical properties of the ambient pressure dried silica aerogels with sodium silicate precursor using various surface modification agents[J]. Appl Surf Sci,2007,253(14):6032.
6 Yang L,Wu H,Chen Q,et al. Effects of preparation parameters on SiO2 aerogels by single-factor and orthogonal experiments[J]. Mater Res Innovat,2015,19(S2):S2-90.
7 Baetens R,Jelle B P,Gustavsen A. Aerogel insulation for building applications: A state-of-the-art review[J]. Energ Build,2011,43(4):761.
8 Yang J, Wu H,He S,et al. Prediction of thermal conductivity of fiber/aerogel composites for optimal thermal insulation [J]. J Porous Media,2015,18(10):971.
9 Shen Jun,Lian Ya,Zu Guoqing,et al. Aerogel low-cost preparation and its application in the field of building insulation [J]. J Funct Mater,2015,46(7):8(in Chinese).
沈军,连娅,祖国庆,等.气凝胶低成本制备及其在建筑保温领域中的应用[J]. 功能材料,2015,46(7):8.
10 Randall J P,Meador M A,Jana S C. Tailoring mechanical properties of aerogels for aerospace applications [J]. ACS Appl Mater Interface,2011,3(3):613.
11 Woignier T,Phalippou J. Mechanical strength of silica aerogels[J]. J Non-Crystalline Solids,1988,100(1):404.
12 Lu H,Luo H,Leventis N. Mechanical characterization of aerogels[M]. New York: Springer,2011.
13 Obrey K A D,Wilson K V,Loy D A. Enhancing mechanical properties of silica aerogels[J]. J Non-Crystalline Solids,2011,357(19-20):3435.
14 Venkateswara Rao A,Kalesh R R. Comparative studies of the physical and hydrophobic properties of TEOS based silica aerogels using different co-precursors[J]. Sci Technol Adv Mater,2003,4(6):509.
15 Matias T,Varino C,Sousa H C D,et al. Novel flexible, hybrid aerogels with vinyl- and methyltrimethoxysilane in the underlying silica structure[J]. J Mater Sci,2016,51(14):6781.
16 Deng Z,Wang J,Wei J,et al. Physical properties of silica aerogels prepared with polyethoxydisiloxanes[J]. J Sol-Gel Sci Technol,2000,19(1):677.
17 Chao X,Shen J,Zhou B. Ultralow density silica aerogels prepared with PEDS[J]. J Non-Crystalline Solids,2009,355(8):492.
18 Chen Yimin,Xie Kai,Hong Xiaobin,et al. Preparation of hydrophobic SiO2 aerogel from self-hydrophobic sol-gel system[J]. J Chinese Ceram Soc,2005,33(9):1149(in Chinese).
陈一民,谢凯,洪晓斌,等.自疏水溶胶-凝胶体系制备疏水SiO2气凝胶[J]. 硅酸盐学报,2005,33(9):1149.
19 Rajanna S K,Vinjamur M,Mukhopadhyay M. Mechanism for formation of hollow and granular silica aerogel microspheres from rice husk ash for drug delivery[J]. J Non-Crystalline Solids,2015,429:226.
20 Nayak J P,Bera J. Preparation of silica aerogel by ambient pressure drying process using rice husk ash as raw material[J]. Trans-Indian Ceram Soc,2015,68(2):91.
21 Wong J C H,Kaymak H,Brunner S,et al. Mechanical properties of monolithic silica aerogels made from polyethoxydisiloxanes[J]. Microp Mesop Mater,2014,183(1):23.
22 Du M,Mao N,Russell S J. Control of porous structure in flexible si-licone aerogels produced from methyltrimethoxysilane (MTMS): The effect of precursor concentration in sol-gel solutions[J]. J Mater Sci,2015,51(2):719.
23 Mahadik D B,Rao A V,Kumar R,et al. Reduction of processing time by mechanical shaking of the ambient pressure dried TEOS based si-lica aerogel granules[J]. J Porous Mater,2012,19(1):87.
24 Rao A V,Kalesh R R,Pajonk G M. Hydrophobicity and physical properties of TEOS based silica aerogels using phenyltriethoxysilane as a synthesis component[J]. J Mater Sci,2003,38(21):4407.
25 Zheng Wenzhi. The preparation of silica aerogels and their structures and properties[D]. Guangzhou:South China University of Technology,2010(in Chinese).
郑文芝.二氧化硅气凝胶研制及其结构性能研究[D]. 广州:华南理工大学,2010.
26 Wormeyer K,Alnaief M,Smirnova I. Amino functionalised silica-ae-rogels for CO2-adsorption at low partial pressure[J]. Adsorption,2012,18(3-4):163.
27 Ou D,Stepanian C J,Hu X. Silica/polymer and silica/polymer/fiber composite aerogels [J]. Nasa Tech Briefs,2010,8:40.
28 Alnaief M,Smirnova I. Effect of surface functionalization of silica aerogel on their adsorptive and release properties[J]. J Non-Crystalline Solids,2010,356(33-34):1644.
29 Wu Yadi,Cui Sheng,Han Guifang,et al. Study on preparation of hydrophobic silica aerogels[J]. J Mater Eng,2010(6):16(in Chinese).
吴亚迪,崔升,韩桂芳,等. 疏水SiO2气凝胶的制备研究[J]. 材料工程,2010(6):16.
30 Soleimani Dorcheh A,Abbasi M H. Silica aerogel;synthesis,properties and characterization[J].J Mater Process Technol,2008,199(1-3):10.
31 Wu Huijun,Hu Huanyi,Chen Qiliang,et al. Preparation of low density hydrophobic silica aerogels by controlling strength of alcogels[J]. CIESC J,2015,66(10):4281(in Chinese).
吴会军,胡焕仪,陈奇良,等.通过控制醇凝胶强度常压制备低密度疏水SiO2气凝胶[J].化工学报,2015,66(10):4281.
32 Sink K. Influence of chemical conditions on the nanoporous structure of silicate aerogels[J]. Materials,2010,3(1):704.
33 Karakuzu B,Temel T M,et al. Effect of acid type and gelation pH on the structural properties of silica aerogels prepared by use of rice hull biosilica[J]. Sigma J Eng Nat Sci,2016,34(2):175.
34 Stolarski M,Walendziewski J,Steininger M,et al. Synthesis and characteristic of silica aerogels[J]. Appl Catal A,1999,177(2):139.
35 Zhao Dafang,Chen Yimin,Hong Xiaobin,et al. Preparation of hydrophobic SiO2 aerogel at lower cost[J]. J Chinese Ceram Soc,2004,32(5):548(in Chinese).
赵大方,陈一民,洪晓斌,等.疏水SiO2气凝胶的低成本制备[J]. 硅酸盐学报,2004,32(5):548.
36 Zhang Yi,Cao Jianxin,Nie Dengpan,et al. Effect of preparation condition on pore structure of SiO2-aerogel[J]. Rare Metal Mater Eng,2009,38(S2):350.
张煜,曹建新,聂登攀,等.制备条件对SiO2气凝胶孔结构的影响[J]. 稀有金属材料与工程,2009,38(增刊2):350.
37 Hegde N D,Rao A V. Effect of processing temperature on gelation and physical properties of low density teos based silica aerogels[J]. J Sol-Gel Sci Technol,2006,38(38):55.
38 Yu J,Zhao L,Cheng B. Preparation of monodispersed microporous SiO2 microspheres with high specific surface area using dodecylamine as a hydrolysis catalyst[J]. J Solid State Chem,2006,179(1):226.
39 Luo Fengzuan,Wu Guoyou,Shao Zaidong,et al. Effects of preparation conitions on hydrophobic silica aerogels via ambient pressure drying[J]. J Mater Eng,2012(3):32(in Chinese).
罗凤钻,吴国友,邵再东,等.常压干燥制备疏水SiO2气凝胶的影响因素分析[J]. 材料工程,2012(3):32.
40 Smitha S,Shajesh P,Kumar S R,et al. Effect of aging temperature on the porosity characteristics of subcritically dried silica aerogels[J]. J Porous Mater,2007,14(1):1.
41 Hu Huanyi. Study on rapid preparation and control method of silica aerogels for thermal insulations[D]. Guangzhou:Guangzhou University,2015(in Chinese).
胡焕仪. SiO2气凝胶绝热材料的快速制备及控制方法研究[D]. 广州:广州大学,2015.
42 Lv Pengpeng,Zhao Hailei,et al. Preparation of silica aerogel via ambient pressure drying[J]. J Mater Eng,2012(4):22(in Chinese).
吕鹏鹏,赵海雷,刘欣,等.常压干燥制备SiO2气凝胶的研究[J]. 材料工程,2012(4):22.
43 Smitha S,Shajesh P,Aravind P R,et al. Effect of aging time and concentration of aging solution on the porosity characteristics of subcritically dried silica aerogels[J]. Microp Mesop Mater,2006,91(1-3):286.
44 Omranpour H,Motahari S. Effects of processing conditions on silica aerogel during aging:Role of solvent,time and temperature[J]. J Non-Crystalline Solids,2013,379(4):7.
45 Sarawade P B,Kim J K,Hilonga A,et al. Influence of aging conditions on textural properties of water-glass-based silica aerogels prepared at ambient pressure[J]. Korean J Chem Eng,2010,27(4):1301.
46 Lee C J,Kim G S,Hyun S H. Synthesis of silica aerogels from waterglass via new modified ambient drying[J]. J Mater Sci,2002,37(11):2237.
47 Chang Jiaojiao. Study on process and properties of low density silica aerogels prepared by one-step and two-step method[D]. Xi’an:Chang’an University,2013(in Chinese).
常姣姣.一步法和两步法制备低密度SiO2气凝胶工艺与性能研究[D].西安:长安大学,2013.
48 Rao A V,Nilsen E,Einarsrud M A. Effect of precursors, methylation agents and solvents on the physicochemical properties of silica aerogels prepared by atmospheric pressure drying method[J]. J Non-Crystalline Solids,2001,296(3):165.
49 Lu Bin,Zhou Qiang,Song Miao,et al. Influence of drying solvents on silica aerogels at ambient pressure[J]. J Central South University:Sci Technol,2012,43(7):2560(in Chinese).
卢斌,周强,宋淼,等. 干燥溶剂介质对常压制备SiO2气凝胶的影响[J]. 中南大学学报:自然科学版,2012,43(7):2560.
50 Rao A P,Rao A V. Microstructural and physical properties of the ambient pressure dried hydrophobic silica aerogels with various solvent mixtures[J]. J Non-Crystalline Solids,2008,354(1):10.
51 Liu J X,Shi F,Bai L N,et al. Synthesis of TiO2-SiO2 aerogel via ambient pressure drying: Effects of sol pre-modification on the microstructure and pore characteristics[J]. J Sol-Gel Sci Technol,2014,69(1):93.
52 Rao A P,Rao A V. Modifying the surface energy and hydrophobicity of the low-density silica aerogels through the use of combinations of surface-modification agents[J]. J Mater Sci,2010,45(1):51.
53 Deng Lingfeng,Zuo Xiaorong,Lu Bin,et al. Effection of surface modification of silica aerogels with mixed modifier(TMCS/HMDSO)at ambient pressure[J]. Mater Rev:Rev,2013,27(2):75(in Chinese).
邓凌峰,左小荣,卢斌,等. TMCS/HMDSO混合改性剂对常压制备SiO2气凝胶的影响[J]. 材料导报:研究篇,2013,27(2):75.
54 Zhang G,Dass A,Rawashdeh A M M,et al. Isocyanate-crosslinked silica aerogel monoliths: Preparation and characterization[J]. J Non-Crystalline Solids,2004,350(8):152.
55 Meador M A B,Scherzer C M,Vivod S L,et al. Epoxy reinforced aerogels made using a streamlined process[J]. ACS Appl Mater Interface,2010,2(7):2162.
56 Maleki H,Dur E L,Portugal A. Synthesis of lightweight polymer-reinforced silica aerogels with improved mechanical and thermal insulation properties for space applications[J]. Microp Mesop Mater,2014,197(197):116.
57 Yang H,Kong X,Zhang Y,et al. Mechanical properties of polymer-modified silica aerogels dried under ambient pressure[J]. J Non-Crystalline Solids,2011,357(19):3447.
58 Cao Qi, Wu Qingren,Wu Qijian,et al. Effect of hydrophobic modifying on the properties and structure of silica aerogel films[J]. Mater Res:Res,2011,25(5):92(in Chinese).
曹旗,吴清仁,吴启坚,等.疏水改性对SiO2气凝胶薄膜性能与结构的影响[J]. 材料导报:研究篇,2011,25(5):92.
59 Mahadik D,Rao A V,Rao A P,et al. Effect of concentration of tri-methylchlorosilane (TMCS) and hexamethyldisilazane (HMDZ) silylating agents on surface free energy of silica aerogels[J]. J Colloid Interface Sci,2011,356(1):298.
60 Yang Kai,Pang Jiawei,Wu Borong,et al. Methods of modification of SiO2 aerogels [J]. Trans Beijing Institute Technol,2009,29(9):833(in Chinese).
杨凯,庞佳伟,吴伯荣,等. 二氧化硅气凝胶改性方法及研究进展[J]. 北京理工大学学报,2009,29(9):833.
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