Abstract: Because of its unique laminar structure, MoS2, which is a member of the transition metal dichalcogenides, exhibits excellent tribological pro-perties. MoS2 plays a major role as a self-lubricating coating in the surface wear reduction and protection of tools and space component materials. However, the sensitivity of MoS2 coatings to moisture, as well as its poor adhesion and wear life, limit its application. Considerable tribological research of MoS2 coatings has been conducted globally, and current research has focused on analyzing tribological behavior in multiple environments under different temperatures, humidity, and gaseous media. The design of nanomultilayer systems to achieve controllable crystal structures has also been a topic of study. In this paper, the research progress on MoS2 self-lubricating coating materials since 2010 is outlined. We primarily review the tribological properties of MoS2 self-lubricating coatings and the effects of different elemental dopings on the properties and structures. The compositions of structures, their properties, and the preparation of MoS2 coatings are summarized, and the research prospects and applications for surface lubrication are discussed. This paper can be a significant reference for the research and engineering applications of MoS2 self-lubricating coatings.
通讯作者:
李伟,上海理工大学材料与化学学院教授、博士研究生导师。2008年上海交通大学材料物理与化学专业博士毕业后到上海理工大学工作至今。目前从事纳米结构功能薄膜材料、生物医用材料、高熵合金材料、PVD技术及其应用方面的研究。发表学术论文80余篇,以第一作者/通信作者在Materials Research Letters、Scripta Materialia、Materials and Design等SCI收录期刊发表论文共42篇。liwei176@usst.edu.cn
于凯, 王静静, 刘平, 马迅, 张柯, 马凤仓, 李伟. 二硫化钼自润滑涂层性能及制备工艺的研究进展[J]. 材料导报, 2024, 38(7): 22080088-10.
YU Kai, WANG Jingjing, LIU Ping, MA Xun, ZHANG Ke, MA Fengcang, LI Wei. Review of the Performance and Preparation of Molybdenum Disulfide Self-lubricating Coatings. Materials Reports, 2024, 38(7): 22080088-10.
1 Sun R L, Sun S W, Guo L X, et al. Aerospace Materials & Technology, 1999(1), 17 (in Chinese). 孙荣禄, 孙树文, 郭立新, 等. 宇航材料工艺, 1999(1), 17. 2 Martin J, Donnet C, Le-Mogne T, et al. Physical Review B, Condensed Matter, 1993, 48, 207. 3 Hilton M R, Fleischauer P D. Surface and Coatings Technology, 1992, 54-55, 435. 4 Voumard P, Savan A, Pflüger E. Lubrication Science, 2001, 13(2), 135. 5 Wang G P, Li N G. Infrared, 2005(10), 33 (in Chinese). 王桂平, 李宁刚. 红外, 2005(10), 33. 6 Lansdown A R. Tribology International, 1999, 33(2), 148. 7 Xu Y, Xie M, Li Y, et al. Surface and Coatings Technology, 2020, 403, 126362. 8 Singh H, Mutyala K C, Evans R D, et al. Surface and Coatings Techno-logy, 2015, 284, 281. 9 Lu X, Yan M, Yan Z, et al. Tribology International, 2021, 156, 106844. 10 Tian P P, Niu Z W, Liu K F, et al. Plating & Finishing, 2021, 43(10), 14 (in Chinese). 田佩佩, 牛宗伟, 刘可峰, 等. 电镀与精饰, 2021, 43(10), 14. 11 Yuan J, Zhu Y, Zheng X, et al. Journal of Alloys and Compounds, 2011, 509(5), 2576. 12 Dickinson R G, Pauling L. Journal of the American Chemical Society, 1923, 45(6), 1466. 13 Buck V. Wear, 1987, 114(3), 263. 14 Xu J, Zhou Z R, Zhang C H, et al. Journal of Materials Processing Technology, 2007, 182(1), 146. 15 Liu C, Chen L, Zhou J, et al. Applied Surface Science, 2014, 300, 111. 16 Shi L, Sun C, Liu W. Applied Surface Science, 2008, 254(21), 6880. 17 Savan A, Pflüger E, Voumard P, et al. Lubrication Science, 2000, 12(2), 185. 18 Qin X, Ke P, Wang A, et al. Surface and Coatings Technology, 2013, 228, 275. 19 Li Y, Xie M, Sun Q, et al. Surface and Coatings Technology, 2019, 378, 125081. 20 Serpini E, Rota A, Ballestrazzi A, et al. Surface and Coatings Technology, 2017, 319, 345. 21 Meng F, Yang C, Han H. Proceedings of the Institution of Mechanical Engineers Part J: Journal of Engineering Tribology, 2018, 232(8), 964. 22 Wang X, Wang T, Ye M, et al. Diamond and Related Materials, 2019, 98, 107471. 23 Fleischauer P D. ASLE Transactions, 1984, 27(1), 82. 24 Muratore C, Voevodin A A. Thin Solid Films, 2009, 517(19), 5605. 25 Kong N, Wei B, Li D, et al. RSC Advances, 2020, 10(16), 9633. 26 Khare H S, Burris D L. Tribology Letters, 2013, 53(1), 1. 27 Li L, Lu Z, Pu J, et al. Ceramics International, 2020, 46(5), 5733. 28 Li H, Li X, Zhang G, et al. Tribology Letters, 2017, 65(2), 38. 29 Ju P F, Wang H X, Pu J B, et al. Chinese Journal of Vacuum Science and Technology, 2018, 38(10), 901 (in Chinese). 鞠鹏飞, 王海新, 蒲吉斌, 等. 真空科学与技术学报, 2018, 38(10), 901. 30 Cao M, Zhao L, Wu L, et al. Coatings, 2018, 8, 134. 31 Lu C, Jia J, Fu Y, et al. Surface and Coatings Technology, 2019, 378, 125072. 32 Zhang X, Qiao L, Chai L, et al. Surface and Coatings Technology, 2016, 296, 185. 33 Wu Y, Liu Y, Yu S, et al. Tribology Letters, 2016, 64(2), 24. 34 Grosseau-Poussard J L, Moine P, Brendle M. Thin Solid Films, 1997, 307(1), 163. 35 Neuville S. Surface and Coatings Technology, 2011, 206(4), 703. 36 Li H, Xie M, Zhang G, et al. Applied Surface Science, 2018, 435, 48. 37 Wu Y, Li H, Li J, et al. Tribology Letters, 2013, 52(3), 371. 38 Song W, Deng J, Yan P, et al. Journal of Wuhan University of Technology(Materials Science Edition), 2011, 26(3), 5. 39 Han C, Li G, Ma G, et al. Surface and Coatings Technology, 2021, 405, 126625. 40 Song G H, Du H, He C L. Hard and superhard coatings——structure, properties, preparation and characterization, Chemical Industry Press, China, 2011, pp. 24 (in Chinese). 宋贵宏, 杜昊, 贺春林. 硬质与超硬涂层——结构、性能、制备与表征, 化学工业出版社, 2011, pp. 24. 41 Zhang C, Yang B, Wang J, et al. Surface and Coatings Technology, 2019, 359, 334. 42 He Y D, Qi H B. Introduction to corrosion and protection of materials, China Machine Press, China, 2005, pp. 218 (in Chinese). 何业东, 齐慧滨. 材料腐蚀与防护概论, 机械工业出版社, 2005, pp.218. 43 Wang Z P, Lu P C, Sun Z. Welding Technology, 2012, 41(7), 7 (in Chinese). 王志平, 路鹏程, 孙振. 焊接技术, 2012, 41(7), 7. 44 Satyavathi Yedida V V, Vasudev H. Materials Today, Proceedings, 2022, 50, 1458. 45 Xu H Y, Zhou H D, Chen J M, et al. Materials for Mechanical Enginee-ring, 2005(3), 35 (in Chinese). 徐海燕, 周惠娣, 陈建敏, 等. 机械工程材料, 2005(3), 35. 46 Deng W, Zhao X, An Y, et al. Tribology International, 2018, 128, 260. 47 Liu Q, Wang Y, Bai Y, et al. Surface and Coatings Technology, 2021, 421, 127383. 48 Wang Q, Li X, Niu W, et al. Surface and Coatings Technology, 2020, 391, 125699. 49 Darolia R. International Materials Reviews, 2013, 58(6), 315. 50 Luo J, Wang Y D, Cai Z B, et al. Journal of Mechanical Engineering, 2012, 48(17), 100 (in Chinese). 罗军, 王运动, 蔡振兵, 等. 机械工程学报, 2012, 48(17), 100. 51 Zhu M H, Zhou H D, Chen J M, et al. Tribology, 2002(1), 14 (in Chinese). 朱旻昊, 周惠娣, 陈建敏, 等. 摩擦学报, 2002(1), 14. 52 Li B, Jiang X, Wu Y, et al. Progress in Organic Coatings (Elsevier), 2019, 132, 211. 53 Cao T K, Yang Q L, Shan C S. Lubrication Engineering, 2012, 37(11), 55 (in Chinese). 曹同坤, 杨岐龙, 单春生. 润滑与密封, 2012, 37(11), 55. 54 Zhang M Y. Microstructure optimization and tribological properties of Ni-SiC-MoS2 composite coating on aluminum alloy. Master’s Thesis, Chang’an University, China, 2020 (in Chinese). 张梦瑶. 铝合金表面Ni-SiC-MoS2复合镀层的组织优化和摩擦学性能研究. 硕士学位论文, 长安大学, 2020. 55 Pinate S, Leisner P, Zanella C. Surface and Coatings Technology, 2021, 421, 127400. 56 Xie Q Q, Zhou Y, Liu J Q, et al. Electroplating & Finishing, 2015, 34(23), 1329 (in Chinese). 谢强强, 周银, 刘家强, 等. 电镀与涂饰, 2015, 34(23), 1329. 57 Du S, Li Z, He Z, et al. Tribology International, 2018, 128, 197. 58 Wang J Z, Jiang S W, Song S, et al. Journal of Alloys and Compounds, 2019, 786, 594. 59 Li Z, Wang J, Lu J, et al. Applied Surface Science, 2013, 264, 516. 60 Zou T Z, Tu J P, Zhang S C, et al. Materials Science and Engineering, A, 2006, 426(1), 162. 61 Zhou H, Zheng J, Wen Q P, et al. Physics Procedia, 2011, 18, 234. 62 Su Y L, Kao W H. Tribology International, 2003, 36(1), 11. 63 Ding X Z, Zeng X T, He X Y, et al. Surface and Coatings Technology, 2010, 205(1), 224. 64 Gao K, Wang Y, Zhang B, et al. Tribology International, 2022, 170, 107499. 65 Hebbar Kannur K, Yaqub T B, Huminiuc T, et al. Applied Surface Science, 2020, 527, 146790. 66 Hebbar Kannur K, Huminiuc T, Yaqub T B, et al. Surface and Coatings Technology, 2021, 408, 126791. 67 Hudec T, Roch T, Gregor M, et al. Surface and Coatings Technology, 2021, 405, 126722. 68 Sun W D, Gu X L, Yang L N, et al. Surface and Coatings Technology, 2020, 399, 126140. 69 Zhang J, Wang Y, Zhou S, et al. Tribology International, 2020, 143, 106029. 70 Ma G Z, He P F, Wang Y W, et al. Proceedings of the Institution of Mechanical Engineers, Part J: Journal of Engineering Tribology, 2019, 233(8), 1236. 71 Ren S, Shang K, Cui M, et al. Journal of Materials Science, 2019, 54(18), 11889.