改性MCrAlY涂层的研究进展

doi:10.11896/cldb.22120155

材料导报

2024, Vol. 38

Issue (7): 22120155-10 https://doi.org/10.11896/cldb.22120155

金属与金属基复合材料

改性MCrAlY涂层的研究进展

孙华键¹, 郭德林¹, 李如庆¹, 侯良朋¹, 杨明辉², 孙金钊^1,*, 殷凤仕^1,*

1 山东理工大学机械工程学院,山东淄博 255000
2 山东理工大学化学化工学院,山东淄博 255000

Research Status of Modified MCrAlY Coatings

SUN Huajian¹, GUO Delin¹, LI Ruqing¹, HOU Liangpeng¹, YANG Minghui², SUN Jinzhao^1,*, YIN Fengshi^1,*

1 School of Mechanical Engineering, Shandong University of Technology, Zibo 255000, Shandong, China
2 School of Chemistry and Chemical Engineering, Shandong University of Technology, Zibo 255000, Shandong,China

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摘要热防护涂层可以有效阻止高温、高压、高速等严苛环境造成的高温氧化、疲劳失效等问题,被广泛用于航空发动机与燃气轮机热端部件的热防护。在热防护涂层体系中,MCrAlY(M代表Co、Ni或两者的组合)涂层作为抗氧化、抗热腐蚀覆盖层以及热障涂层系统中的粘结层,以其优异的抗热腐蚀性能及灵活的选择性得到广泛应用。为进一步提高MCrAlY涂层热稳定性及延长其使用寿命,满足使用温度超过1 000 ℃的要求,众多制备与改性方法应运而生。为进一步拓展MCrAlY涂层的应用,本文系统总结了MCrAlY涂层的发展历程及制备方法,重点梳理了掺杂元素、氧化物分散强化、纳米涂层、真空热处理、激光表面处理及梯度结构设计等改性方法,并在此基础上对MCrAlY涂层的未来发展方向进行了展望。

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	孙金钊
	殷凤仕

关键词: MCrAlY 制备技术改善方法微观组织抗高温氧化性

Abstract: Thermally protective coatings can effectively prevent fatigue failure caused by high-temperature oxidation and harsh environments such as high temperature, high pressure and high speed, and are widely used for thermal protection of aero-engine and gas turbine hot end components. Among the thermal protection coating systems, MCrAlY coatings are widely used as antioxidant and thermal corrosion-resistant cover layers as well as binder layers for thermal barrier coating systems due to their excellent thermal corrosion resistance and flexible selectivity. To further improve the thermal stability and service life of MCrAlY coatings to meet the requirements of operating temperatures above 1 000 ℃, several preparation and modification methods have emerged. They mainly include vacuum pretreatment, nano-coating, elemental doping, oxide dispersion strengthening, laser surface treatment, gradient coating, etc. These modifications are used to improve the structural refinement, grain boundary purification and adhesion of Al₂O₃ oxides, thereby increasing the thermally stable behaviour and service life of MCrAlY coatings. There are many ways to improve MCrAlY coatings, but they are not systematically summarised and presented. Based on this. This paper clarifies the application of MCrAlY coatings and the current standard preparation methods, focuses on sorting out the ways to improve the performance of MCrAlY coa-tings, introduces their advantages and disadvantages, and provides a reference basis for further expanding the application of MCrAlY coatings.

Key words: MCrAlY preparation technology improvement method microstructure high-temperature oxidation resistance

出版日期: 2024-04-10 发布日期: 2024-04-11

ZTFLH:

TG174.4

基金资助: 山东自然科学基金(ZR20191112010)

通讯作者: 孙金钊,山东理工大学机械工程学院材控系讲师、硕士研究生导师,2018年西北工业大学材料加工工程博士毕业后到山东理工大学工作至今。目前主要从事移动式增材修复与再制造、热障涂层方面研究。发表论文10余篇,包括MSEA、JAC、AME。nwpusjz@163.com
殷凤仕,山东理工大学机械工程学院教授,硕士/博士研究生导师,中国科学院金属研究所材料科学与工程专业博士,韩国科学技术研究院和爱尔兰利默瑞克大学访问学者。主要从事航空、航天、舰船以及超超临界(USC)火电机组用高性能金属材料及其构(零)件表面增材和再制造技术研究,发表SCI、EI收录论文40余篇,获得授权发明专利12项。fsyin@sdut.edu.cn

作者简介: 孙华键,2021年毕业于潍坊学院,获得学士学位,现为山东理工大学硕士研究生。在孙金钊讲师、殷凤仕教授的指导下进行研究,目前主要研究领域为高温防护涂层。

引用本文:

孙华键, 郭德林, 李如庆, 侯良朋, 杨明辉, 孙金钊, 殷凤仕. 改性MCrAlY涂层的研究进展[J]. 材料导报, 2024, 38(7): 22120155-10.
SUN Huajian, GUO Delin, LI Ruqing, HOU Liangpeng, YANG Minghui, SUN Jinzhao, YIN Fengshi. Research Status of Modified MCrAlY Coatings. Materials Reports, 2024, 38(7): 22120155-10.

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https://www.mater-rep.com/CN/10.11896/cldb.22120155 或 https://www.mater-rep.com/CN/Y2024/V38/I7/22120155

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