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材料导报  2024, Vol. 38 Issue (17): 23030026-6    https://doi.org/10.11896/cldb.23030026
  金属与金属基复合材料 |
激光选区熔化CoCrMo合金的组织研究及生物应用
陶宏伟1,2, 禹庭1, 曹明轩1, 吴仲恒3, 蔡召兵4, 刘敏2, 闫星辰2,*
1 五邑大学智能制造学部,广东 江门 529000
2 广东省科学院新材料研究所,广东省现代表面工程技术重点实验室,现代材料表面工程技术国家工程实验室,广州 510650
3 广州博仕动物医院,广州 510030
4 武汉科技大学冶金装备及其控制教育部重点实验室,武汉 430081
Microstructure Study and Biological Application of Laser Selective Melting CoCrMo Alloy
TAO Hongwei1,2, YU Ting1, CAO Mingxuan1, WU Zhongheng3, CAI Zhaobing4, LIU Min2, YAN Xingchen2,*
1 Faculty of Intelligent Manufacturing, Wuyi University, Jiangmen 529000, Guangdong, China
2 National Engineering Laboratory of Modern Materials Surface Engineering Technology, Guangdong Provincial Key Laboratory of Modern Surface Engineering Technology, Institute of New Materials, Guangdong Academy of Sciences, Guangzhou 510650, China
3 Guangzhou Boshi Animal Hospital, Guangzhou 510030, China
4 Key Laboratory of Metallurgical Equipment and Control Technology, Ministry of Education, Wuhan University of Science and Technology, Wuhan 430081, China
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摘要 激光选区熔化(Selective laser melting,SLM)技术是一种可快速制备具有复杂结构件的近净成形方法,由于极高的空间制造自由度,其在个性化定制医疗中有着极为广阔的应用前景。本研究关注了激光能量密度对CoCrMo合金微观组织及成形性能的影响,从致密度、微观组织及力学强度等方面对SLM CoCrMo材料进行了体系性探究,分析了能量密度对CoCrMo合金组织及缺陷的作用机制,得到了孔隙率低(0.18%)、晶粒组织细小(0.31 μm)且力学性能优异(拉伸强度1 157 MPa、显微硬度421.53HV0.1)的CoCrMo合金成形最优参数(激光功率165 W、扫描速度1 050 mm/s)。从患者对生物型膝关节植入体的需求出发,探究了一种骨接触面具有骨小梁结构的生物型全膝关节植入体的设计方法,并对优化后的膝关节假体模型开展了大动物原位膝关节置换实验。术后影像学检查发现3D打印膝关节假体不仅可对原有患病关节部位进行精准替代,更能促进实验犬尽快恢复原本的行走姿态,无脱位和其他并发症的发生。本研究报道的个性化定制方法为临床用3D打印生物型全膝关节的置换提供了强有力的理论基础和数据支撑。
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陶宏伟
禹庭
曹明轩
吴仲恒
蔡召兵
刘敏
闫星辰
关键词:  激光选区熔化  CoCrMo合金  微观组织  力学性能  生物应用    
Abstract: Selective laser melting (SLM) technology is a near-net-shaping method that can rapidly prepare complex structural parts. Due to its high degree of freedom in spatial manufacturing, it has a very broad application prospect in personalized medical treatment. This study focuses on the effect of laser energy density (Ev) on the microstructure and formability of CoCrMo alloy, and systematically explores SLM CoCrMo alloy in terms of density, microstructure and mechanical strength. The effect of Ev on the microstructure and defects of CoCrMo alloy was analyzed. The optimal parameters (laser power=165 W, scanning speed=1 050 mm/s) were obtained with low porosity (0.18%), fine grain structures (0.31 μm) and excellent mechanical properties (tensile strength=1 157 MPa, microhardness=421.53HV0.1). Starting from the needs of patients for biological knee implants, the design method of a biological total knee implant with bone trabecular structure on the bone contact surface was explored, and in-situ knee replacement experiments in large animals were carried out. Postoperative imaging examination found that the 3D printed knee prosthesis can not only accurately replace the original diseased joint parts, but also promote the recovery of the original walking posture of the experimental dog as soon as possible, without dislocation and other complications. The successful implementation of this study provides a strong theoretical basis and data support for the clinical use of 3D printed biological total knee replacement.
Key words:  selective laser melting    CoCrMo alloy    microstructure    mechanical property    biological application
出版日期:  2024-09-10      发布日期:  2024-09-30
ZTFLH:  TG146.1  
基金资助: 广东省科学院建设国内一流研究机构行动专项资金项目(2021GDASYL-20210102005;2022GDASZH-2022010107;2022GDASZH-2022010203-003);广东省特支计划项目(2019BT02C629);广东省基础与应用基础研究基金项目(2020A1515111031;2021A1515010939);中国科协“青年人才托举工程”(YESS20210269);广州市科技计划项目(202007020008;202102020327)
通讯作者:  *闫星辰,广东省科学院新材料研究所副研究员、硕士研究生导师,激光制造研究室副主任(主持工作)。博士毕业于法国贝尔福-蒙贝利亚技术大学,2019—2020年先后在法国国家科学研究中心LERMPS实验室和爱尔兰都柏林圣三一大学从事激光3D打印材料成形的研究工作。2021年作为广东省科学院引进的高层次海外人才加入新材料研究所激光制造团队,主要从事高性能3D打印材料的设计及研发,激光成形制备技术在航空航天、医疗、能源等领域关键零部件的应用开发工作。获第七届中国科协青年人才托举工程资助,目前主持国际及地区项目6项。发表高水平论文60余篇,总引1 000余次(谷歌学术统计),H指数21;累计申请专利12件。yanxingchen@gdinm.com   
作者简介:  陶宏伟,2021年9月于萍乡学院获得工学学士学位。现为五邑大学智能制造学部硕士研究生,在闫星辰副研究员的指导下进行研究。目前主要研究领域为激光制造。
引用本文:    
陶宏伟, 禹庭, 曹明轩, 吴仲恒, 蔡召兵, 刘敏, 闫星辰. 激光选区熔化CoCrMo合金的组织研究及生物应用[J]. 材料导报, 2024, 38(17): 23030026-6.
TAO Hongwei, YU Ting, CAO Mingxuan, WU Zhongheng, CAI Zhaobing, LIU Min, YAN Xingchen. Microstructure Study and Biological Application of Laser Selective Melting CoCrMo Alloy. Materials Reports, 2024, 38(17): 23030026-6.
链接本文:  
http://www.mater-rep.com/CN/10.11896/cldb.23030026  或          http://www.mater-rep.com/CN/Y2024/V38/I17/23030026
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