L12型纳米有序相析出强化(FeNiCoCr)93Al5Ti2高熵合金

doi:10.11896/cldb.23110207

材料导报

2024, Vol. 38

Issue (22): 23110207-5 https://doi.org/10.11896/cldb.23110207

金属与金属基复合材料

L1₂型纳米有序相析出强化(FeNiCoCr)₉₃Al₅Ti₂高熵合金

王沛锦¹, 卓家乐¹, 艾桃桃^1,2,*, 董洪峰^1,2

1 陕西理工大学材料科学与工程学院,陕西汉中 723000
2 陕西理工大学矿渣综合利用环保技术国家地方联合工程实验室,陕西汉中 723000

L1₂-type Nano-ordered Precipitation Phase Reinforced (FeNiCoCr)₉₃Al₅Ti₂ High Entropy Alloy

WANG Peijin¹, ZHUO Jiale¹, AI Taotao^1,2,*, DONG Hongfeng^1,2

1 School of Materials Science and Engineering, Shaanxi University of Technology, Hanzhong 723000, Shaanxi, China
2 National & Local Joint Engineering Laboratory for Slag Comprehensive Utilization and Environmental Technology, Shaanxi University of Technology, Hanzhong 723000, Shaanxi, China

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摘要 L1₂型纳米有序相析出强化面心立方结构高熵合金有望获得理想的强度-延性平衡。受此启发,本工作采用热压成形技术制备了一种L1₂型纳米有序相析出强化的(FeNiCoCr)₉₃Al₅Ti₂高熵合金。研究发现,该合金由FCC基体相、少量富Cr相及富Fe相组成,其中基体相晶粒内析出呈圆球状L1₂型结构的Ni₃(Al,Ti)颗粒,L1₂有序析出相与基体相呈共格关系。经估算,有序相强化对高熵合金屈服强度的贡献增量达221.0 MPa,远高于共格弥散强化和模量错配强化。(FeNiCoCr)₉₃Al₅Ti₂高熵合金具有优异的压缩性能,其工程屈服强度、压缩强度和压缩应变分别为717 MPa、2 304 MPa和44%。

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	王沛锦
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关键词: 高熵合金纳米析出相微观组织力学性能

Abstract: High entropy alloys(HEAs) with face-centered cubic structure strengthened by L1₂-type nano-ordered precipitates can obtain ideal strength-ductility equilibrium. In the present study, (FeNiCoCr)₉₃Al₅Ti₂ HEA reinforced by L1₂-type nano-ordered precipitation phase was prepared by hot pressing technique. It could be found that the alloy was consisted of FCC matrix phase, a small amount of Cr-rich phase, and Fe-rich phase. Spheroidal L1₂-type structured Ni₃(Al, Ti) particles were precipitated inside the matrix grains and had a coherent relationship with the matrix phase. It was estimated that the incremental contribution of ordered strengthening to the yield strength of the alloy was 221.0 MPa, which was much higher than that of the coherent dispersion strengthening and the modulus mismatch strengthening. The (FeNiCoCr)₉₃Al₅Ti₂ HEA exhibited excellent compressive properties, as its engineered yield strength, compressive strength, and compressive strain were 717 MPa, 2 304 MPa, and 44%, respectively.

Key words: high entropy alloy nano-precipitation phase microstructure mechanical property

出版日期: 2024-11-25 发布日期: 2024-11-22

ZTFLH:

TG146

基金资助: 陕西省自然科学基础研究计划项目(2023-JC-ZD-22)

通讯作者: *艾桃桃,陕西理工大学材料科学与工程学院教授、博士研究生导师。2004年陕西科技大学无机非金属材料工程专业本科毕业,2007年陕西科技大学材料学专业硕士毕业后到陕西理工大学工作至今,2015年陕西科技大学材料物理与化学专业博士毕业。目前主要从事金属构型强韧化技术、能源催化技术等方面的研究工作。发表论文200余篇,包括《材料导报》、Chemical Engineering Journal、Fuel、Intermetallics等。aitaotao0116@126.com

作者简介: 王沛锦,2020年7月、2023年6月于陕西理工大学分别获得工学学士学位和硕士学位。研究生期间师从艾桃桃教授。目前主要研究领域为光电器件制造。

引用本文:

王沛锦, 卓家乐, 艾桃桃, 董洪峰. L1₂型纳米有序相析出强化(FeNiCoCr)₉₃Al₅Ti₂高熵合金[J]. 材料导报, 2024, 38(22): 23110207-5.
WANG Peijin, ZHUO Jiale, AI Taotao, DONG Hongfeng. L1₂-type Nano-ordered Precipitation Phase Reinforced (FeNiCoCr)₉₃Al₅Ti₂ High Entropy Alloy. Materials Reports, 2024, 38(22): 23110207-5.

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http://www.mater-rep.com/CN/10.11896/cldb.23110207 或 http://www.mater-rep.com/CN/Y2024/V38/I22/23110207

1 Yeh J W, Chen S K, Lin S J, et al. Advanced Engineering Materials, 2004, 6(5), 299.
2 Yeh J W. JOM, 2013, 65(12), 1759.
3 Biswas K, Yeh J W, Bhattacharjee P P, et al. Scripta Materialia, 2020, 188, 54.
4 Tsai K Y, Tsai M H, Yeh J W. Acta Materialia, 2013, 61(13), 4887.
5 Santodonato L J, Zhang Y, Feygenson M, et al. Nature Communications, 2015, 6(1), 5964.
6 Lei Z, Liu X, Wu Y, et al. Nature, 2018, 563(7732), 546.
7 Li D, Zhang Y. Intermetallics, 2016, 70, 24.
8 Shi P, Zhong Y, Li Y, et al. Materials Today, 2020, 41, 62.
9 Senkov O N, Wilks G B, Scott J M, et al. Intermetallics, 2011, 19(5), 698.
10 Senkov O N, Wilks G B, Miracle D B, et al. Intermetallics, 2010, 18(9), 1758.
11 Jenczyk P, Jarzabek D M, Lu Z, et al. Materials & Design, 2022, 216, 110568.
12 Pickering E J, Carruthers A W, Barron P J, et al. Entropy, 2021, 23(1), 98.
13 Zhang H, Tang H, Li W H, et al. Materials Science and Technology, 2018, 34(5), 572.
14 Muskeri S, Gwalani B, Jha S, et al. Scientific Reports, 2021, 11(1), 22715.
15 Jiang H, Han K M, Qiao D, et al. Materials Chemistry and Physics, 2017, 210, 43.
16 Huang T D, Jiang L, Zhang C, et al. Science China Technological Sciences, 2018, 61, 117.
17 Ma H, Shek C. Journal of Alloys and Compounds, 2020, 827, 154159.
18 He J Y, Liu W H, Wang H, et al. Acta Materialia, 2014, 62, 105.
19 Rogal Ł, Kalita D, Tarasek A, et al. Journal of Alloys and Compounds, 2017, 708, 344.
20 Schuh B, Völker B, Todt J, et al. Acta Materialia, 2018, 142, 201.
21 Jeong H T, Kim W J. Journal of Materials Science & Technology, 2021, 71, 228.
22 Ding Q, Zhang Y, Chen X, et al. Nature, 2019, 574(7777), 223.
23 Klimova M, Stepanov N, Shaysultanov D, et al. Materials, 2018, 11(1), 53.
24 Yang T, Zhao Y L, Tong Y, et al. Science, 2018, 362(6417), 933.
25 Zhao Y L, Yang T, Tong Y, et al. Acta Materialia, 2017, 138, 72.
26 He J Y, Wang H, Huang H L, et al. Acta Materialia, 2016, 102, 187.
27 Qi Y L, Zhao L, Sun X, et al. Journal of Materials Science & Technology, 2021, 86, 271.
28 Gwalani B, Dasari S, Sharma A, et al. Acta Materialia, 2021, 219, 117234.
29 Chen Y, Hu Y, Hsieh C, et al. Journal of Alloys and Compounds, 2009, 481, 768.
30 Colombini E, Rosa R, Trombi L, et al. Materials Chemistry and Physics, 2018, 210, 78.
31 Fang J Y C, Liu W H, Luan J H, et al. Journal of Phase Equilibria and Diffusion, 2021, 42(5), 781.
32 Wu H, Huang S, Qiu H, et al. Scientific Reports, 2019, 9(1), 1.
33 Li Y L, Zhao Y, Shen L, et al. Journal of Iron and Steel Research International, 2021, 28(4), 496.
34 Jansson B, Melander A. Scripta Metallurgica, 1978, 12, 497.
35 He J Y, Wang H, Wu Y, et al. Intermetallics, 2016, 79, 41.
36 Laplanche G, Gadaud P, Bärsch C, et al. Journal of Alloys and Compounds, 2018, 746, 244.
37 Wang Y, Liu B, Yan K, et al. Acta Materialia, 2018, 154, 79.
38 Zhang F, He J, Wu Y, et al. Materials Science and Engineering A, 2022, 839, 142879.
39 Chu C, Chen W, Chen Z, et al. Acta Metallurgica Sinica(English Letters), 2021, 34(4), 445.
40 Gao S, Kong T, Zhang M, et al. Journal of Materials Research, 2019, 34(5), 819.
41 Soni V K, Sanyal S, Sinha S K. Vacuum, 2020, 174, 109173.
42 Chanda B, Das J. Advanced Engineering Materials, 2017, 20, 1700908.
43 Soni V K, Sanyal S, Sinha S K. Intermetallics, 2021, 132, 107161.

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