石墨烯改性及在有机涂层中的形态

doi:10.11896/cldb.21100195

材料导报

2023, Vol. 37

Issue (17): 21100195-9 https://doi.org/10.11896/cldb.21100195

高分子与聚合物基复合材料

石墨烯改性及在有机涂层中的形态

李晓丹^*, 刘宏宇, 何瑞, 王锋

重庆工商大学环境与资源学院,催化与环境新材料重庆市重点实验室,重庆 400067

Modification and Morphology in Organic Coatings of Graphene

LI Xiaodan^*, LIU Hongyu, HE Rui, WANG Feng

Chongqing Key Laboratory of Catalysis and New Environmental Materials, School of Environment and Resources, Chongqing Technology and Business University, Chongqing 400067, China

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摘要一直以来,金属的腐蚀都是令各国头疼的问题,每年都会对经济造成巨大损失,最常见的防腐措施就是在其表面喷涂有机涂层。石墨烯作为填料加入到有机涂层中,可利用其纳米片层结构阻隔腐蚀物质渗透,但由于其在聚合物基体中分散性不好,具有团聚倾向,因而不能完全发挥其阻隔性能。同时石墨烯具有的导电性会使外界腐蚀介质与金属基体之间形成微导电通路,反而加速基体腐蚀,导致石墨烯改性有机涂层在短期有效,但在长期的耐腐蚀过程中表现不足。因此石墨烯在有机涂层中的形态控制是影响石墨烯/聚合物复合涂层防腐性能的关键因素,探究如何提高石墨烯的分散性和定向取向来增强涂层的耐腐蚀性是需要进一步攻克的难题。本文综述了从有机小分子、聚合物和无机纳米颗粒三方面改性石墨烯以提高其分散性,同时利用磁场、电场、力场、层层自组装等方法对石墨烯在有机涂层中的定向取向进行了详细分析,为解决石墨烯在有机涂层中的形态控制问题提供了思路。

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	李晓丹
	刘宏宇
	何瑞
	王锋

关键词: 石墨烯改性形态分散性取向有机涂层防腐

Abstract: Metal corrosion, causing massive economic losses, is always important issue to be concerned by the government and industry field. One of the conventional anti-corrosion routes is physical separated the metal by spray coating the polymeric film. As an additive, the nano lamellar grapheme is able to enhance the barrier performance by blocking corrosive substances penetration despite the possible agglomeration tendency due to its poor miscibility to the polymer matrix. Furthermore, an inferior conductive pathway is possibly constructed between the external corrosive medium and the metal matrix caused by the conductivity of graphene, thus, shortening the graphene-modified organic coating film lifetime as well as acquiring an insufficient protection because of accelerating the matrix corrosion. Therefore, controlling graphene morphology, dispersion and orientation become the ley role to enhance the corrosion resistance of the coating, which was carefully reviewed, especially the graphene modified with organic molecules, polymers and inorganic nanoparticles to improve its dispersion, the graphene orientation in magnetic field, electric field or force field and self-assembly layer by layer to have a designed morphology.

Key words: graphene modification morphology dispersibility orientation organic coating anti-corrosion

出版日期: 2023-09-10 发布日期: 2023-09-05

ZTFLH:

TQ311

基金资助: 国家自然科学基金(42172321;51403025);重庆市科技局(CSTB2023NSCQ-MSX0474;cstc2019jscx-msxmX0050);重庆市教委(KJZD-K202200807;KJQN202100830);重庆工商大学(1952015)

通讯作者: *李晓丹,重庆工商大学材料科学与工程系教授、硕士研究生导师。2007年6月毕业于四川大学,获工学学士学位。2007年9月进入四川大学高分子科学与工程学院硕博连读,2012年6月获高分子科学与工程专业工学博士学位。2015年10月—2017年12月在四川大学从事博士后研究。长期从事功能高分子材料、纳米复合材料、环境功能材料等领域。近年来,主持国家自然科学基金项目2项、省部级项目10余项,以第一或通信作者在Polymer Chemistry、Physical Chemistry Chemical Physics等国际学术期刊上发表相关研究论文20余篇,授权发明专利3项,编著专著2部。12345ruby@163.com

引用本文:

李晓丹, 刘宏宇, 何瑞, 王锋. 石墨烯改性及在有机涂层中的形态[J]. 材料导报, 2023, 37(17): 21100195-9.
LI Xiaodan, LIU Hongyu, HE Rui, WANG Feng. Modification and Morphology in Organic Coatings of Graphene. Materials Reports, 2023, 37(17): 21100195-9.

链接本文:

http://www.mater-rep.com/CN/10.11896/cldb.21100195 或 http://www.mater-rep.com/CN/Y2023/V37/I17/21100195

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