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材料导报  2023, Vol. 37 Issue (3): 22110300-9    https://doi.org/10.11896/cldb.22110300
  多尺度稀土晶体材料及其应用 |
稀土改性锂基氧化物固态电解质研究现状与展望
张家庆1,2,3,†, 张达1,2,3,†, 陈昆峰4,*, 薛冬峰5,*, 梁风1,2,3,*
1 昆明理工大学云南省有色金属真空冶金重点实验室,昆明 650093
2 昆明理工大学真空冶金国家工程研究中心,昆明 650093
3 昆明理工大学冶金与能源工程学院,昆明 650093
4 山东大学晶体材料国家重点实验室,济南 250100
5 中国科学院深圳先进技术研究院多尺度晶体材料研究中心,广东 深圳 518055
Recent Advances and Perspective on Rare Earth Element Modified Lithium-based Oxide Solid Electrolytes
ZHANG Jiaqing1,2,3,†, ZHANG Da1,2,3,†, CHEN Kunfeng4,*, XUE Dongfeng5,*, LIANG Feng1,2,3,*
1 Key Laboratory for Nonferrous Vacuum Metallurgy of Yunnan Province, Kunming University of Science and Technology, Kunming 650093, China
2 National Engineering Research Center of Vacuum Metallurgy, Kunming University of Science and Technology, Kunming 650093, China
3 Faculty of Metallurgical and Energy Engineering, Kunming University of Science and Technology, Kunming 650093, China
4 State Key Laboratory of Crystal Materials, Shandong University, Jinan 250100, China
5 Multiscale Crystal Materials Research Center, Shenzhen Institute of Advanced Technology, Chinese Academy of Science, Shenzhen 518055, Guangdong, China
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摘要 全固态锂电池具有能量密度高和安全性好等优点,成为新能源领域的研究热点。固态电解质作为全固态锂电池的核心部分,决定了电池的能量密度、循环稳定性以及安全性等。其中,氧化物固态电解质因离子电导率高、电化学窗口宽、力学性能优异而备受青睐,所涉及的研究体系主要包括石榴石型、NASICON型以及钙钛矿型固态电解质。然而,烧结温度高、室温离子电导率低、结构不稳定使其难以满足实际应用。本文概述了石榴石型、NASICON型以及钙钛矿型氧化物固态电解质近年的研究现状和存在的问题;总结了具有大离子半径、高价态、低电负性、可变配位数和4f5d电子结构的稀土离子在改性氧化物固态电解质时起到的增加致密度、提高离子电导率以及稳定高离子导电晶相的作用;分析了当前稀土改性氧化物固态电解质面临的主要科学问题和技术瓶颈;最后,对未来稀土改性氧化物固态电解质发展方向进行了展望。
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张家庆
张达
陈昆峰
薛冬峰
梁风
关键词:  稀土  氧化物固态电解质  改性  离子电导率    
Abstract: All-solid-state lithium batteries have been a hot topic of research in the field of new energy because of their high energy density and high safety.The solid electrolyte, which is the key component of all-solid-state lithium battery, has significant influence on the energy density, cycle stability and safety of the battery. Among solid electrolytes, oxide solid electrolytes possess many merits of the high ionic conductivity, wide electrochemical window, and excellent mechanical property, including garnet-type, NASICON-type and perovskite-type solid electrolytes. However, the high sintering temperature, low ionic conductivity at room temperature, and unstable structure of oxide solid electrolytes cannot meet demands of the practical application. In this review, the research status and existing problems of garnet-type, NASICON-type and perovskite-type solid electrolytes in recent years are summarized. The functions of rare earth elements with large ionic radius, high valence, low electronegativity, variable coordination number and special electronic structure of 4f5d modified oxide solid electrolytes are concluded, including increasing the relative density, improving the ionic conductivity, and stabilizing the high ionic conductive crystal phase. The main scientific problems and technical bottlenecks of rare earth modified oxide solid electrolytes are analyzed. Finally, the future development direction of rare earth modified oxide solid electrolyte is prospected.
Key words:  rare earth    oxide solid electrolyte    modification    ionic conductivity
出版日期:  2023-02-10      发布日期:  2023-02-23
ZTFLH:  O799  
基金资助: 国家自然科学基金(12175089;12205127;51832007;52220105010;M-0755);云南省重点研发计划项目(202103AF140006);云南省科技厅应用基础研究计划项目(202001AW070004)
通讯作者:  *Kunfeng.Chen@sdu.edu.cn;df.xue@siat.ac.cn;liangfeng@kust.edu.cn，陈昆峰,山东大学新一代半导体材料研究院教授、博士研究生导师,2014年博士毕业于大连理工大学。目前主要从事多尺度晶体材料生长制备与性能器件研究工作。发表论文100余篇,包括Journal of Rare Earths、Chemistry Frontiers、Dalton Transactions、Advanced Energy Materials等。
薛冬峰,中国科学院深圳先进技术研究院研究员,深圳理工大学科研讲席教授、博士研究生导师,1998年博士毕业于中国科学院长春应化所。目前主要从事功能无机材料结晶物理化学、多尺度晶态材料设计制备与应用、功能无机材料量子设计与合成及其器件应用以及稀土新材料研究工作。发表论文600余篇,包括Journal of the American Chemical Society、Advanced Materials、Physical Review Letters、Inorganic Chemistry等。
梁风,昆明理工大学冶金与能源工程学院教授、博士研究生导师,2014年博士毕业于东京工业大学。目前主要从事高能量密度电池及材料、碳基新材料、等离子体制备与改性能源材料等方面的研究。发表论文100余篇,包括Nature Communications、Materials Today、Advanced Functional Materials、Nano Energy等。   
作者简介:  †共同第一作者。张家庆,现为昆明理工大学冶金与能源工程学院硕士研究生。目前主要研究固态电解质和钠离子电池正极材料。张达,昆明理工大学冶金与能源工程学院讲师,2021年博士毕业于昆明理工大学。目前主要从事等离子体制备与改性纳米材料和新能源材料与器件的研究工作。发表论文10余篇,包括Carbon,Journal of Power Sources、Nano Energy、Advanced Functional Materials等。
引用本文:    
张家庆, 张达, 陈昆峰, 薛冬峰, 梁风. 稀土改性锂基氧化物固态电解质研究现状与展望[J]. 材料导报, 2023, 37(3): 22110300-9.
ZHANG Jiaqing, ZHANG Da, CHEN Kunfeng, XUE Dongfeng, LIANG Feng. Recent Advances and Perspective on Rare Earth Element Modified Lithium-based Oxide Solid Electrolytes. Materials Reports, 2023, 37(3): 22110300-9.
链接本文:  
http://www.mater-rep.com/CN/10.11896/cldb.22110300  或          http://www.mater-rep.com/CN/Y2023/V37/I3/22110300
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