稀土发光配合物及其在有机发光二极管中的应用

doi:10.11896/cldb.21060045

材料导报

2023, Vol. 37

Issue (3): 21060045-10 https://doi.org/10.11896/cldb.21060045

多尺度稀土晶体材料及其应用

稀土发光配合物及其在有机发光二极管中的应用

卓明鹏^1,2,*, 俞燕君², 丁灵奕², 陈伟凡^3,4, 廖良生²

1 苏州大学纺织与服装工程学院,江苏苏州 215123
2 苏州大学功能纳米与软物质研究院,江苏苏州 215123
3 南昌大学材料科学与工程学院,南昌 330031
4 南昌大学稀土研究院,南昌 330031

Rare Earth Luminous Complexes and Their Applications in Organic Light-emitting Diodes

ZHUO Mingpeng^1,2,*, YU Yanjun², DING Lingyi², CHEN Weifan^3,4, LIAO Liangsheng²

1 College of Textile and Clothing Engineering, Soochow University, Suzhou 215123, Jiangsu, China
2 Institute of Functional Nano & Soft Materials (FUNSOM), Soochow University, Suzhou 215123, Jiangsu, China
3 School of Materials Science & Engineering, Nanchang University, Nanchang 330031, China
4 Rare Earth Research Institute, Nanchang University, Nanchang 330031, China

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摘要稀土材料素有“工业维生素”或“工业味精”之美称,被广泛应用于信息、能源、交通、环境、航天航空等领域。稀土材料也是我国具有特色的战略资源。稀土材料独特的4f壳层电子结构具有丰富的能级结构和优良的光、电、磁、核等物理特性,使得稀土发光配合物可实现从紫外光到红外光的荧光发射,同时具有发光峰窄、稳定性好以及光色可调等特点,在有机电致发光器件研究领域引起了广泛关注。本文综述了基于合理的设计选择有机配体,调控稀土配合物宇称禁阻4f-4f跃迁和宇称允许5d-4f跃迁两种发光机制,并进一步总结其在有机电致发光器件中运用的研究进展,为新型高性能有机电致发光器件的设计与优化提供了新思路。

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	卓明鹏
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关键词: 稀土发光配合物有机发光二极管 4f-4f跃迁 5d-4f跃迁

Abstract: Rare earth materials have been regarded as ‘industrial vitamin’ or ‘industrial monosodium glutamate’, which were widely applied in information, energy, transportation, environment, aerospace and the other fields. Due to the unique 4f shell electronic structure, the rare earth materials demonstrate the excellent physical property of the optical, electrical, magnetic and nuclear aspects, acting as the strategic resources in China. Notably, the rare earth materials with the outstanding fluorescence emission from ultraviolet light to infrared light region play an important role among all kinds of luminescent materials. Significantly, the rare earth luminous complexes expected to become high-performance electroluminescence materials with the characteristics of narrow luminescence peak, high luminescence stability, and adjustable light color, and so on, which are attributed to the novel photoluminescence mechanism of both parity inhibited 4f-4f transition and parity allowed 5d-4f transition. Furthermore, a summary of recent advances in organic light-emitting diodes (OLEDs) of organic rare earth complexes supplies an insight for rationally designing and optimizing the high-performant OLEDs.

Key words: rare earth luminous complexes organic light-emitting diodes 4f-4f transition 5d-4f transition

出版日期: 2023-02-10 发布日期: 2023-02-23

ZTFLH:

O641.4

基金资助: 国家重点研发计划(2016YFB0400700);博士后创新人才支持计划(BX20190228);国家自然科学基金(52203234;51773141;61961160731;51821002)

通讯作者: ^*mpzhuo@suda.edu.cn，卓明鹏,苏州大学纺织与服装工程学院副教授。2014年、2016年分别获南昌大学材料科学与工程学院学士和硕士学位。2019年获苏州大学功能纳米与软材料研究院博士学位。2019年获中国博士后创新人才计划资助在廖良生教授和李述汤院士指导下开展博士后研究工作,2022年加盟苏州大学纺织与服装工程学院。以第一或通信作者在Adv. Mater.(3篇)、Matter、Nat. Commun.(2篇)、Angew. Chem. Int. Ed.(3篇)、CCS Chem.、ACS Nano(2篇)、Mater. Horiz.、ACS Appl. Mater. Interfaces(2篇)、J. Phys. Chem. Lett.(2篇)、ACS Mater. Lett.等国际重要学术期刊发表论文29篇(其中有16篇IF > 10)。主要研究方向是有机光电功能低维微纳米晶体和多级异质结构的精细合成,稀土/钨/碳光电纳米功能材料的合成新方法、构效关系及其柔性智能纺织应用。

引用本文:

卓明鹏, 俞燕君, 丁灵奕, 陈伟凡, 廖良生. 稀土发光配合物及其在有机发光二极管中的应用[J]. 材料导报, 2023, 37(3): 21060045-10.
ZHUO Mingpeng, YU Yanjun, DING Lingyi, CHEN Weifan, LIAO Liangsheng. Rare Earth Luminous Complexes and Their Applications in Organic Light-emitting Diodes. Materials Reports, 2023, 37(3): 21060045-10.

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http://www.mater-rep.com/CN/10.11896/cldb.21060045 或 http://www.mater-rep.com/CN/Y2023/V37/I3/21060045

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