Research Progress of High Temperature Antioxidant Modified Silicide Coatings of Molybdenum and Its Alloys
FU Mingjun1, ZHANG Yong1,*, ZHANG Gengfei1, WANG Kai1, JIA Zhiyuan1, WANG Na2
1 School of Materials Science and Engineering, Chang'an University, Xi'an 710064, China 2 Technical Center, Jinduicheng Molybdenum Co., Ltd., Xi'an 710077, China
Abstract: Molybdenum and molybdenum alloys are widely used in the electronics industry, aviation industry, nuclear industry, and other fields due to their excellent high-temperature mechanical properties. However, the susceptibility to oxidation of these materials at high temperatures limits their application in industrial production. Preparing silicide coating on the surface of molybdenum and its alloy is the crucial measure to improve the oxidation resistance, and element modification can further improve the protective effect. In this paper, based on the recent research of modified silicide high-temperature anti-oxidation coatings of molybdenum and its alloys, four kinds of anti-oxidation mechanisms of modified element are described, which is, inhibiting the oxidation loss of coating, preventing the formation of Si barren zone, improving the self-healing of coating and reducing the formation tendency of the crack in the coating. The modified silicide coating system and preparation methods are introduced. The research direction of modified silicide high temperature anti-oxidation coatings of molybdenum and its alloys are prospected.
符明君, 张勇, 张耿飞, 王凯, 贾致远, 王娜. 钼及钼合金改性硅化物高温抗氧化涂层研究现状[J]. 材料导报, 2023, 37(3): 21030219-8.
FU Mingjun, ZHANG Yong, ZHANG Gengfei, WANG Kai, JIA Zhiyuan, WANG Na. Research Progress of High Temperature Antioxidant Modified Silicide Coatings of Molybdenum and Its Alloys. Materials Reports, 2023, 37(3): 21030219-8.
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