稀土氧化物复合材料在电催化中的研究进展

doi:10.11896/cldb.22110067

材料导报

2023, Vol. 37

Issue (3): 22110067-9 https://doi.org/10.11896/cldb.22110067

多尺度稀土晶体材料及其应用

稀土氧化物复合材料在电催化中的研究进展

江永, 杜亚平^*

南开大学材料科学与工程学院,国家新材料研究院,天津市稀土材料与应用重点实验室,稀土与无机功能材料研究中心, 天津 300350

Research Progress on Rare Earth Oxide Composites in Electrocatalysis

JIANG Yong, DU Yaping^*

Center for Rare Earth and Inorganic Functional Materials,Tianjin Key Lab for Rare Earth Materials and Applications, National Institute for Advanced Materials, School of Materials Science and Engineering, Nankai University, Tianjin 300350, China

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摘要稀土是一种重要的战略资源,稀土元素共包含元素周期表中的17种元素,即15种镧系元素(原子序数从57到71)和钪(原子序数 21)与钇(原子序数 39)。在催化领域,稀土元素由于具有特殊的4f电子构型,电子能级结构丰富,配位数多变,在许多反应中表现出出色的催化性能。在各种稀土催化材料中,稀土氧化物复合催化剂由于其制备工艺简单、结构可调变性强等特点在电催化反应中表现出优异的性能。但当前,稀土氧化物基复合催化剂的电催化反应活性与其自身的电子结构之间的关系尚不明确,阻碍了对稀土在电催化反应中所起作用的理解。本文从稀土氧化物电子结构特点出发,简要综述其复合物在电催化反应中的应用。

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	江永
	杜亚平

关键词: 稀土氧化物电子结构电催化能源转换

Abstract: Rare earth is an important strategic resource, and the rare earth elements (REEs) are a class of 17 elements in the periodic table that include 15 lanthanides (atomic numbers from 57 to 71), scandium (atomic number 21), and yttrium (atomic number 39). Rare earth elements show excellent catalytic performance in many reactions in the field of catalysis due to their special 4f electron configuration, abundant electron structure and flexible coordination numbers. Among all kinds of rare earth catalytic materials, the rare earth oxide based composite catalysts show superior performance in electrocatalytic reactions due to its simple preparation process, versatile structural tunability. However, at present, the relationship between the electrocatalytic activity of rare earth oxides based composite catalyst and their electronic structures is still not clear, which hinders the understanding of REEs in electrocatalytic reactions. Therefore, in this review paper, we tried to summarize and highlight the applications of rare earth oxides based composites in electrocatalytic reactions based on the characteristics of their electronic structures.

Key words: rare earth oxide electronic structure electrocatalysis energy conversion

出版日期: 2023-02-10 发布日期: 2023-02-23

ZTFLH:	TQ426
	O614.33

基金资助: 国家自然科学基金(21971117);南开大学中央高校功能科研业务费专项资金(63186005);天津市稀土材料与应用重点实验室(ZB19500202);稀土资源利用国家重点实验室开放基金(RERU2019001);天津市自然科学基金杰出青年项目(20JCJQJC00130);天津市自然科学基金重点项目(20JCZDJC00650);省部共建特色金属材料与组合结构全寿命安全国家重点实验室开放基金(2022GXYSOF07)

通讯作者: ^*ypdu@nankai.edu.cn，杜亚平,理学博士,南开大学教授、博士研究生导师。现任天津市稀土材料与应用重点实验室主任、南开大学稀土与无机功能材料研究中心执行主任。主要集中在新型稀土纳米材料的研究,承担和参加国家自然科学基金优青、面上项目、天津市杰青、重点项目、京津冀协同创新重点项目和科技部重点研发项目等研究课题。近五年以通讯作者在Science Advance、Angewandte Chemie International Edition、Advanced Materials、Chemical Society Review等刊物发表论文140余篇,总引用次数12 000余次。曾获国家自然科学基金优秀青年基金。

作者简介: 江永,2019年6月、2022年6月分别于池州学院和西南大学获得工学学士学位和硕士学位。现为南开大学材料科学与工程学院博士研究生,在杜亚平教授的指导下进行研究。目前主要研究领域为稀土基新型能源材料。

引用本文:

江永, 杜亚平. 稀土氧化物复合材料在电催化中的研究进展[J]. 材料导报, 2023, 37(3): 22110067-9.
JIANG Yong, DU Yaping. Research Progress on Rare Earth Oxide Composites in Electrocatalysis. Materials Reports, 2023, 37(3): 22110067-9.

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http://www.mater-rep.com/CN/10.11896/cldb.22110067 或 http://www.mater-rep.com/CN/Y2023/V37/I3/22110067

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