基于光电催化的硫化氢高值利用研究进展

doi:10.11896/cldb.22020097

材料导报

2023, Vol. 37

Issue (3): 22020097-7 https://doi.org/10.11896/cldb.22020097

无机非金属及其复合材料

基于光电催化的硫化氢高值利用研究进展

唐春^1,2,*, 吴梦南², 段超², 余堂杰², 于姗², 周莹^1,2,*

1 西南石油大学油气藏地质及开发工程国家重点实验室,成都 610500
2 西南石油大学新能源与材料学院,成都 610500

Research Progress of High-value Utilization of Hydrogen Sulfide Based on Photoelectrocatalysis

TANG Chun^1,2,*, WU Mengnan², DUAN Chao², YU Tangjie², YU Shan², ZHOU Ying^1,2,*

1 State Key Laboratory of Oil and Gas Reservoir Geology and Exploitation, Southwest Petroleum University, Chengdu 610500, China
2 School of New Energy and Materials, Southwest Petroleum University, Chengdu 610500, China

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摘要油气田的开采和石油化工的生产过程中存在大量剧毒硫化氢(H₂S)气体。传统处理H₂S的方法是克劳斯工艺,该工艺只能提取H₂S中的硫元素,潜在的氢能直接以水的形式排放,从而造成巨大的能源浪费。因此,开发与设计出能够实现硫化氢高值利用的新技术已迫在眉睫。光电催化技术是一种能够实现将硫化氢同时转化为氢能与硫化工产品的新型绿色低碳技术,目前已被广泛研究。然而,光电催化H₂S走向实际应用的挑战主要在于开发抗硫毒化的高活性光电催化材料和调控硫氧化反应实现高附加值产品的定向转化。因此,本文从光电催化H₂S的反应原理、反应类型、高活性H₂S分解光电材料构筑策略和H₂S耦合利用四方面进行概述,指出目前光电催化H₂S高值利用研究体系存在的问题并对未来发展方向进行了展望,以期为光电催化H₂S高值利用的发展提供参考。

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	唐春
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	周莹

关键词: 光电催化硫化氢氢能硫化工产品

Abstract: Hydrogen sulfide (H₂S) is a toxic gas widely generated in oil and gas fields and the petrochemical industry. The traditional Claus process not only consumes avast amount of energy but also does not reclaim the hydrogen energy stored in H₂S. Hence it is imminent to design new technology to achieve the high-value utilization of H₂S. Photoelectrocatalysis is a green and low-carbon technology that realizes the simultaneous conversion of H₂S into hydrogen energy and sulfur chemical products. However, the development of photoelectrocatalysts with high activity and poisoning resistance and value-added chemicals product obtained from the sulfur oxidation reaction are still tremendous challenges. Therefore, this review introduces the reaction principle, reaction types, photoelectrocatalyst design strategies, and H₂S coupling reaction systems. The research challenges and prospects associated with the photoelectrocatalytic splitting of H₂S are also provided, thus providing guidance to researchers in this field.

Key words: photoelectrocatalysis hydrogen sulfide hydrogen energy sulfur chemical product

出版日期: 2023-02-10 发布日期: 2023-02-23

ZTFLH:	O643.3
	O646

基金资助: 国家自然科学基金(22178291;22109132);四川省重点研发项目(2022YFSY0052);西南石油大学启航计划(2021QHZ014)

通讯作者: ^*tangchun@swpu.edu.cn;yzhou@swpu.edu.cn，唐春,西南石油大学新能源与材料学院副研究员、硕士研究生导师。2013年在西华师范大学获得学士学位,2016年在西华师范大学获得硕士学位,2019年在西南大学获得博士学位。主要从事氢能与电催化制氢研究。在Angewandte Chemie International Edition、Advanced Materials、Nano Letter等期刊发表SCI论文30余篇,7篇论文入选ESI高被引论文,论文他引4 600余次,单篇最高引用超过1 000次。
周莹,西南石油大学新能源与材料学院教授、博士研究生导师。2004年在中南大学获得无机非金属材料学士学位,2007年在中国科学院上海光学精密机械研究所获得材料学硕士学位,2010年在瑞士苏黎世大学(UZH)获得材料化学博士学位。长期从事油气资源清洁利用与污染治理材料研究,入选国家百千万人才工程人选、“长江学者奖励计划”青年学者、德国洪堡学者、日本JSPS邀请学者、四川省学术与技术带头人、四川省有突出贡献的优秀专家等,受聘为日本京都大学讲座教授等。在《科学通报》《中国科学化学》、Nature Communications、Angewandte Chemie International Edition、ACS Catalysis等期刊发表论文130余篇,被正面引用7 000多次,H因子为50,17篇论文入选ESI高被引论文,授权中国发明专利20项、美国发明专利1项。获得侯德榜化工科学技术青年奖、霍英东教育基金会青年教师奖二等奖、中国石油和化学工业联合会青年科技突出贡献奖。

引用本文:

唐春, 吴梦南, 段超, 余堂杰, 于姗, 周莹. 基于光电催化的硫化氢高值利用研究进展[J]. 材料导报, 2023, 37(3): 22020097-7.
TANG Chun, WU Mengnan, DUAN Chao, YU Tangjie, YU Shan, ZHOU Ying. Research Progress of High-value Utilization of Hydrogen Sulfide Based on Photoelectrocatalysis. Materials Reports, 2023, 37(3): 22020097-7.

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http://www.mater-rep.com/CN/10.11896/cldb.22020097 或 http://www.mater-rep.com/CN/Y2023/V37/I3/22020097

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