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材料导报  2023, Vol. 37 Issue (3): 21030187-10    https://doi.org/10.11896/cldb.21030187
  无机非金属及其复合材料 |
钠离子电池负极材料锐钛矿型二氧化钛的研究进展
赵宏顺1,2,3, 戚燕俐1,2,3, 任玉荣1,2,3,*
1 常州大学材料科学与工程学院,江苏 常州 213164
2 江苏省新能源汽车动力电池制造技术工程研究中心,江苏 常州 213164
3 常州市动力电池智能制造高技术重点实验室,江苏 常州 213164
Research Progress on Anatase Titanium Dioxide as Anode Material for Sodium-ion Batteries
ZHAO Hongshun1,2,3, QI Yanli1,2,3, REN Yurong1,2,3,*
1 School of Materials Science and Engineering, Changzhou University, Changzhou 213164, Jiangsu, China
2 Jiangsu Province Engineering Research Center of Intelligent Manufacturing Technology for the New Energy Vehicle Power Battery, Changzhou 213164, Jiangsu, China
3 Changzhou Key Laboratory of Intelligent Manufacturing and Advanced Technology for Power Battery, Changzhou 213164, Jiangsu, China
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摘要 相较于锂离子电池,钠离子电池具有价格低廉、原料丰富、循环稳定性及倍率性能较好等优点,因此,随着低成本储能技术的需求日益增长,越来越多的研究者加入到钠离子电池基础研究和工程化探索的工作中。在钠离子电池体系中,负极材料在很大程度上影响着电池的能量密度、循环性能及安全性等。另外,在种类繁多的负极材料中,锐钛矿型二氧化钛(TiO2)因自放电低、安全性高、循环寿命长、环境友好以及钠离子脱嵌电位相对较高等优点,逐渐成为钠离子电池负极材料的研究热点。然而,TiO2属于半导体,离子扩散速率小和电子电导率低,严重制约着其倍率性能和循环性能,限制了其发展空间。因此,需对锐钛矿型TiO2进行改性以提升其电导率。本文系统综述了微观结构调控、缺陷(氧空位和杂原子掺杂)以及与导电基体复合等改性方法对锐钛矿型TiO2基负极材料导电性和储钠性能的影响,并对锐钛矿型TiO2作为钠离子电池负极材料在未来的研究与应用进行了展望。
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赵宏顺
戚燕俐
任玉荣
关键词:  钠离子电池  负极材料  锐钛矿型二氧化钛  改性方法    
Abstract: Compared with lithium-ion batteries, sodium-ion batteries have the advantages of low cost, abundant raw materials, good cycle stability and rate performance. Hence, a growing number of researchers have joined the basic research and engineering exploration of sodium-ion batteries because of the increasing demand for low-cost energy storage technologies. With regard to the sodium-ion battery system, the anode materials significantly influence the energy density of the battery, as well as the cycling performance and safety. Recently, anatase titanium dioxide (TiO2), among many anode materials, has gradually become a research hotspot for sodium-ion battery on account of its low self-discharge, high safety, long cycle life, environmental friendliness and relatively high sodium-ion deintercalation potential. Yet, since TiO2 is a semiconductor material, the sluggish ionic diffusivity and poor electronic conductivity severely hinder the performance under high rates and long-term cycling conditions. Therefore, anatase TiO2 needs to be modified to improve its electrical conductivity. This study systematically reviews the effects of different modification methods, such as microstructure adjustment, defects (oxygen vacancy and heteroatom doping) and compounding with conductive matrix. In addition, the research and applications of anatase TiO2 as sodium-ion anode in the future are also prospected.
Key words:  sodium-ion battery    anode material    anatase titanium dioxide    modification method
出版日期:  2023-02-10      发布日期:  2023-02-23
ZTFLH:  O646  
  TM912  
基金资助: 国家自然科学基金(91961126;22078029);江苏高校优势学科建设工程资助项目;江苏省高校青蓝工程科技创新团队项目;江苏省研究生科研与实践创新计划项目(SJCX21_1180)
通讯作者:  *ryrchem@cczu.edu.cn，任玉荣,常州大学材料科学与工程学院教授、博士研究生导师。1998年7月本科毕业于吉林师范大学。2010年7月在中国科学院成都有机化学研究所获得博士学位。2015—2016年在加州大学洛杉矶分校作访问学者。主要研究方向包括新型炭材料和新型纳米能源材料与器件研究。发表学术论文60余篇,公开或授权专利20余项。   
作者简介:  赵宏顺,2019年6月毕业于常州大学,获得工学学士学位。现为常州大学材料科学与工程学院硕士研究生,师从任玉荣教授。目前主要研究课题为二氧化钛基储钠负极材料。
引用本文:    
赵宏顺, 戚燕俐, 任玉荣. 钠离子电池负极材料锐钛矿型二氧化钛的研究进展[J]. 材料导报, 2023, 37(3): 21030187-10.
ZHAO Hongshun, QI Yanli, REN Yurong. Research Progress on Anatase Titanium Dioxide as Anode Material for Sodium-ion Batteries. Materials Reports, 2023, 37(3): 21030187-10.
链接本文:  
http://www.mater-rep.com/CN/10.11896/cldb.21030187  或          http://www.mater-rep.com/CN/Y2023/V37/I3/21030187
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