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材料导报  2021, Vol. 35 Issue (24): 24011-24017    https://doi.org/10.11896/cldb.20090028
  无机非金属及其复合材料 |
冷冻干燥辅助法制备具有增强储锂性能的介孔NiMoO4纳米簇
张意丽, 汤旭涛, 李坚烨, 王府权, 唐康, 胡金星, 方振兴, 严洁峰, 王卫
宁波大学科学技术学院,宁波 315300
Freeze-drying-assisted Synthesis of Mesoporous NiMoO4 Nanoclusters with Enhanced Lithium Storage Properties
ZHANG Yili, TANG Xutao, LI Jianye, WANG Fuquan, TANG Kang, HU Jinxing, FANG Zhenxing, YAN Jiefeng, WANG Wei
College of Science and Technology, Ningbo University, Ningbo 315300, China
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摘要 采用一种简便、绿色的冷冻干燥法制备介孔NiMoO4纳米簇。作为锂离子电池负极材料,介孔NiMoO4纳米簇展现出较高的比容量和倍率性能,在0.2 A/g的电流密度下循环100圈,其可逆容量维持在1 104.8 mAh/g,每圈容量损失仅0.09%。即使在1.0 A/g和2.0 A/g的电流密度下,其可逆容量依然能分别维持在664.7mAh/g 和468.4 mAh/g。此外,以介孔NiMoO4纳米簇为负极、商用LiFePO4为正极组装所得的全电池,在0.1 C(1 C=170 mA/g)下,容量稳定在152.1 mAh/g。介孔NiMoO4纳米簇电化学性能的提高与其独特的介孔结构、较短的锂离子扩散途径密切相关。本工作为设计高储锂性能多孔电极材料提供一个新的视角。
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张意丽
汤旭涛
李坚烨
王府权
唐康
胡金星
方振兴
严洁峰
王卫
关键词:  冷冻干燥  介孔纳米簇  钼酸镍  负极材料  锂离子电池    
Abstract: Afacile and green freeze-drying-assisted method was proposed to synthesize mesoporous NiMoO4 nanoclusters. The mesoporous NiMoO4 nanoclusters exhibit high specific capacity and good rate performance when evaluated as anode materials for lithium-ion batteries (LIBs). The reversible specific capacity can be kept at 1 104.8 mAh/g after 100 cycles at a current density of 0.2 A/g, about 0.09% capacity fading per cycle. Even at the current densities of 1 A/g and 2 A/g, the mesoporous NiMoO4 nanoclusters electrode can still retain the reversible capacities of 664.7 mAh/g and 468.4 mAh/g, respectively. Furthermore, the full cell(mesoporous NiMoO4 nanoclusters anode/LiFePO4 cathode) displays a stable discharge capacity of 152.1 mAh/g at 0.1 C(1 C=170 mA/g). The improved electrochemical performance of mesoporous NiMoO4 nanoclusters is closely related to their unique porous structures and shorter diffusion pathways of lithium ions. This work offers a new perspective to the design of other porous electrode materials with a good energy storage performance.
Key words:  freeze-drying    mesoporous nanoclusters    nickel molybdate    anode material    lithium ion battery
出版日期:  2021-12-25      发布日期:  2021-12-27
ZTFLH:  TM911  
基金资助: 浙江省自然科学基金(LQ18B010001);宁波市自然科学基金(2018A610083);国家级大学生创新创业训练计划(201913277002);国家自然科学基金青年基金(41907100)
通讯作者:  wangwei4@nbu.edu.cn   
作者简介:  张意丽,2017年9月就读于宁波大学科学技术学院,应用化学专业。她的研究兴趣集中在锂离子电池负极材料的开发。王卫,宁波大学科学技术学院,副教授,2016年取得北京理工大学化学专业博士学位。目前主要研究方向为纳米结构材料的合成与性能研究,包括金属氧化物、金属硫化物、石墨烯基复合材料等。
引用本文:    
张意丽, 汤旭涛, 李坚烨, 王府权, 唐康, 胡金星, 方振兴, 严洁峰, 王卫. 冷冻干燥辅助法制备具有增强储锂性能的介孔NiMoO4纳米簇[J]. 材料导报, 2021, 35(24): 24011-24017.
ZHANG Yili, TANG Xutao, LI Jianye, WANG Fuquan, TANG Kang, HU Jinxing, FANG Zhenxing, YAN Jiefeng, WANG Wei. Freeze-drying-assisted Synthesis of Mesoporous NiMoO4 Nanoclusters with Enhanced Lithium Storage Properties. Materials Reports, 2021, 35(24): 24011-24017.
链接本文:  
http://www.mater-rep.com/CN/10.11896/cldb.20090028  或          http://www.mater-rep.com/CN/Y2021/V35/I24/24011
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