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材料导报  2023, Vol. 37 Issue (13): 21080180-8    https://doi.org/10.11896/cldb.21080180
  无机非金属及其复合材料 |
新型氢同位素分离材料研究进展
邓潇君1,*, 熊仁金1, 闫霞艳1, 罗文华2,*
1 中国工程物理研究院材料研究所,四川 绵阳 621907
2 表面物理与化学重点实验室,四川 绵阳 621908
Development of New Materials for Hydrogen Isotopes Separation
DENG Xiaojun1,*, XIONG Renjin1, YAN Xiayan1, LUO Wenhua2,*
1 Institute of Materials, China Academy of Engineering Physics, Mianyang 621907, Sichuan, China
2 Science and Technology on Surface Physics and Chemistry Laboratory, Mianyang 621908, Sichuan, China
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摘要 高效、大规模的氢同位素分离技术是实现氘氚聚变能源利用的关键前提之一,而方法、技术的发展主要取决于关键材料(即分离材料)的发展。本文简要综述了氢同位素分离材料的发展现状,介绍了传统的用于氢同位素分离的钯或含钯材料的应用情况、存在的主要问题以及后续可能的改进方向;重点介绍了二维膜、有机金属骨架和具有孔开关效应的分子筛这三类近年发展起来的新型分离材料,给出了它们用于氢同位素分离的原理、分离效果、存在的问题以及后续的研究、发展方向。
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邓潇君
熊仁金
闫霞艳
罗文华
关键词:  氢同位素  分离  二维膜  MOF  孔开关效应    
Abstract: Tritium/hydrogen isotopes separation with high efficiency and huge scale is one of the crucial technologies for the realization of deuterium-tritium fusion energy application, and the development of separation methods is highly dependent on the separation materials. This paper provides a state-of-the-art review of hydrogen isotopes separation materials. It contains a brief introduction of advantages, disadvantages and applications of the traditional palladium and Pd-containing materials, and then a detailed summary on three kinds of newly developed materials, i.e., two-dimensional membranes, metal-organic framework (MOF) and zeolites with trapdoor effects, focusing on their separation mechanisms, separation demonstrations, and also some existent problems. Finally, based on that summary, the paper gives suggestions about the directions for future researches and improvements of each type of separation material and potential separation material.
Key words:  hydrogen isotopes    separation    two-dimensional membranes    MOF    trapdoor effect
发布日期:  2023-07-10
ZTFLH:  O643.14  
  TL992  
基金资助: 国家重点研发计划(2017YFE0301500);表面物理与化学重点实验室开放基金(XKFZ202004);中国工程物理研究院创新发展基金(CX20200019;CX2019018)
通讯作者:  *邓潇君,2007年毕业于中南大学,获得化学工程与工艺学士学位,并分别于2010年和2021年获得中国工程物理研究院核燃料循环与材料专业的工学硕士和博士学位。目前主要研究领域为氢同位素分离材料与技术、储氢材料等,并在International Journal of Hydrogen Energy、Microporous and Mesoporous Materials等SCI期刊上发表数篇研究论文,获得多项国家发明专利。dengxiaojun@caep.cn;
罗文华,中国工程物理研究院材料研究所所长,表面物理与化学重点实验室主任,研究员,博士研究生导师,中国核学会理事,中国化学会理事,中国核学会锕系物理与化学分会理事长,享受国务院特殊津贴。长期从事核材料性能和相容性、氚化学与氚工艺等相关领域的研究,并取得了大量系统性、创新性的研究成果,以第一或通信作者身份在Journal of Nuclear Materials、Journal of Power Sources、 International Journal of Hydrogen Energy、 Acta Physico-Chimica Sinica等SCI学术期刊发表研究论文数十篇,获部委级和军队科技进步奖10余项,国家专利10余项。luowenhua@caep.cn   
引用本文:    
邓潇君, 熊仁金, 闫霞艳, 罗文华. 新型氢同位素分离材料研究进展[J]. 材料导报, 2023, 37(13): 21080180-8.
DENG Xiaojun, XIONG Renjin, YAN Xiayan, LUO Wenhua. Development of New Materials for Hydrogen Isotopes Separation. Materials Reports, 2023, 37(13): 21080180-8.
链接本文:  
http://www.mater-rep.com/CN/10.11896/cldb.21080180  或          http://www.mater-rep.com/CN/Y2023/V37/I13/21080180
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