壳聚糖衍生碳包覆纳米硅复合材料锂离子电池性能研究

doi:10.11896/cldb.23010052

材料导报

2024, Vol. 38

Issue (10): 23010052-6 https://doi.org/10.11896/cldb.23010052

无机非金属及其复合材料

壳聚糖衍生碳包覆纳米硅复合材料锂离子电池性能研究

吴强¹, 李正伟¹, 周建华^1,*, 张冬梅², 党锋², 刘文平³, 苗蕾^1,*

1 桂林电子科技大学材料科学与工程学院,广西电子信息材料构效关系重点实验室,广西桂林 541004
2 山东大学材料科学与工程学院,济南 250061
3 中国有色桂林矿产地质研究院有限公司,国家特种矿物材料工程技术研究中心,广西超硬材料重点实验室,广西桂林 541004

Performance of Chitosan-Derived Carbon-coated Nanosilicon Anode Materials for Lithium-ion Batteries

WU Qiang¹, LI Zhengwei¹, ZHOU Jianhua^1,*, ZHANG Dongmei², DANG Feng², LIU Wenping³, MIAO Lei^1,*

1 Guangxi Key Laboratory of Information Materials, School of Materials Science and Engineering, Guilin University of Electronic Technology, Guilin 541004, Guangxi, China
2 School of Materials Science and Engineering, Shandong University, Jinan 250061, China
3 National Special Mineral Materials Engineering Technology Research Center & Guangxi Key Laboratory of Superhard Materials, China Nonferrous Metal (Guilin) Geology and Mining Co., Ltd., Guilin 541004, Guangxi, China

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摘要硅负极材料因具有较高的理论容量(Li₂₂Si₅合金相对应4 200 mAh/g)、较低的工作电压(0.2～0.3 V vs Li/Li⁺)和地球上丰富的原材料储备,成为代替石墨负极的理想材料之一。但是,低电导率及在循环过程中发生剧烈体积膨胀导致电极失效问题限制了硅负极材料的进一步发展。因此,本工作通过物理法利用壳聚糖和石墨对纳米硅实现碳包覆和复合,制备壳聚糖/石墨@纳米硅复合材料(C/G@Si复合材料),对C/G@Si复合材料的结构、形貌和电化学性能进行研究。结果表明:随着石墨添加量的提高,C/G@Si复合材料的可逆比容量略微下降,循环性能和导电性能显著提高。当添加50%(质量分数)石墨时,在100 mA/g的电流密度下,C/G@Si复合材料的首次放电比容量为1 136.1 mAh/g,循环充放电100次后剩余容量保持在658.5 mAh/g,展示出优异的电化学性能,对进一步推广硅碳负极材料具有一定的参考价值。

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	吴强
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	刘文平
	苗蕾

关键词: 锂离子电池硅碳负极材料壳聚糖石墨掺杂

Abstract: Silicon anode material has become an ideal material to replace graphite anode due to its high theoretical capacity (4 200 mAh/g), low opera-ting voltage (0.2—0.3 V vs Li/Li⁺) and abundant raw materials on the earth for energy storage. However, the volume expansion of silicon anode materials would lead to electrode degradation during the cycle. Therefore, in this paper, chitosan/graphite@silicon (C/G@Si) composite was prepared by using chitosan and graphite to achieve carbon coating and compositing on nano silicon through physical methods. For C/G@Si, the structure, morphology and electrochemical properties of the composites were studied. The results showed that with the increase of graphite addition, the reversible specific capacity decreased slightly, while the cycle performance and conductivity improved significantly. When 50wt% graphite was added, the specific capacity of the first discharge was 1 136.1 mAh/g under the current density of 100 mA/g, and the residual capacity remained at 658.5 mAh/g after 100 cycles of charging/discharging, which exhibits excellent electrochemical performance and has certain reference value for further promotion of silicon-carbon anode materials.

Key words: lithium ion battery silicon-carbon anode material chitosan graphite doping

出版日期: 2024-05-25 发布日期: 2024-05-28

ZTFLH:

TB332

基金资助: 中央引导地方科技发展资金项目 (ZY21195037);广西杰出青年基金(2019GXNSFFA245010); 国家自然科学基金 (52173094); 桂林市科学研究与技术开发计划 (20220110-1)

通讯作者: *周建华,桂林电子科技大学材料科学与工程学院教授、硕士研究生导师,广西杰出青年基金获得者,广西高校“千骨计划”入选者。2010年南京航空航天大学材料加工工程专业博士毕业后到中国科学院广州能源研究所工作,2015年到桂林电子科技大学工作至今。目前主要从事锂离子电池、新能源功能材料、智能高分子材料等方面的研究工作。发表论文70余篇,SCI他引2 000余次,入选全球前1%ESI高被引论文1篇。申请发明专利20项,已获授权15项。jianhuazhou@guet.edu.cn
苗蕾,桂林电子科技大学材料科学与工程学院教授、博士研究生导师,广西八桂学者,中国科学院“百人计划”入选者。兼日本精细陶瓷研究中心材料技术研究所客座研究员、中国硅酸盐学会特陶分会和热电分会理事。2004年于日本名古屋工业大学获博士学位。主要从事热电转换、锂离子电池、太阳能光热转换和气凝胶材料的创新合成及其在可再生能源和节能领域的应用研究。miaolei@guet.edu.cn

作者简介: 吴强,2020年6月于中国矿业大学徐海学院取得工学学士学位。现为桂林电子科技大学材料科学与工程学院硕士研究生,目前主要研究领域为新能源材料、锂离子电池。

引用本文:

吴强, 李正伟, 周建华, 张冬梅, 党锋, 刘文平, 苗蕾. 壳聚糖衍生碳包覆纳米硅复合材料锂离子电池性能研究[J]. 材料导报, 2024, 38(10): 23010052-6.
WU Qiang, LI Zhengwei, ZHOU Jianhua, ZHANG Dongmei, DANG Feng, LIU Wenping, MIAO Lei. Performance of Chitosan-Derived Carbon-coated Nanosilicon Anode Materials for Lithium-ion Batteries. Materials Reports, 2024, 38(10): 23010052-6.

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http://www.mater-rep.com/CN/10.11896/cldb.23010052 或 http://www.mater-rep.com/CN/Y2024/V38/I10/23010052

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