壳聚糖交联腐殖酸凝胶球吸附渗滤液中重金属离子研究

doi:10.11896/cldb.21040317

材料导报

2023, Vol. 37

Issue (3): 21040317-8 https://doi.org/10.11896/cldb.21040317

高分子与聚合物基复合材料

壳聚糖交联腐殖酸凝胶球吸附渗滤液中重金属离子研究

刘珊^1,2,*, 廖磊^1,2, 魏莉^1,3, 李炫妮^1,2, 曹磊^1,2, 王鑫^1,2

1 长安大学水利与环境学院,西安 710054
2 长安大学旱区地下水文与生态效应教育部重点实验室,西安 710054
3 甘肃省地矿局第四地质矿产勘查院,甘肃酒泉 735000

Adsorption of Heavy Metal Ions from Leachate by Chitosan Cross-linked Humic Acid Gel Beads

LIU Shan^1,2,*, LIAO Lei^1,2, WEI Li^1,3, LI Xuanni^1,2, CAO Lei^1,2, WANG Xin^1,2

1 School of Water and Environment,Chang'an University, Xi'an 710054, China
2 Key Laboratory of Subsurface Hydrology and Ecological Effects in Arid Region, Ministry of Education, Chang'an University, Xi'an 710054, China
3 Fourth Institute of Geological and Mineral Exploration of Gansu Provincial Bureau of Geology and Mineral Resources, Jiuquan 735000, Gansu, China

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摘要以甲醛(CH₂O)为交联剂,聚乙二醇(PEG)为制孔剂,将腐殖酸(HA)交联到壳聚糖(CS)上成功制备了一种新型多孔吸附材料CS-HA凝胶球, 研究其对Cr(Ⅵ)、Ni(Ⅱ)、Cu(Ⅱ)和Pb(Ⅱ)的吸附行为,以及在渗滤液环境下这四种重金属离子的动态吸附效果。结果表明:CS-HA凝胶球对Cr(Ⅵ)、Ni(Ⅱ)、Cu(Ⅱ)和Pb(Ⅱ)的最佳吸附pH分别为3、8、6和6;吸附均为自发进行的;吸附过程更符合拟二级动力学过程和Langmuir等温模型,其单层饱和吸附量分别为108.84 mg/g、170.40 mg/g、104.95 mg/g 和92.80 mg/g。在动态吸附实验中,CS-HA凝胶球能同时吸附渗滤液中的Cr(Ⅵ)、Ni(Ⅱ)、Cu(Ⅱ)和Pb(Ⅱ),四种重金属离子的动态总吸附量相近;Ni(Ⅱ)达到耗竭点的时间最长,对吸附剂的利用率相对最高。FTIR红外光谱结果表明CS-HA凝胶球中的氨基、羟基和羧基等官能团与重金属离子的络合作用是主要的吸附机制。

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	刘珊
	廖磊
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	曹磊
	王鑫

关键词: 壳聚糖腐殖酸渗滤液重金属离子吸附

Abstract: Anovel porous composite adsorbent(CS-HA gel beads) was prepared by chitosan (CS) modified with humic acid(HA), using formaldehyde (CH₂O) as the crosslinking agent and polyethylene glycol (PEG) as the pore-forming agent. The static adsorption performance of Cr(Ⅵ), Ni(Ⅱ), Cu(Ⅱ) and Pb(Ⅱ) by CS-HA gel beads and the dynamic adsorption capacity of the four heavy metal ions in the leachate environment were investigated. The results showed that the optimal adsorption pH of Cr(Ⅵ), Ni(Ⅱ), Cu(Ⅱ) and Pb(Ⅱ) were 3, 8, 6 and 6, respectively. The adsorption process of the four heavy metal ions conformed to the pseudo-second-order kinetics and Langmuir isothermal model, with the adsorption being spontaneous.The maximum adsorption capacity of Cr(Ⅵ), Ni(Ⅱ), Cu(Ⅱ) and Pb(Ⅱ) was 108.84 mg/g, 170.40 mg/g, 104.95 mg/g and 92.80 mg/g, respectively. The dynamic adsorption experiment results showed that CS-HA gel beads could simultaneously adsorb Cr(Ⅵ), Ni(Ⅱ), Cu(Ⅱ) and Pb(Ⅱ) from the leachate, and the adsorption capacity of the four heavy ions was similar. The depletion time of Ni(Ⅱ) was the longest, and the utilization efficiency of the adsorbent was the highest. The FTIR results indicated that the complexation of hydroxyl, amino and carboxyl groups with heavy metal ions was the main adsorption mechanism.

Key words: chitosan humic acid leachate heavy metal ion adsorption

出版日期: 2023-02-10 发布日期: 2023-02-23

ZTFLH:	TQ424
	X52
	O647.3

基金资助: 国家自然科学基金(51408041)

通讯作者: ^*534148120@qq.com，刘珊,长安大学水利与环境学院副教授、硕士研究生导师。2003年4月毕业于西安建筑科技大学环境工程专业取得硕士学位,目前主要从事水污染控制、固体废物处理与资源化研究,已在国内外学术刊物发表论文70余篇。

引用本文:

刘珊, 廖磊, 魏莉, 李炫妮, 曹磊, 王鑫. 壳聚糖交联腐殖酸凝胶球吸附渗滤液中重金属离子研究[J]. 材料导报, 2023, 37(3): 21040317-8.
LIU Shan, LIAO Lei, WEI Li, LI Xuanni, CAO Lei, WANG Xin. Adsorption of Heavy Metal Ions from Leachate by Chitosan Cross-linked Humic Acid Gel Beads. Materials Reports, 2023, 37(3): 21040317-8.

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http://www.mater-rep.com/CN/10.11896/cldb.21040317 或 http://www.mater-rep.com/CN/Y2023/V37/I3/21040317

1 Li Z, Wu L, Shen M Y, et al.Journal of Environment and Health, 2019, 36(6), 560 (in Chinese).
李志, 吴莉娜, 沈明玉, 等. 环境与健康杂志, 2019, 36(6), 560.
2 Liu Z M, Xu L C, Cui L J, et al.Industrial Water Treatment, 2017, 37(6), 19 (in Chinese).
刘占孟, 徐礼春, 崔立杰, 等. 工业水处理, 2017, 37(6), 19.
3 Li H Q, Liu X Y, Sun Y, et al.Environmental Science & Technology, 2020(7), 154 (in Chinese).
李海青, 刘欣艳, 孙宇, 等. 环境科学与技术, 2020(7), 154.
4 Peng Y Z, Zhang S J, Zheng S W, et al.Techniques and Equipment for Environmental Pollution Control, 2006, 7(1), 1 (in Chinese).
彭永臻, 张树军, 郑淑文, 等. 环境污染治理技术与设备, 2006, 7(1), 1.
5 Li H Q, Liu X Y,Zhao Y L, et al.Environmental Sanitation Engineering, 2018, 26(6), 38 (in Chinese).
李海青, 刘欣艳, 赵月龙, 等. 环境卫生工程, 2018, 26(6), 38.
6 LiuS, Fan S G, Sun Z H, et al.Applied Chemical Industry, 2018, 47(6), 1304 (in Chinese).
刘珊, 樊升光, 孙朝辉, 等. 应用化工, 2018, 47(6), 1304.
7 Abdul A N, Sucharita D S, Naidu G S, et al.Chemosphere, 2021, 266, 1.
8 Guo M, Yin F, Dong Y.Journal of Shandong Agricultural University(Na-tural Science Edition), 2008, 39(3), 361 (in Chinese).
郭淼, 尹峰, 董毅.山东农业大学学报(自然科学版), 2008, 39(3), 361.
9 Luo J M, Sun M, Ritt C L, et al.Environmental Science & Technology, 2019, 53(4), 2075.
10 Chen J F, Zhang W Y, Li X.Polymer Bulletin,2016,73(7), 1965.
11 Liu H L, He L H, Zhao Y.Journal of Salt Science and Chemical Industry, 2020, 49(1), 1 (in Chinese).
刘海龙, 何璐红, 赵扬. 盐科学与化工, 2020, 49(1), 1.
12 Qin P, Yu G,Qu Y J, et al.Materials Reports B:Research Papers, 2014, 28(12), 52 (in Chinese).
秦朋, 于刚, 区又君, 等. 材料导报:研究篇, 2014, 28(12), 52.
13 Jin X, Li K, Ning P, et al.Water Air and Soil Pollution, 2017, 228(8), 939.
14 Elsayed S A, Saad E M, Butler I S, et al.Journal of Environmental Chemical Engineering, 2018, 6(2), 3451.
15 Liu F B, Jia M C, Men J F.Environmental Science & Technology, 2015, 38(4), 96 (in Chinese).
刘法邦, 贾铭椿, 门金凤.环境科学与技术, 2015, 38(4), 96.
16 Wang X Q, Tao L Y, Dong R J, et al.Bioresource Technology, 2021, 320(Pt A), 1.
17 Yang L F, Liu Z R, Wang Y, et al.Fine Chemicals, 2018, 35(4), 662 (in Chinese).
杨灵芳, 刘峙嵘, 王云, 等.精细化工, 2018, 35(4), 662.
18 Yuan Y, Rong Y L, Yang F, et al.Food and Fermentation Industries, 2020, 46(18) , 252 (in Chinese).
袁媛, 荣雅利, 杨丰,等. 食品与发酵工业, 2020, 46(18), 252.
19 Jiang Y J, Yu X Y, Luo T, et al.Journal of Chemical & Engineering Data, 2013, 58(11), 3142.
20 Wu W H. Impact of humic acid on the adsorption of copper ions by activated sludge. Master's Thesis, Chongqing University, China, 2015 (in Chinese).
武文会. 腐殖酸对活性污泥吸附铜离子的影响研究. 硕士学位论文, 重庆大学, 2015.
21 Padilla-Ortega E, Leyva-Ramos R, Mendoza-Barron J.Applied Clay Science, 2014, 88-89, 10.
22 Ma M G, Zhou M, Jiang Y F, et al.Journal of Safety and Environment, 2006, 6(3), 68 (in Chinese).
马明广, 周敏, 蒋煜峰, 等.安全与环境学报, 2006, 6(3), 68.
23 Iram M, Guo C, Guan Y, et al.Journal of Hazardous Materials, 2010, 181(1-3), 1039.
24 Chen L, Bai B.Industrial & Engineering Chemistry Research, 2013, 52(44), 15568.
25 Li C L, Yue Q Y, Li Y, et al.Environmental Science, 2010, 31(1), 223 (in Chinese).
李春玲, 岳钦艳, 李颖, 等.环境科学, 2010, 31(1), 223.
26 Li X R, Liang Y.Acta Scientiae Circumstantiae, 2020, 40(9), 3389 (in Chinese).
李星燃, 梁媛. 环境科学学报, 2020, 40(9), 3389.
27 Zhang H, Jiang J, Liu Y M, et al.Chinese Journal of Environmental Engineering, 2015, 9(12), 5865 (in Chinese).
张宏, 蒋菊, 刘燕梅, 等. 环境工程学报, 2015, 9(12), 5865.
28 Siswoyo E, Mihara Y, Tanaka S.Applied Clay Science, 2014, 97-98, 164.
29 Ji Z H, Wu X F, Feng C L, et al.China Environmental Science, 2016, 36(11), 3368 (in Chinese).
冀泽华 ,吴晓芙, 冯冲凌, 等.中国环境科学, 2016, 36(11), 3368.
30 Zhu C, Liu F, Xu C, et al.Journal of Hazardous Materials, 2015, 287, 234.
31 Liu D R. Adsorption study of Cr(Ⅵ) and Ni(Ⅱ) from landfill leachate by CS/HFO and CS/MnFe₂O₄ gel spheres. Master's Thesis, Chang'an University, China, 2020 (in Chinese).
刘丹荣. CS/HFO及CS/MnFe₂O₄凝胶球对垃圾渗滤液中Cr(Ⅵ)和Ni(Ⅱ)的吸附研究. 硕士学位论文, 长安大学, 2020.
32 Zhu C, Liu F, Zhang Y, et al.Chemical Engineering Journal, 2016, 306, 579.
33 Jiang C T. Adsorption of heavy metals from aqueous solution by iron (hydrogen) oxide-chitosan modified aluminum sludge.Master's Thesis, Chang'an University, China,2019 (in Chinese).
蒋翠婷. 铁(氢)氧化物-壳聚糖改性铝污泥吸附水中重金属的研究. 硕士学位论文, 长安大学, 2019.
34 Parr R G, Pearson R G.Journal of the American Chemical Society, 1983, 105(26), 7512.

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