Abstract: Immersion experiments of hardened LC3 paste particles, which prepared by limestone, calcined clay, and cement, were carried out in diffe-rent concentrations of NaCl, CaCl2 and MgCl2 solutions to investigate the changing law of the chloride ion concentration in the immersion solution, the physical composition, and the microstructure of the LC3 paste particles with the immersion time. The effect of different cations, such as Na+, Ca2+ and Mg2+ on the chloride binding capacity of LC3 paste were also analyzed. The results showed that the effect of the three cations on the chloride binding capacity of LC3 paste was Mg2+ > Ca2+ > Na+. Mg2+ and Ca2+ can promote the formation of Friedel's salt, which can improve the chemical binding capacity of chlorides in LC3 paste. Ca2+ can influence the content and structure of C-(A)-S-H gel to increase its physical adsorption capacity of chlorides. When the concentration of Mg2+ is higher, M-S-H gel can be formed to resulting in a decrease of the physical adsorption capacity of chlorides, but Na+ has no apparent influence on the physical adsorption capacity of chlorides.
1 Yuan Q, Shi C J, De Schutter G, et al. Construction and Building Materials, 2009, 23(1), 1. 2 Scrivener K, Martierna F, Bishnoi S, et al. Cement and Concrete Research, 2018, 114, 49 3 Avet F, Scrivener K. Cement and Concrete Research, 2018, 107, 124. 4 Dong Y M, Qian X, Hu C L, et al. Journal of the Chinese Ceramic Society, 2023, 51(9), 2446(in Chinese). 董烨民, 钱雄, 胡传林, 等. 硅酸盐学报, 2023, 51(9), 2446. 5 Shi Z G, Geiker M R, De Weerdt K, et al. Cement and Concrete Research, 2017, 95, 205. 6 Gou M F, Guan X M, Sun Q. Journal of Building Materials, 2015, 18(3), 363 (in Chinese). 勾密峰, 管学茂, 孙倩. 建筑材料学报, 2015, 18(3), 363. 7 Liu X, Feng P, Shen X Y, et al. Materials Reports, 2021, 35(9), 9157 (in Chinese). 刘新, 冯攀, 沈叙言, 等. 材料导报, 2021, 35(9), 9157. 8 Wang X G, Shi C J, He F Q, et al. Journal of the Chinese Ceramic Society, 2013, 41(2), 187(in Chinese). 王小刚, 史才军, 何富强, 等. 硅酸盐学报, 2013, 41(2), 187. 9 Guo L P, Xue X L, Cao Y Z, et al. Materials Reports, 2021, 35(2), 2039(in Chinese). 郭丽萍, 薛晓丽, 曹园章, 等. 材料导报, 2021, 35(2), 2039. 10 De Weerdt K, Colombo A, Coppola L, et al. Cement and Concrete Research, 2015, 68, 196. 11 Fei X P, Guo L P, Wu J D, et al. Construction and Building Materials, 2023, 392, 131967. 12 Farnam Y, Villani C, Washington T, et al. Construction and Building Materials, 2016, 111, 63. 13 The state bureau of quality and technical supervision. Method of testing cements-Determination of strength (GB/T 17671-1999). Standards Press of China, 1999 (in Chinese). 国家质量技术监督局. 水泥胶砂强度检测方法 (GB/T 17671-1999), 中国标准出版社, 1999. 14 Cheewaket T, Jaturapitakkul C, Chalee W. Construction and Building Materials, 2010, 24(8), 1352. 15 William W, Nicolas J G, Fabien G, et al. Cement and Concrete Research, 2022, 156, 106747. 16 Long W J, Zhang X, Feng G L, et al. Cement and Concrete Composites, 2022, 132, 104603. 17 Tang H Y, Zuo X B, Zou Y X, et al. Journal of Building Materials, 2023, 26(6), 571 (in Chinese). 汤昊源, 左晓宝, 邹欲晓, 等. 建筑材料学报, 2023, 26(6), 571. 18 Cheng S K, Shui Z H, Sun T, et al. Construction and Building Materials, 2019, 204, 265. 19 Liu X, Feng P, Yu X H, et al. Cement and Concrete Research, 2022, 160, 106901. 20 Hong S X, Qin S F, Liu Z M, et al. Construction and Building Materials, 2021, 276, 122259. 21 Yang J, Zhang G Z, Ding Q J, et al. Journal of Building Materials, 2022, 25(6), 565(in Chinese) 杨军, 张高展, 丁庆军, 等. 建筑材料学报, 2022, 25(6), 565. 22 Tan L F, Qu B, Shi C J, et al. Materials Reports, 2020, 34(12), 12057(in Chinese) 覃丽芳, 曲波, 史才军, 等. 材料导报, 2020, 34(12), 12057.