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材料导报  2024, Vol. 38 Issue (3): 22060274-13    https://doi.org/10.11896/cldb.22060274
  无机非金属及其复合材料 |
活化亚硫酸(氢)盐降解有机污染物的研究进展
齐亚兵1,*, 贾宏磊2
1 西安建筑科技大学化学与化工学院,西安 710055
2 浙江先锋科技股份有限公司质保部,浙江 台州 317000
Research Advances of Degradation of Organic Pollutants by Activated Sulfite or Hydrosulfite
QI Yabing1,*, JIA Honglei2
1 School of Chemistry and Chemical Engineering, Xi'an University of Architecture and Technology, Xi'an 710055, China
2 Quality Assurance Department, Zhejiang Xianfeng Technologies Co., Ltd., Taizhou 317000, Zhejiang, China
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摘要 与过硫酸盐相比,亚硫酸(氢)盐价格低廉,来源广泛,毒性更低。活化亚硫酸(氢)盐过程不但可产生强氧化性的SO4·-和SO5·-,还可产生兼具氧化性和还原性的SO3·-,因此,活化亚硫酸(氢)盐在降解有机污染物的同时可实现自身的氧化,不会造成二次污染,具有广阔的发展前景。活化亚硫酸(氢)盐的方式主要包括光活化、过渡金属活化、炭质材料活化和电化学活化等。本文简述了活化亚硫酸(氢)盐的机制,综述了活化亚硫酸(氢)盐降解有机污染物的研究进展,解析了活化亚硫酸(氢)盐降解有机污染物的影响因素,分析了活化亚硫酸(氢)盐降解有机污染物存在的问题,展望了活化亚硫酸(氢)盐降解有机污染物的发展趋势,以期为相关学者的后续研究工作提供一定的参考。目前活化亚硫酸(氢)盐降解有机污染物技术还处于实验室研究阶段,未见相关工业应用的报道。假以时日,如若技术成熟,活化亚硫酸(氢)盐在有机污染物的降解领域必将占有一席之地。
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齐亚兵
贾宏磊
关键词:  高级氧化技术  亚硫酸(氢)盐  活化  降解  自由基  有机污染物    
Abstract: Compared to persulfate, sulfite (hydrosulfite) has lower price, more sources, and lower toxicity. During the activation of sulfite, not only the highly oxidizing free radicals such as SO4·-and SO5·- are produced, but also SO3·- which possesses oxidizability and reducibility is generated. Therefore, its autoxidation is realized when degradation of organic pollutants by activated sulfite (hydrosulfite), leading to no secondary pollution and broad development prospects. Activation pattern of sulfite (hydrosulfite) mainly contains activation of light, transition metals, carbon mate-rials and electrodes. In this paper, we review the activation mechanism of sulfite (hydrosulfite), summarize the research progress on degradation of organic pollutants by activated sulfite (hydrosulfite), sketch the influencing factors of degradation of organic pollutants by activated sulfite (hydrosulfite), analyze the existing problems of degradation of organic pollutants by activated sulfite (hydrosulfite), and discuss the deve-lopment trends of degradation of organic pollutants by activated sulfite (hydrosulfite). It can provide direction and guidance for subsequent research. At present, this technology is still at the experimental stage and the related industrial application has not been reported. In future, once the technology becomes mature, it will occupy a place in field of degradation of organic pollutants.
Key words:  advanced oxidation process    sulfite(hydrosulfite)    activation    degradation    free radical    organic pollutant
出版日期:  2024-02-10      发布日期:  2024-02-19
ZTFLH:  X703  
基金资助: 西安市碑林区科技计划项目(GX2134);西安建筑科技大学人才科技基金(RC1714);西安建筑科技大学青年科技基金(QN1509);西安建筑科技大学大学生创新创业训练计划项目(X2022189)
通讯作者:  *齐亚兵,西安建筑科技大学化学与化工学院讲师。2006年本科毕业于长安大学水利与环境学院,2009年和2013年分别在四川大学化工学院获得硕士和博士学位。2013年8月进入陕西化工研究院有限公司工作,2014年5月调入西安建筑科技大学应用化学系任教。目前主要从事传质与分离技术、水处理技术等方面的研究工作。近年来在SCI、EI和中文核心期刊发表论文40余篇。 qiyabing123@163.com   
引用本文:    
齐亚兵, 贾宏磊. 活化亚硫酸(氢)盐降解有机污染物的研究进展[J]. 材料导报, 2024, 38(3): 22060274-13.
QI Yabing, JIA Honglei. Research Advances of Degradation of Organic Pollutants by Activated Sulfite or Hydrosulfite. Materials Reports, 2024, 38(3): 22060274-13.
链接本文:  
http://www.mater-rep.com/CN/10.11896/cldb.22060274  或          http://www.mater-rep.com/CN/Y2024/V38/I3/22060274
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