自组装烧结法可控合成钛酸钡微纳米陶瓷的效果和适用范围研究

doi:10.11896/cldb.22010205

材料导报

2023, Vol. 37

Issue (17): 22010205-6 https://doi.org/10.11896/cldb.22010205

无机非金属及其复合材料

自组装烧结法可控合成钛酸钡微纳米陶瓷的效果和适用范围研究

宋恩鹏^1,*, 靳权¹, 刘钊², 陈奋华², 蔡克¹

1 中国石油集团工程材料研究院有限公司,西安 710077
2 中国石油长庆油田分公司物资供应处,西安 710016

Study on the Effect and Application Scope of Controllably Synthesizing the Barium Titanate Micro-nano Ceramics by the Self-assembly and Sintering Method

SONG Enpeng^1,*, JIN Quan¹, LIU Zhao², CHEN Fenhua², CAI Ke¹

1 CNPC Tubular Goods Research Institute, Xi’an 710077, China
2 Material Supply Department, PetroChina Changqing Oilfield Company, Xi’an 710016, China

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摘要微纳米钛酸钡陶瓷(BaTiO₃)是多层陶瓷电容器(Multilayer ceramic capacitors,MLCCs)的关键材料,其可控合成受到研究者的广泛关注。本工作采用自组装烧结法制备了具有不同晶粒尺寸的微纳米BaTiO₃陶瓷,从样品的相对密度、晶粒尺寸和介电性能研究了该方法在可控合成微纳米BaTiO₃陶瓷时的效果和适用范围。结果表明,采用二元粒径自组装烧结法,通过合理选择BaTiO₃粉体尺寸和组合方式,实现了可控合成不同晶粒尺寸的陶瓷;采用三元和四元粒径自组装烧结法,虽然提高了陶瓷的相对密度,但是降低了晶粒尺寸的可控性。因此,采用二元粒径自组装烧结法有利于可控合成微纳米BaTiO₃陶瓷。

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	宋恩鹏
	靳权
	刘钊
	陈奋华
	蔡克

关键词: 钛酸钡相对密度晶粒尺寸介电性能自组装烧结法可控合成

Abstract: Because themicro-nano barium titanate ceramics (BaTiO₃) are the key materials of the multilayer ceramic capacitors (MLCCs), the researchers focus on synthesizing them controllably. In this work, the micro-nano BaTiO₃ ceramics with different sizes were prepared by a self-assembly sintering method. We have researched the effects and application scopes of this method to synthesize the micro-nano BaTiO₃ ceramics controllably by investigating the relative density, grain size, and dielectric properties. We can controllably prepared the ceramics with different grain sizes by the binary particle size self-assembly sintering method, that is, selecting the BaTiO₃ powder sizes and combination method reaso-nably. Although the relative density of the ceramics were improved via the ternary and quaternary grain size self-assembly sintering methods, the controllability of grain size were reduced simultaneously. Therefore, it is beneficial to synthesize the micro-nano BaTiO₃ ceramics controllably though the binary particle size one.

Key words: barium titanate relative density grain size dielectric properties self-assembly sintering method controllable synthesis

出版日期: 2023-09-10 发布日期: 2023-09-05

ZTFLH:

TQ174

基金资助: 国家自然科学基金(21071115);陕西省自然科学基金重点项目(2020JZ-44);陕西省自然科学基金(2019TD-007)

通讯作者: *宋恩鹏,分别于2011年6月、2014年4月于西安电子科技大学获得工学学士学位和硕士学位。现工作于中国石油集团工程材料研究院有限公司,现主要从事陶瓷材料制备和油气增产研究工作。songep@cnpc.com.cn

引用本文:

宋恩鹏, 靳权, 刘钊, 陈奋华, 蔡克. 自组装烧结法可控合成钛酸钡微纳米陶瓷的效果和适用范围研究[J]. 材料导报, 2023, 37(17): 22010205-6.
SONG Enpeng, JIN Quan, LIU Zhao, CHEN Fenhua, CAI Ke. Study on the Effect and Application Scope of Controllably Synthesizing the Barium Titanate Micro-nano Ceramics by the Self-assembly and Sintering Method. Materials Reports, 2023, 37(17): 22010205-6.

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http://www.mater-rep.com/CN/10.11896/cldb.22010205 或 http://www.mater-rep.com/CN/Y2023/V37/I17/22010205

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