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材料导报  2023, Vol. 37 Issue (1): 21080126-7    https://doi.org/10.11896/cldb.21080126
  无机非金属及其复合材料 |
Fe3O4-GO复合纳米纸的制备及吸波性能研究
李威霖1, 陈玲2, 王佳3, 袁凯1, 焦剑1,*
1 西北工业大学化学与化工学院,西安 710129
2 河北经贸大学信息技术学院电子信息工程系,石家庄 050062
3 西安超码科技有限公司,西安 710025
Preparation and Microwave Absorption Performance of Fe3O4-GO Composite Buckypaper
LI Weilin1, CHEN Ling2, WANG Jia3, YUAN Kai1, JIAO Jian1,*
1 School of Chemistry and Chemical Engineering, Northwestern Polytechnical University, Xi’an 710129, China
2 Department of Electronic Information Engineering, College of Information Technology, Hebei University of Economics and Business, Shijiazhuang 050062, China
3 Xi’an Chaoma Technology Co., Ltd., Xi’an 710025, China
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摘要 为了实现目前实际应用对吸波材料“轻、薄、宽、强”的要求,本工作采用氧化石墨烯(GO)结合磁性纳米粒子四氧化三铁(Fe3O4)构筑了一类新型的轻质且具有良好柔韧性的复合纳米纸吸波材料,希望其能简化复合材料成型工艺并替代吸波涂料,实现对吸波性能的调控。首先,利用γ-氨丙基三乙氧基硅烷(KH-550)对Fe3O4纳米粒子进行有机化修饰,制备了分散均匀、具有电磁双损性能的Fe3O4-GO复合纳米粒子,进而利用溶剂蒸发沉积法制备了GO及Fe3O4-GO纳米纸,并对其结构及性能进行了研究。结果表明,NH2-Fe3O4稳定附着在GO片层上,当Fe3O4与GO的质量比为4 ∶6时,其输入阻抗Zin与自由空间阻抗Z0最为接近,复合纳米纸的阻抗匹配性能最好。Fe3O4-GO复合纳米纸较复合纳米粒子具有更强的吸波性能,当Fe3O4与GO的质量比分别为4 ∶6和5 ∶5时,在2～18 GHz频段内,反射损耗(RL)值均小于-10 dB。
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李威霖
陈玲
王佳
袁凯
焦剑
关键词:  氧化石墨烯  四氧化三铁纳米粒子  复合纳米纸  吸波性能    
Abstract: In response to the requirement of light-weight absorbing materials, a new type of flexible composite buckypaper were prepared with graphene oxide (GO) buckypaper and magnetic nanoparticles (Fe3O4) and acted as a lightweight electromagnetic wave absorbing material, which is expected to replace the wave-absorbing paint and simplify the molding process to realize the control of wave-absorbing performance. First, γ-aminopropyltriethoxysilane (KH-550) was used to organically modify Fe3O4 nanoparticles to prepare Fe3O4-GO composite nanoparticles with uniform dispersion and electromagnetic double loss performance, and then GO and Fe3O4-GO buckypapers were prepared by solvent evaporation deposition method. The results show that NH2-Fe3O4 is stably attached to the GO sheet. When the mass ratio of Fe3O4 to GO is 4 ∶6, the input impedance Zin is closest to the free space impedance Z0, which means the impedance matching performance of the composite buckypaper is the best. Furthermore, Fe3O4-GO composite buckypaper has stronger absorbing performance than composite nanoparticles. When the mass ratio of Fe3O4 to GO is 4 ∶6 and 5 ∶5, respectively, the reflection loss(RL) values are less than -10 dB in the 2—18 GHz frequency band.
Key words:  graphene oxide    Fe3O4 nanoparticles    composite buckypaper    wave-absorbing performance
出版日期:  2023-01-10      发布日期:  2023-01-31
ZTFLH:  TB332  
基金资助: 陕西省自然科学基础研究计划(2020JM-087)
通讯作者:  * 焦剑,西北工业大学化学与化工学院教授、博士研究生导师,陕西省复合材料学会会员,中国环氧树脂学会会员。1991年毕业于西北工业大学高分子材料与工程专业,获学士学位;1994年于西北工业大学化学工程系,获材料学硕士学位;2000年于西北工业大学,获材料学博士学位。目前主要研究方向有中空无机纳米粒子的合成及应用、介孔材料的设计在透波材料和二氧化碳吸附材料上的应用以及石墨烯、碳纳米管等在电磁屏蔽材料上的应用等。在Advanced Functional Materials、Chemical Engineering Journal等国内外期刊发表研究论文70余篇(其中SCI、EI索引20余篇),主编与合著教材、专著6部。jjiao@nwpu.edu.cn   
作者简介:  李威霖,2019年6月毕业于西北工业大学,于2019年9月至今在西北工业大学化学与化工学院攻读材料学硕士学位,主要从事吸波复合材料领域的研究。
引用本文:    
李威霖, 陈玲, 王佳, 袁凯, 焦剑. Fe3O4-GO复合纳米纸的制备及吸波性能研究[J]. 材料导报, 2023, 37(1): 21080126-7.
LI Weilin, CHEN Ling, WANG Jia, YUAN Kai, JIAO Jian. Preparation and Microwave Absorption Performance of Fe3O4-GO Composite Buckypaper. Materials Reports, 2023, 37(1): 21080126-7.
链接本文:  
http://www.mater-rep.com/CN/10.11896/cldb.21080126  或          http://www.mater-rep.com/CN/Y2023/V37/I1/21080126
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