基于氧化石墨烯/ZnO纳米阵列的无酶葡萄糖传感器

doi:10.11896/cldb.21010061

材料导报

2022, Vol. 36

Issue (13): 21010061-6 https://doi.org/10.11896/cldb.21010061

无机非金属及其复合材料

基于氧化石墨烯/ZnO纳米阵列的无酶葡萄糖传感器

梁旭¹, 韩露¹, 雷雅京¹, 黎雯¹, 黄瑞滨², 陈荣生¹, 倪红卫¹, 詹玮婷^1,*

1 武汉科技大学省部共建耐火材料与冶金国家重点实验室,武汉科技大学钢铁冶金及资源利用省部共建教育部重点实验室,武汉 430081
2 南昌大学第一附属医院,南昌 330006

Non-enzymatic Glucose Sensor Based on Graphene Oxide/ZnO Nanoarrays

LIANG Xu¹, HAN Lu¹, LEI Yajing¹, LI Wen¹, HUANG Ruibin², CHEN Rongsheng¹, NI Hongwei¹, ZHAN Weiting^1,*

1 The State Key Laboratory for Refractories and Metallurgy, Key Laboratory for Ferrous Metallurgy and Resource Utilization of Ministry of Education, Wuhan University of Science and Technology, Wuhan 430081, China
2 The First Affiliated Hospital of Nanchang University, Nanchang 330006, China

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摘要采用微波水热合成法在不锈钢表面制备氧化石墨烯/ZnO纳米棒阵列(GO/ZnO NRs)作为无酶葡萄糖传感器电极。通过扫描电子显微镜、X射线衍射仪、透射电子显微镜等对电极进行形貌、组织和结构的表征,并通过电化学工作站在有光和无光条件下对电极进行了电流-时间(I-t)曲线测试,分析了在不同氧化石墨烯(GO)沉积条件下GO/ZnO NRs的光电化学性能,在无酶条件下对电极进行光电化学葡萄糖传感测试。结果表明,GO的添加使得ZnO无序的纳米颗粒/棒形貌转变为定向生长的一维阵列,并随着GO的全程添加,ZnO(200)晶面的垂直堆积被抑制,(100)晶面和(101)晶面逐渐堆积,从而使ZnO纳米棒的形貌从原有的尖头生长成平头形。所得GO/ZnO NRs对葡萄糖具有较高的检测灵敏度、较低的检测限和良好的检测范围。

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	梁旭
	韩露
	雷雅京
	黎雯
	黄瑞滨
	陈荣生
	倪红卫
	詹玮婷

关键词: ZnO纳米棒阵列氧化石墨烯无酶葡萄糖传感器不锈钢光电化学传感

Abstract: Graphene oxide/ZnO nanorod arrays (GO/ZnO NRs) were prepared on the surface of stainless steel by microwave hydrothermal synthesis as an enzyme-free glucose sensor electrode. The morphology, organization and structure of the electrode were characterized by scanning electron microscope, X-ray diffractometer, transmission electron microscope, etc., and the electrode was subjected to current-time (I-t) through electrochemical workstation under light and non-light conditions. I-t curve tests were used to analyzed the photoelectrochemical performance of GO/ZnO NRs under different graphene oxide (GO) deposition conditions, and photoelectrochemical glucose sensing tests were performed on the electrode under enzyme-free conditions. The results show that the addition of GO transform the disordered nanoparticle/rod morphology of ZnO into an one-dimensional array of directional growth. With the increase of GO content, the vertical accumulation of ZnO(200) crystal planes is suppressed, while the crystal planes (100) and ( 101) are gradually accumulated. Thus, the morphology of ZnO NRs grow from the original sharp tip to a flat tip. The obtained GO/ZnO NRs have high detection sensitivity for glucose, low detection limit and good detection range.

Key words: ZnO nanorod array graphene oxide non-enzymatic glucose sensor stainless steel photoelectrochemical sensor

出版日期: 2022-07-10 发布日期: 2022-07-12

ZTFLH:	Q657.1
	S951.4+2

基金资助: 国家自然科学基金青年科学基金项目(51601136);中国博士后科学基金特别资助项目(2015T80842);武汉科技大学大学生创新创业训练计划项目(S201910488003;20ZA016)

通讯作者: * zhanwt@wust.edu.cn

作者简介: 梁旭,2018年6月毕业于济南大学,获得工程学士学位。同年进入武汉科技大学学习至今,主要从事ZnO和CuO纳米材料领域的研究。
詹玮婷,武汉科技大学副教授。武汉科技大学本硕博连读,2012年获得材料与冶金博士学位。2013年7月加入武汉科技大学省部共建耐火材料与冶金国家重点实验室工作至今,多年来从事纳米结构的设计与构筑、多功能高效抗菌材料、光催化纳米材料合成和生物功能化研究等方面的工作。发表相关的学术论文30余篇,被Electrochemistry Communications、Applied Surface Science、Journal of the Electrochemical Society、Ceramics International、Journal of Materials Science、《功能材料》等国内外重要学术期刊收录,申请国家发明专利8项,已授权7项。

引用本文:

梁旭, 韩露, 雷雅京, 黎雯, 黄瑞滨, 陈荣生, 倪红卫, 詹玮婷. 基于氧化石墨烯/ZnO纳米阵列的无酶葡萄糖传感器[J]. 材料导报, 2022, 36(13): 21010061-6.
LIANG Xu, HAN Lu, LEI Yajing, LI Wen, HUANG Ruibin, CHEN Rongsheng, NI Hongwei, ZHAN Weiting. Non-enzymatic Glucose Sensor Based on Graphene Oxide/ZnO Nanoarrays. Materials Reports, 2022, 36(13): 21010061-6.

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http://www.mater-rep.com/CN/10.11896/cldb.21010061 或 http://www.mater-rep.com/CN/Y2022/V36/I13/21010061

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