Structural Design, Synthesis and Photocatalytic Applications of g-C3N4/Transition Metal Sulfide Composite Material
TANG Fei1,2, CAI Wenyu1,2, CHEN Fei1,2, ZHU Chen1,2, LIU Chengbao1,2,3,*, CHEN Zhigang1,2
1 Jiangsu Key Laboratory for Environment Functional Materials, Suzhou University of Science and Technology, Suzhou 215009, Jiangsu,China 2 School of Materials Science and Engineering, Suzhou University of Science and Technology, Suzhou 215009,Jiangsu,China 3 Jiangsu Collaborative Innovation Center of Technology and Material for Water Treatment, Suzhou University of Science and Technology, Suzhou 215009, Jiangsu,China
Abstract: Graphite carbonnitride (g-C3N4), as an inorganic non-metallic semiconductor photocatalytic material, comprises a special energy band and crystal structure, which receives extensive attention in environmental governance and clean energy. However, the single-phase g-C3N4 has disadvantages of small response range to natural light, small specific surface area, few reactive sites, and high recombine efficiency of photoelectron-hole pairs, which limit its large-scale utilization in the field of photocatalysis. Transition metal sulfides have a special energy band structure, and excellent physical and photocatalytic properties, which show great development potential in photocatalytic applications. There were numerous researches generally focused on the construction of heterojunctions to solve the problems that catalytic materials has, such as narrow optical response range, low photocatalytic quantum efficiency due to the easy combination of carriers, short duration of carriers and insufficient reactive sites. Herein, the performance, structure design and reaction mechanism of the g-C3N4/transition metal sulfide photocatalytic materials were reviewed, the progress of the heterogeneous junction construction was discussed, and the development prospect of the g-C3N4/transition metal sulfide composite materials was prospected.
通讯作者:
* 刘成宝,苏州科技大学材料科学与工程学院副教授、硕士研究生导师。2004年本科毕业于江苏大学无机非金属材料工程专业,2007年获江苏大学材料学专业工学硕士学位,2010年获江苏大学材料学专业工学博士学位。2018年在美国罗格斯大学材料科学与工程系担任为期一年的访问学者。2016年8月被遴选为江苏省第五期“333高层次人才培养工程”中青年学术技术带头人。主要从事二维基催化材料、量子点材料和环境功能材料等的结构设计、合成及其环境和能源性能评价。已在Ceramics International、Journal of Alloys and Compounds、Journal of Rare Earths等国内外重要期刊发表学术论文100余篇,其中SCI收录70余篇;申请国家发明专利18项,其中已获授权12项。lcb@mail.usts.edu.cn
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