催化化学中的聚合物基纳米反应器

doi:10.11896/cldb.21050109

材料导报

2022, Vol. 36

Issue (24): 21050109-9 https://doi.org/10.11896/cldb.21050109

高分子与聚合物基复合材料

催化化学中的聚合物基纳米反应器

邱嘉琪¹, 闵玉婷¹, 陈涛^1,2,*

1 浙江理工大学先进纺织材料与制备技术教育部重点实验室,杭州 310018
2 浙江省绿色清洁技术及洗涤用品重点实验室,浙江丽水 323000

Polymer-based Nanoreactors in Catalytic Chemistry

QIU Jiaqi¹, MIN Yuting¹, CHEN Tao^1,2,*

1 Key Laboratory of Advanced Textile Materials and Manufacturing Technology, Ministry of Education, Zhejiang Sci-Tech University, Hangzhou 310018, China
2 Key Laboratory of Green Cleaning Technology & Detergent of Zhejiang Province, Lishui 323000, Zhejiang, China

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摘要聚合物基纳米反应器具有制备简单、分散性好、结构易调控等优点。将均相催化剂引入到聚合物基纳米反应器中既可实现均相催化和异相催化的有机结合,也可有效地利用纳米反应器底物浓缩效应、限域效应等特殊效应。此外,由于聚合物基催化纳米反应器的结构易调控、可实现串联催化、可回收再利用等特点,且其模拟了酶作用的微环境,具有催化活性高、可水相催化等优点。基于此,国内外的研究者们设计了大量不同结构的催化纳米反应器,包括两亲性聚合物自组装的纳米反应器、交联聚合物自组装的纳米反应器、单链粒子型纳米反应器以及其它类型聚合物基纳米反应器。本文对不同类型的聚合物基纳米反应器的构筑以及催化应用进行了综述。

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	邱嘉琪
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关键词: 聚合物纳米反应器催化化学

Abstract: The polymer-based nanoreactor has the characteristics of easy preparation, good dispersion and facile modulation of molecular structure. The introduction of homogeneous catalyst into polymer-based nanoreactor can not only realize the organic combination of homogeneous catalysis and heterogeneous catalysis, but also effectively utilize the nanoreactor's substrate concentration effect, confinement effect, etc. Polymer-based nanoreactors have been widely used in many fields, such as separation, sensing, electronics, drug delivery, catalysis, etc. In the field of catalysis, the polymeric nanoreactor simulates the microenvironment of enzyme possessing excellent catalytic activity in water. Besides, polymer-based nanoreactor is recyclable and can be used for cascade catalysis. Therefore, researchers around the world have designed a large number of catalytic nanoreactors with different structures, including nanoreactors based on amphiphilic polymers, crosslinked polymers, single-chain particles and other types of polymers. These catalytic nanoreactors displayed excellent catalytic performance. This paper reviews the fabrication and catalytic application of such polymer-based nanoreactors.

Key words: polymer nanoreactor catalytic chemistry

发布日期: 2023-01-03

ZTFLH:

O63

基金资助: 国家自然科学基金(52273216)

通讯作者: tao.chen@zstu.edu.cn

作者简介: 邱嘉琪,2021年6月毕业于浙江理工大学,获得工学硕士学位。此前,在陈涛老师的指导下从事聚合物基纳米反应器的构筑及催化应用研究。
陈涛,浙江理工大学纺织科学与工程学院轻化工程系研究员。2007年于华东理工大学获得应用化学博士学位。主要从事聚合物基催化纳米反应器以及智能纺织材料的研究,已发表相关学术论文40余篇。

引用本文:

邱嘉琪, 闵玉婷, 陈涛. 催化化学中的聚合物基纳米反应器[J]. 材料导报, 2022, 36(24): 21050109-9.
QIU Jiaqi, MIN Yuting, CHEN Tao. Polymer-based Nanoreactors in Catalytic Chemistry. Materials Reports, 2022, 36(24): 21050109-9.

链接本文:

http://www.mater-rep.com/CN/10.11896/cldb.21050109 或 http://www.mater-rep.com/CN/Y2022/V36/I24/21050109

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