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材料导报  2022, Vol. 36 Issue (24): 21050108-14    https://doi.org/10.11896/cldb.21050108
  金属与金属基复合材料 |
纳米孪晶强化合金制备技术与力学性能研究进展
韩基鸿1, 张洋1,*, 马亚玺1, 刘力源1, 杨忠波2, 张中武1,*
1 哈尔滨工程大学材料科学与化学工程学院,超轻材料与表面技术教育部重点实验室,哈尔滨 150001
2 中国核动力研究设计院核燃料及材料国家级重点实验室,成都 610041
Research Progress in the Preparation Techniques and Mechanical Properties of Nanotwin Strengthened Alloys
HAN Jihong1, ZHANG Yang1,*, MA Yaxi1, LIU Liyuan1, YANG Zhongbo2, ZHANG Zhongwu1,*
1 Key Laboratory of Ultralight Materials and Surface Technology of Ministry of Education, School of Materials Science and Chemical Engineering, Harbin Engineering University, Harbin 150001, China
2 National Key Laboratory of Nuclear Fuel and Materials, China Nuclear Power Research and Design Institute, Chengdu 610041, China
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摘要 近年来,纳米孪晶强化由于在提高合金强度的同时还保持良好塑性的特点而受到研究者们的广泛关注。在纳米孪晶强化中,孪晶界是位错运动的二维界面障碍,这种界面障碍能够通过减少位错平均自由程来提升合金的加工硬化率和抗拉强度。此外,孪晶片层厚度与强化效果遵循Hall-Petch关系,孪晶片层厚度越小意味着孪晶界的密度越高,孪晶界和位错的相互作用将更加频繁。纳米孪晶强化技术已经被成功应用于多种合金体系。本文重点分析研究了高熵合金、TWIP钢、铝合金、铜合金和不锈钢中纳米孪晶强化技术的应用情况。首先,围绕纳米级变形孪晶和纳米级生长孪晶介绍了纳米孪晶的形成机理与制备方法。制备纳米级变形孪晶时,通常需要驱动肖克莱不全位错的运动;制备纳米级生长孪晶则需要控制微观局部应力集中和应力松弛,应力松弛使局部应力得到释放,进而形成低能的纳米级生长孪晶。然后,归纳了层错能对纳米孪晶形成的影响,概述了几种合金元素对层错能的影响规律,总结了评估层错能的四种方法,分析了温度和应变速率协调孪生机制的一般规律,即如何协调滑移-孪生两种机制的竞争关系,因此制备纳米孪晶需要协调好合金体系、层错能、温度、应变速率与孪生应力之间的关系。最后,讨论了纳米孪晶强化在力学性能方面的研究进展,与具有常规结构的材料相比,具有纳米孪晶结构的材料通常表现出更优异的力学性能,尤其是强塑性和断裂韧性。纳米孪晶甚至有望优化其他性能,将纳米孪晶引入到合金中有望为材料性能优化提供更多的机会。
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韩基鸿
张洋
马亚玺
刘力源
杨忠波
张中武
关键词:  层错能  温度  应变速率  孪生应力  纳米孪晶    
Abstract: In recent years, nanotwin strengthening has received extensive attention because of its ability to increase alloy strength while maintaining good plasticity. In nanotwin strengthening, a twin boundary is a two-dimensional interface obstacle for the movement of dislocations. This interface obstacle can improve the work-hardening rate and tensile strength by reducing the mean free path of dislocations. In addition, the thickness of the twin layer and the strengthening effect follow the Hall-Petch relationship. The thinner the twin layer, the higher is the density of the twin boundaries, and thus, the more frequent is the interaction between the twin boundaries and dislocations. This paper summarized and analyzed the applications of nanotwin strengthening in various alloy systems, including high-entropy alloys, TWIP steels, aluminum alloys, copper alloys and stainless steels. Firstly, the formation mechanism and preparation method of nanoscale deformation twins and nanoscale growth twins are introduced.During the preparation of deformation nanotwins, the movement of Shockley partial dislocations is generally necessary, and the preparation of growth nanotwins requires controlling micro-local stress concentration and stress relaxation. Stress relaxation can release local stress and form low-energy-growth nanotwins. Subsequently, the influence of the stacking fault energy (SFE) on the formation of nanotwins is analyzed. The influence of several alloying elements on the SFE was summarized. Four methods for calculating the SFE were reviewed. Moreover, the general mechanisms of temperature-and strain-rate-coordinated twinning were analyzed, that is, how to coordinate the competition between slip and twinning mechanism. The results show that the preparation of nanotwins requires coordinating the relationship between the alloy system, SFE, temperature, strain rate and twin stress. Finally, the paper discusses the research progress of nanotwin strengthening in terms of mechanical properties. Compared with metals with conventional structures, materials with nanotwins generally exhibit better mechanical properties, especially strength, plasticity and fracture toughness. Nanotwins are also expected to optimize other properties, and the introduction of nanotwins into alloys is expected to provide more opportunities for performance optimization.
Key words:  stacking fault energy    temperature    strain rate    twin stress    nanotwin
发布日期:  2023-01-03
ZTFLH:  TG115  
基金资助: 国家重点研发计划(2018YFE0115800);中核集团青年英才计划菁英项目(CNNC2019YTEP-HEU01)
通讯作者:  zhangyang0115@hrbeu.edu.cn;zwzhang@hrbeu.edu.cn   
作者简介:  韩基鸿,2018年本科毕业于黑龙江工程学院,2020级哈尔滨工程大学硕博连读生,研究方向为纳米孪晶和纳米相强化高熵合金及其辐照效应。
张洋,博士,硕士研究生导师,哈尔滨工程大学副教授。2015年12月博士毕业于山东大学,2014年11月至2016年9月期间在美国宾夕法尼亚州立大学作为联合培养博士研究生和博士后,2016年11月入职哈尔滨工程大学。近五年在国际期刊发表SCI论文20余篇,其中2篇被选为期刊封面文章。研究方向为新型耐辐照核结构材料开发、纳米相强化与层错能调控技术及应用、金属材料动态力学性能等。
张中武,博士,哈尔滨工程大学教授、博士研究生导师,黑龙江省“龙江学者”讲座教授,黑龙江省杰出青年科学基金获得者。获得中国产学研合作创新成果二等奖。获授权专利17项。在国际期刊,如Science Advances、Acta Materialia、International Journal of Plasticity等刊物上发表SCI论文80余篇。在国际学术会议上做包括主题报告(keynote)和邀请报告(invited)在内的学术报告40余篇次,组织国际会议3次。其中以宣讲人身份做大会报告3次、主题报告5次、邀请报告15次。2012年被遴选为美国橡树岭国家实验室网站封面人物,2015年被遴选为科学中国人(2014)年度人物(化工冶金与材料领域)。 研究方向为纳米相强化技术及应用、层错能调控合金设计及变形机制、船舶海工及核能应用新型金属材料、小角中子散射和三维原子探针在合金中的应用等。
引用本文:    
韩基鸿, 张洋, 马亚玺, 刘力源, 杨忠波, 张中武. 纳米孪晶强化合金制备技术与力学性能研究进展[J]. 材料导报, 2022, 36(24): 21050108-14.
HAN Jihong, ZHANG Yang, MA Yaxi, LIU Liyuan, YANG Zhongbo, ZHANG Zhongwu. Research Progress in the Preparation Techniques and Mechanical Properties of Nanotwin Strengthened Alloys. Materials Reports, 2022, 36(24): 21050108-14.
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http://www.mater-rep.com/CN/10.11896/cldb.21050108  或          http://www.mater-rep.com/CN/Y2022/V36/I24/21050108
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