PEDOT夹心PVDF多孔膜的电驱动性能研究

doi:10.11896/cldb.21010222

材料导报

2022, Vol. 36

Issue (10): 21010222-6 https://doi.org/10.11896/cldb.21010222

高分子与聚合物基复合材料

PEDOT夹心PVDF多孔膜的电驱动性能研究

张晓蝶, 丁井鲜, 黄建建, 王放, 马丽, 郭东杰^*

郑州轻工业大学河南省表界面重点实验室,郑州 450002

Electromechanical Response of Porous PVDF Film Sandwiched by PEDOT Electrodes

ZHANG Xiaodie, DING Jingxian, HUANG Jianjian, WANG Fang, MA Li, GUO Dongjie^*

State Laboratory of Surface & Interface, Zhengzhou University of Light Industry, Zhengzhou 450002, China

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摘要常规离子聚合物金属复合材料(IPMC)以Pt金属纳米颗粒为电极、Nafion膜作为母体,存在电极刚性大、电极与聚合物母体不兼容、制备成本高等缺陷。本工作采用聚乙烯吡咯烷酮和聚氧化乙烯作为造孔剂、离子液([EMIm]·[BF₄])为增塑剂,制备了高多孔度的柔性聚偏氟乙烯(PVDF)母体膜。物化性能测试表明:PVDF膜的多孔度高达26.3%,杨氏模量仅为17.1 MPa。以3,4-乙烯二氧噻吩(EDOT)为单体、FeCl₃为催化剂,利用原位化学沉积方法在PVDF膜两侧制备了导电聚(3,4-乙烯二氧噻吩)(PEDOT)电极。施加交流电场后,得到PEDOT电极的IPMC致动器。在0.1 Hz、22 V的条件下,新型IPMC致动器具备连续稳定的驱动性能,末端最大位移输出为6.0 mm。改变驱动电压或频率,位移输出随之发生变化,IPMC致动器展现出了良好的可控性。

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关键词: 离子聚合物金属复合材料电活性聚合物(EAP) 聚(3,4-乙烯二氧噻吩) 聚偏氟乙烯离子液

Abstract: Conventional ionic polymer-metal composite (IPMC) employs Pt metal nanoparticles as electrodes and Nafion membrane as matrix film, and thus brings severe drawbacks of high electrode rigidity of electrode, an incompatibility between the matrix and the electrodes, and high cost of fabrication. This work used polyvinylpyrrolidone and polyvinyl oxide as the pore-forming agents and ionic liquid of [EMIm]·[BF₄] as the plasticizer to prepare a highly porous flexible polyvinylidene fluoride (PVDF) matrix film. Physicochemical tests showed that PVDF matrix presented the high porosity of 26.3% and the low Young's modulus of 17.1 MPa. Using 3, 4-vinylenedioxythiophene (EDOT) as the monomer and FeCl₃ as the catalyst, conductive PEDOT electrodes were anchored on both sides of the PVDF film by in-situ chemical deposition. After applying an AC electric field, a novel IPMC actuator using PEDOT electrode was obtained. In the condition of 0.1 Hz and 22 V, the resultant IPMC actuator showed continuous and stable driving behaviors with a maximum displacement output of 6.0 mm. With driven voltage or frequency changing, the displacement outputs subsequently changed, the IPMC actuator showing a good controllability.

Key words: ionic exchange polymer metal composite electroactive polymer poly(3,4-ethylenedioxythiophene) polyvinylidene fluoride ionic liquid

发布日期: 2022-05-24

ZTFLH:

TQ317

基金资助: 教育部长江学者创新团队计划(IRT1187);国家自然科学基金-河南省联合(U1704149);河南省科技攻关(202102210292);河南省高等学校重点科研项目(20A530005)

通讯作者: djiguo@zzuli.edu.cn

作者简介: 张晓蝶,郑州轻工业大学硕士研究生。2015年9月至2019年6月,在郑州航空工业管理学院获得学士学位。2019年9月至今,在郑州轻工业大学攻读硕士学位。
郭东杰,教授,博士,2006年在肖守军教授的指导下获得南京大学材料化学博士学位,他在2008—2009年和2016—2017年,在美国科罗拉多大学博尔德分校机械工程系进行博士后研究,随后作访问学者。2008年,在南京航空航天大学担任副研究员,2021年任郑州轻工业大学教授,专门从事IPMC、DEP等电活性聚合物(EAP)的制造和应用研究。

引用本文:

张晓蝶, 丁井鲜, 黄建建, 王放, 马丽, 郭东杰. PEDOT夹心PVDF多孔膜的电驱动性能研究[J]. 材料导报, 2022, 36(10): 21010222-6.
ZHANG Xiaodie, DING Jingxian, HUANG Jianjian, WANG Fang, MA Li, GUO Dongjie. Electromechanical Response of Porous PVDF Film Sandwiched by PEDOT Electrodes. Materials Reports, 2022, 36(10): 21010222-6.

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http://www.mater-rep.com/CN/10.11896/cldb.21010222 或 http://www.mater-rep.com/CN/Y2022/V36/I10/21010222

1 Wang H S, Cho J, Song D S, et al. ACS Applied Materials & Interfaces, 2017, 9(26), 21998.
2 Guo D J, Han Y B, Huang J J, et al. ACS Applied Materials & Interfaces, 2019, 11(2), 2386.
3 Fukushima T, Asaka K, Kosaka A, et al. Angewandte Chemie Internatio-nal Edition, 2005, 44(16), 2410.
4 Wu G, Hu Y, Liu Y, et al. Nature Communications, 2015, 6(3), 7258.
5 Lee S, Park H C, Kim K J. Smart Materials and Structures, 2005, 14(6), 1363.
6 Cheong H R, Nguyen N T, Khaw M K, et al. Lab on a Chip, 2018, 18(20), 3207.
7 Carrico J D, Hermans T, Kim K J, et al. Scientific Reports, 2019, 9(2), 819.
8 Acome E, Mitchell S K, Morrissey T G, et al. Science, 2018, 359(6371), 61.
9 Wang Y J, Ru J, Zhao D X. Materials Reports A: Review Papers, 2017, 31(8), 24 (in Chinese).
王延杰, 汝杰, 赵东旭, 等.材料导报:综述篇, 2017, 31(8), 24.
10 Guo D J, Liu R, Cheng Y, et al. ACS Applied Materials & Interfaces, 2015, 7(9), 5480.
11 Liu Y, Ghaffari M, Zhao R, et al. Macromolecules, 2012, 45(12), 5128.
12 Jiang T, Liu L X, Lian H Q. Materials Reports A: Review Papers, 2011, 25(9), 22 (in Chinese).
姜涛, 柳乐仙, 连慧琴.材料导报:综述篇, 2011, 25(9), 22.
13 Bennett M D, Leo D J. Sensors and Actuators A: Physical, 2004, 115(1), 79.
14 Ji J, Liu F, Hashim N A, et al. Reactive & Functional Polymers, 2015, 86, 134.
15 Guo D J, Wang L, Wang X J, et al. Sensors and Actuators B: Chemical, 2020, 305, 127488.
16 Liu J Q, Li Y F, Liang B, et al. IOP Conference Series: Materials Science and Engineering, 2019, 493(1), 12048.
17 Wang H M, Tang G Q, Jin S S, et al. Acta Chimica Sinica, 2007, 65(21), 2454.
18 Rajagopalan M, Oh I K. ACS Nano. 2011, 5, 2248.
19 Shahinpoor M, Bar-cohen Y, Simpson J O, et al. Smart Materials and Structures, 1998, 7, 251.
20 Neves M, Damasceno J, Junior O, et al. Synthetic Metals, 2021, 272, 116657.
21 Xu Y, Jia Y, Liu P, et al. Chemical Engineering Journal, 2021, 404, 126552.
22 Rasouli H, Naji L, Hosseini M G. New Journal of Chemistry, 2018, 42(14), 12104.
23 Lee S W, Kim J W, Kim Y H, et al. Macromolecular Research, 2013, 21(6), 699.
24 Huang J X, Yang H J, Chen M, et al. Polymer Testing, 2017, 59, 212.
25 Chen P, Hou Z C, Lu X F. Journal of Radiation Research and Radiation Processing, 2011, 29(3), 134 (in Chinese).
陈鹏, 侯铮迟, 陆晓峰. 辐射研究与辐射工艺学报, 2011, 29(3), 134.
26 Wang X H, Song F, Qian D, et al. Chemical Engineering Journal, 2018, 349, 588.
27 Martins P, Costa C M, Ferreira J, et al. Journal of Physical Chemistry B, 2012, 116(2), 794.
28 Wang T, Li H, Wang F, et al. Polymer Chemistry, 2011, 2(8), 1688.

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