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材料导报  2022, Vol. 36 Issue (6): 20120257-7    https://doi.org/10.11896/cldb.20120257
  无机非金属及其复合材料 |
金属有机骨架衍生的层状Co3O4/C在锂硫电池中的应用
赵文文, 王韵芳, 段东红, 刘世斌, 周娴娴, 陈良
太原理工大学化学化工学院,洁净化工研究所,太原 030024
Application of Layered Co3O4 /C Derived from Metal-organic Framework in Lithium-sulfur Batteries
ZHAO Wenwen, WANG Yunfang, DUAN Donghong, LIU Shibin, ZHOU Xianxian, CHEN Liang
Institute of Clean Technique for Chemical Engineering, College of Chemistry and Chemical Engineering, Taiyuan University of Technology, Taiyuan 030024, China
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摘要 通过对层状金属有机骨架(Metal-organic framework 71,MOF-71) 前驱体先碳化后氧化的方法合成了四氧化三钴/碳复合纳米颗粒。将制得的纳米颗粒与硫复合后借助四氧化三钴的极性优势能对多硫化锂产生很强的亲和力,可以抑制穿梭效应。通过对材料进行物理表征和电化学测试发现,氧化温度对Co3O4/C 结构形貌有较大的影响,高温氧化所制备的Co3O4/C 材料粒径约50 nm,平均孔径为17.44 nm,多层网状结构有利于提升电池容量和稳定性。以Co3O4/C为正极基质负载硫组装的锂硫电池,在0.2C放电倍率下,首圈放电比容量为1 142.2 mAh·g-1;在0.5C电流密度下循环300圈,其库仑效率仍保持在98%以上,该锂硫电池表现出优异的电化学性能。
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赵文文
王韵芳
段东红
刘世斌
周娴娴
陈良
关键词:  金属有机骨架  锂硫电池  穿梭效应  四氧化三钴  多硫化锂    
Abstract: Cobalt tetroxide/carbon composite nanoparticles were synthesized by a method of oxidizing layer-shaped MOF-71 precursor primary carbonization. By virtue of the polar advantage of cobalt tetroxide, the prepared nanoparticles can have a strong affinity for lithium polysulfide and inhibit the shuttle effect. Through physical characterization and electrochemical test of the material, it is found that the oxidation temperature has a greater impact on the shape of the Co3O4/C structure and the particle size of the Co3O4/C material prepared by high temperature oxidation is about 50 nm, the average pore size of which is 17.44 nm. Multi-layered reticular structure is conducive to improving battery capacity and stability. Discharge specific capacity of lithium sulfur batteries assembled with Co3O4/C as positive matrix loaded with sulfur is 1 142.2 mAh·g-1 in the first cycle at a discharge rate of 0.2C. After cycled 300 times at the current density of 0.5C, the Coulombic efficiency remains above 98%, lithium sulfur batteries exhibiting excellent electrochemical performance.
Key words:  metal organic framework    lithium sulfur battery    shuttle effect    cobalt tetroxide    lithium polysulfide
出版日期:  2022-03-25      发布日期:  2022-03-21
ZTFLH:  O646  
基金资助: 山西省重点研发计划项目(201803D121120);山西省应用基础研究计划项目(201901D211064)
通讯作者:  wangyunfang@tyut.edu.cn;dhduan@163.com   
作者简介:  赵文文,太原理工大学化学化工学院硕士研究生,师从王韵芳副教授和段东红副教授。目前从事锂硫电池硫正极材料制备及性能研究。
王韵芳,博士,副教授,2011年获得太原理工大学工学博士学位。在国内主要学术刊物上发表论文10篇(其中SCI、EI收录6篇)。主要研究光催化材料在能源、生物等领域的应用。
段东红, 博士,副教授,2010年获太原理工大学化学工程专业博士学位。1996年至今在太原理工大学工作,共发表SCI学术论文50余篇,申请国家发明专利23项,授权18项。主要从事电催化和电化学储能研究。
引用本文:    
赵文文, 王韵芳, 段东红, 刘世斌, 周娴娴, 陈良. 金属有机骨架衍生的层状Co3O4/C在锂硫电池中的应用[J]. 材料导报, 2022, 36(6): 20120257-7.
ZHAO Wenwen, WANG Yunfang, DUAN Donghong, LIU Shibin, ZHOU Xianxian, CHEN Liang. Application of Layered Co3O4 /C Derived from Metal-organic Framework in Lithium-sulfur Batteries. Materials Reports, 2022, 36(6): 20120257-7.
链接本文:  
http://www.mater-rep.com/CN/10.11896/cldb.20120257  或          http://www.mater-rep.com/CN/Y2022/V36/I6/20120257
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