Preparation and Application of Polymer-based MOFs Composites
XU Qunna1,2,3, QIU Ruijie1,2, MA Jianzhong1,2
1 National Demonstration Center for Experimental Light Chemistry Engineering Education, College of Bioresources Chemical and Materials Engineering, Shaanxi University of Science & Technology, Xi'an 710021, China 2 Shaanxi Collaborative Innovation Center of Industrial Auxiliary Chemistry & Technology, Shaanxi University of Science & Technology, Xi'an 710021, China 3 Shaanxi Research Institute of Agricultural Products Processing Technology, Xi'an 710021, China
Abstract: Metal-organic framework compounds (MOFs), an organic-inorganic porous complex mainly formed by self-assembly of metal ions and organic ligands. Metal organic frameworks (MOFs)emerging as a kind of porous of organic-inorganic skeleton materials, have tunable nanospaces, high porosity and high specific surface area, which makes it has a wide range of applications in biomedicine, sensing, gas separation membranes, etc. But MOFs materials have some disadvantages, such as poor stability and low mechanical strength. In order to improve its shortcomings, some researchers have combined MOFs materials with inorganic or organic materials to improve the defects of MOFs meanwhile broa-den the application of MOFs. This review focuses on the synthesis of polymer-based MOFs composites. In this review, MOFs are classified into the following categories according to the naming, composition and synthesis methods of MOFs: isoreti-cular metal-organic frameworks (IRMOFs), zeoliticimidazolate frameworks (ZIFs), and metarial sofistitute Lavoisier frameworks (MILs), poc-ket-channel frameworks (PCNs), etc. Two preparation methods commonly used in polymer-based MOFs composites are summarized: physical blending and in-situ methods. The composite mode of the polymer and MOFs in the material is non-covalently bonded, including hydrogen bond, van der Waals force, electrostatic action, etc.; covalent bond, which is mainly the combination of amino group and carboxyl group. In the combination of non-covalent bond and covalent bond, there are hydrogen bonds. And the combination of covalent bond can make the polymer and MOFs material better composite, the polymer-based MOFs composite material is more stable and more applicable widely. Finally, the application status of polymer-based MOFs composites in biomedicine, sensing, gas separation membranes, etc. are introduced. The development trend of polymer-based MOFs composites are prospected. It mainly includes the way of composites, the structural control of composites, and the application of composites in other fields. It is hoped that researchers in polymer-based MOFs composites will provide some guidance and reference.
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2020, Vol. 34 
