Recent Progress in Phosphorus-containing Polysilsesquioxane and Flame Retardancy to Polymers
WANG Xiaoxia1, WANG Yong2, ZHANG Juan2
1 School of Materials Science and Engineering, Beijing Institute of Technology, Beijing 100081, China 2 Guangdong R&D Center for Technological Economy, Guangzhou 510070, China
Abstract: Polymer materials have broad application prospects. However, flame retardancy is one of factors limiting their application. Polysilsesquioxane (POSS) has unique molecular designability and has received extensive attention in the field of polymer flame retardancy in recent years. Aiming at the research status of POSS, it is reviewed for flame retardant mechanism and general synthesis. The synthetic and application of phosphorus-containing oligomeric silsesquioxane (phosphorus-containing POSS) in polymers are mainly discussed. The common phosphorus-containing POSS can be divided into five categories according to their structural morphology: complete cage, incomplete cage, cage-trapezoid, POSS-based copolymer, and POSS-based functionalized graphene oxide. At the same time, their influence on the flame retardancy of different polymers was discussed. The results show that polymer with different phosphorus-containing POSS can exhibit excellent flame retardancy.
1 Hazer S, Coban M, Aytac A.Fire and Materials, 2019, 43(3), 277. 2 Zhou K Q, Gui Z, Hu Y. Composites Part A-Applied Science and Manufacturing, 2016, 80,217. 3 Ma H Y, Song P A, Fang Z P.Science China-Chemistry, 2011, 54(2), 302. 4 Li D P, Li C X, Jiang X L, et al.Journal of Cellular Plastics, 2018, 54(3), 615. 5 Wang Z Y, Han E H, Ke W.Progress in Organic Coatings, 2005, 53(1), 29. 6 Qin Z L, Li D H, Li Q, et al.Materials & Design, 2016, 89,988. 7 Wilkie C A. Fire retardancy of polymers: new application of mineral fillers, Royal Society of Chemistry, UK, 2005, pp. 1. 8 Bourbigot S, Duquesne S.Journal of Materials Chemistry, 2007, 17(22),2283. 9 Furgal J C, Goodson T, Laine R M. Dalton Transactions, 2016, 45(3), 1025. 10 兰中旭, 韦嘉, 俞燕蕾.功能高分子学报, 2020, 33(4), 320. 11 张晓静, 胡跃磊, 李翀, 等.功能高分子学报, 2014, 27(3), 296. 12 Gon M, Tanaka K, Chujo Y.Polymer Journal, 2018, 50(1),109. 13 Li G Z, Wang L C, Ni H L, et al.Journal of Inorganic and Organometallic Polymers, 2001, 11(3),123 14 Laine R M, Roll M F.Macromolecules, 2011, 44(5),1073. 15 Scott D W. Journal of the American Chemical Society, 1946, 68(3),356. 16 Li G, Wang L, Ni H, et al. Journal of Inorganic and Organometallic Polymers, 2001, 11(3), 123. 17 Li G, Pittman C U.Polyhedral Oligomeric Silsesquioxane (POSS) Polymers, Copolymers, and Resin Nanocomposites, Mississippi State University, US, 2005. 18 Li S, Zhao X, Liu X, et al.Journal of Applied Polymer Science, 2019, 136(23), 47607. 19 李远源. POSS基含磷共聚物改性环氧树脂的研究. 博士学位论文, 厦门大学, 2016. 20 Fina A, Tabuani D, Frache A, et al.Polymer, 2005, 46(19),7855. 21 Wu K, Song L, Hu Y, et al.Progress in Organic Coatings, 2009, 65(4),490. 22 Fina A, Abbenhuis H C L, Tabuani D, et al.Polymer Degradation and Stability, 2006, 91(10),2275. 23 Li Z Q, Yang R J.Polymer Degradation and Stability, 2014, 109,233. 24 Qian Y, Wei P, Zhao X, et al. 2013, 37(1),1. 25 Tanaka K, Chujo Y.Journal of Materials Chemistry, 2012, 22(5),1733. 26 Kuo S W, Chang F C.Progress in Polymer Science, 2011, 36(12),1649. 27 Zhang W, Li X, Guo X, et al.Polymer Degradation and Stability, 2010, 95(12),2541. 28 肖俊平, 王欣.有机硅材料, 2011, 25(5),300. 29 沈蓉. 三苯基膦和三苯基氧化膦功能化的 POSS 基杂化多孔聚合物的制备及其应用研究. 硕士毕业论文, 山东大学, 2017. 30 Qi Z, Zhang W, He X, et al.Composites Science and Technology, 2016, 127,8. 31 Wang X, Zhang W, Qin Z, et al.Composites Part A: Applied Science and Manufacturing, 2019, 117,92. 32 Zhu S E, Wang L L, Wang M Z, et al.RSC Advances, 2017, 7(85), 54021. 33 Liu C, Chen T, Yuan C, et al.RSC Advances, 2017, 7(73),46139. 34 Wang Q, Xiong L, Liang H, et al. Inorganic and Nano-Metal Chemistry, 2016, 47(1),99. 35 Wang Q, Xiong L, Liang H, et al.Journal of Macromolecular Science, Part B, 2016, 55(12),1146. 36 Yaoke D, Yuan Z, Wang J.E-Polymers, 2018, 18(3),237. 37 Tsafack M J, Levalois-Grützmacher J.Surface and Coatings Technology, 2006, 200(11),3503. 38 Li M, Zhang H, Wu W, et al. Polymers, 2019, 11(2),241. 39 Park D S, Ha T S, Lim J H, et al. Polymer Journal, 2015, 47(6),415. 40 Tang C, Yan H, Li S, et al.Journal of Polymer Research, 2017, 24(10),157. 41 Yu B, Tao Y J, Liu L, et al.RSC Advances, 2015, 5(92),75254.