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材料导报  2021, Vol. 35 Issue (Z1): 552-559    
  高分子与聚合物基复合材料 |
含磷低聚倍半硅氧烷及其阻燃应用的研究进展
王小霞1, 王勇2, 张娟2
1 北京理工大学材料学院,北京 100081
2 广东省技术经济研究发展中心,广州 510070
Recent Progress in Phosphorus-containing Polysilsesquioxane and Flame Retardancy to Polymers
WANG Xiaoxia1, WANG Yong2, ZHANG Juan2
1 School of Materials Science and Engineering, Beijing Institute of Technology, Beijing 100081, China
2 Guangdong R&D Center for Technological Economy, Guangzhou 510070, China
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摘要 高分子材料具有广泛的应用前景,但其阻燃性往往成为限制其使用的因素之一。聚倍半硅氧烷(POSS)具有独特的分子可设计性,近年来在聚合物阻燃领域受到广泛关注。本文针对聚倍半硅氧烷的研究现状,综述了其阻燃机理及一般合成方法。重点讨论了含磷低聚倍半硅氧烷(含磷POSS)的合成方法及其在聚合物中的应用效果。将常见的含磷POSS,按照结构形态分为五类:完整笼形、不完整笼形、笼-梯形、POSS基共聚物、POSS基官能化氧化石墨烯,并讨论了它们对不同聚合物带来的阻燃性能的影响。结果表明,不同的含磷POSS与一定的聚合物混合均能表现出优异的阻燃性能,具有广泛的应用前景。
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王小霞
王勇
张娟
关键词:  含磷低聚倍半硅氧烷  合成方法  阻燃性    
Abstract: Polymer materials have broad application prospects. However, flame retardancy is one of factors limiting their application. Polysilsesquioxane (POSS) has unique molecular designability and has received extensive attention in the field of polymer flame retardancy in recent years. Aiming at the research status of POSS, it is reviewed for flame retardant mechanism and general synthesis. The synthetic and application of phosphorus-containing oligomeric silsesquioxane (phosphorus-containing POSS) in polymers are mainly discussed. The common phosphorus-containing POSS can be divided into five categories according to their structural morphology: complete cage, incomplete cage, cage-trapezoid, POSS-based copolymer, and POSS-based functionalized graphene oxide. At the same time, their influence on the flame retardancy of different polymers was discussed. The results show that polymer with different phosphorus-containing POSS can exhibit excellent flame retardancy.
Key words:  phosphorus-containing oligomeric silsesquioxane    synthesis    flame retardancy
                    发布日期:  2021-07-16
ZTFLH:  TQ314.24  
通讯作者:  wangyongtnt@hotmail.com   
作者简介:  王小霞,2019年7月毕业于北京理工大学,获得硕士学位。在读期间,研究领域为“功能高分子与阻燃材料”,主要研究课题为“含磷低聚倍半硅氧烷及其阻燃应用”。攻读硕士学位期间,以学生中第一作者的身份发表2篇SCI TOP期刊、2篇国际会议论文,以学生中第一发明人的身份申请6篇专利。曾获得国家奖学金、校级优秀毕业论文和北京市优秀毕业生称号。王勇,现任广东省技术经济研究发展中心专项管理部部长,科技情报专业助理研究员。2008年6月,在北京理工大学获得材料化学专业理学学士学位,2010年4月,在香港科技大学获得机械工程专业理学硕士学位,2015年4月,在香港理工大学获得工业与系统工程工学博士学位后,在广东省技术经济研究发展中心(广东省科技评估中心)工作至今,其中2016年和2018年到科技部科技评估中心进行访问、合作研究。研究方向主要包括:科技评估、科技情报研究、科技政策等。牵头负责广东省省级科研项目3项,累计经费超过100万元,在各类期刊发表论文10余篇。
引用本文:    
王小霞, 王勇, 张娟. 含磷低聚倍半硅氧烷及其阻燃应用的研究进展[J]. 材料导报, 2021, 35(Z1): 552-559.
WANG Xiaoxia, WANG Yong, ZHANG Juan. Recent Progress in Phosphorus-containing Polysilsesquioxane and Flame Retardancy to Polymers. Materials Reports, 2021, 35(Z1): 552-559.
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http://www.mater-rep.com/CN/  或          http://www.mater-rep.com/CN/Y2021/V35/IZ1/552
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