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《材料导报》期刊社  2017, Vol. 31 Issue (18): 49-54    https://doi.org/10.11896/j.issn.1005-023X.2017.018.011
  材料研究 |
硅丙乳液对镁系无机胶黏剂性能和微结构的影响*
肖俊华, 左迎峰, 吴义强, 刘文杰, 吴志平, 孟陶陶
中南林业科技大学材料科学与工程学院,长沙 410004
Effect of Silicone-acrylic Emulsion on Properties and Microstructure of Mg-based Inorganic Adhesive
XIAO Junhua, ZUO Yingfeng, WU Yiqiang, LIU Wenjie, WU Zhiping, MENG Taotao
College of Materials Science and Engineering, Central South University of Forestry and Technology, Changsha 410004
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摘要 以硅丙乳液为改性剂,通过扫描电镜(SEM)、X射线衍射仪(XRD)等手段分析了添加量对镁系无机胶黏剂复合板材力学强度、耐水性能、阻燃性能和镁系无机胶黏剂凝固时间的影响原因。结果表明:硅丙乳液与镁系无机胶黏剂可以形成有机无机的互穿网络结构;随着添加量增大,硅丙乳液的成膜性增强,使镁系无机胶黏剂的黏结性能及材料的整体性增加,复合板材力学性能增强,耐水性能提高;添加量增加的同时也会延缓镁系无机胶黏剂的凝固时间,但不会对镁系无机胶黏剂的晶相组成产生影响;此外,镁系无机胶黏剂还赋予秸秆板较好的阻燃抑烟特性,硅丙乳液的添加对复合板材的阻燃性能没有明显影响。
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肖俊华
左迎峰
吴义强
刘文杰
吴志平
孟陶陶
关键词:  镁系无机胶黏剂  硅丙乳液  力学强度  耐水性能  凝固时间  阻燃性能    
Abstract: Taking acrylic emulsion as modifier, effects of dosage on the mechanical strength, water resistance and flame retardation of magnesium-based inorganic adhesive composite board and the setting time of magnesium-based inorganic adhesive were discussed. Then the causes of those effects were analyzed by scanning electron microscopy (SEM) and X-ray diffraction (XRD). The results showed that silicone-acrylic emulsion could form an organic and inorganic interpenetrating network structure with magnesium-based inorganic adhesive. With the increasing dosage, the film-forming property of silicone-acrylic emulsion improved, and the bon-ding property of magnesium-based inorganic adhesive and the integrity of the material increased, thus the mechanical properties and water resistance were improved. Meanwhile, the increase of dosage would also delay the setting time of magnesium-based inorganic adhesive, but it had no effect on the crystalline phases. Moreover, magnesium-based inorganic adhesive also provided the straw board with good performance of flame retardation and smoke suppression. The addition of silicone-acrylic emulsion showed no significant effect on the flame retardation of the composites.
Key words:  magnesium-based inorganic adhesive    silicone-acrylic emulsion    mechanical strength    water resistance    setting time    flame retardation
               出版日期:  2017-09-25      发布日期:  2018-05-08
ZTFLH:  TQ433.5  
  S38  
基金资助: “十二五”国家科技支撑计划课题(2012BAD24B03);林业专利产业化引导项目(林业专利2016-11);国家林业公益性行业科研重大专项(201204704);湖南省科技人才计划项目(2016TP1013);湖南省科技创新平台(2016RS2010)
通讯作者:  吴义强:通讯作者,男,1967年生,博士,教授,主要从事农作物资源利用、生物质复合材料、木材科学研究 E-mail:wuyq0506@126.com   
作者简介:  肖俊华:男,1993年生,硕士研究生,主要研究方向为无机胶黏剂与秸秆无机复合材料 E-mail:shawtable0416@163.com,左迎峰:男,1986年生,博士,讲师,主要从事木材胶黏剂制备及改性研究 E-mail:zuoyf1986@163.com
引用本文:    
肖俊华, 左迎峰, 吴义强, 刘文杰, 吴志平, 孟陶陶. 硅丙乳液对镁系无机胶黏剂性能和微结构的影响*[J]. 《材料导报》期刊社, 2017, 31(18): 49-54.
XIAO Junhua, ZUO Yingfeng, WU Yiqiang, LIU Wenjie, WU Zhiping, MENG Taotao. Effect of Silicone-acrylic Emulsion on Properties and Microstructure of Mg-based Inorganic Adhesive. Materials Reports, 2017, 31(18): 49-54.
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http://www.mater-rep.com/CN/10.11896/j.issn.1005-023X.2017.018.011  或          http://www.mater-rep.com/CN/Y2017/V31/I18/49
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