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材料导报  2020, Vol. 34 Issue (14): 14214-14217    https://doi.org/10.11896/cldb.19060189
  高分子与聚合物基复合材料 |
次磷酸铝对竹炭/聚乳酸复合材料阻燃和力学性能的影响
王珊珊, 赵磊, 周海瑛, 李文珠, 张文标
浙江农林大学工程学院, 浙江省竹资源与高效利用协同创新中心, 杭州 311300
Effect of Aluminum Hypophosphite on Flame Retardancy and Mechanical Property of Bamboo Charcoal/Polylactic Acid Composites
WANG Shanshan, ZHAO Lei, ZHOU Haiying, LI Wenzhu, ZHANG Wenbiao
Zhejiang Province, Bamboo Resources and Efficient Utilization Collaborative Innovation Center, College of Engineering, Zhejiang Agriculture and Forestry University School, Hangzhou 311300, China
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摘要 本研究采用熔融共混法制备了竹炭/聚乳酸(BC/PLA)复合材料,通过次磷酸铝(AHP)对复合材料进行阻燃处理,并研究了AHP添加量对BC/PLA复合材料阻燃及力学性能的影响。采用万能力学试验机、UL-94垂直燃烧测试仪、X射线衍射(XRD)仪和扫描电子显微镜(SEM)分别对复合材料及其燃烧残炭进行测试。实验结果表明,适量AHP的加入可提高BC/PLA复合材料的弯曲强度,改善其刚性。当AHP添加量为20%(质量分数)时,复合材料的弯曲强度达到74.4 MPa;当AHP添加量为25%时,复合材料进行垂直燃烧试验时溶滴现象完全消失,可通过UL94 V-0级测试,极限氧指数(LOI)提升至29.3%(体积分数)。此外,BC/PLA复合材料燃烧后形成的石墨残炭层对其也能起到有效的阻燃作用。
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王珊珊
赵磊
周海瑛
李文珠
张文标
关键词:  次磷酸铝  竹炭/聚乳酸复合材料  力学性能  阻燃性能    
Abstract: In this study, bamboo charcoal/polylactic acid (BC/PLA) composite materials were prepared by melt blending method, and the composite materials were flame retarded by aluminum hypophosphite (AHP), and the amount of AHP added to flame retardant BC/PLA composite materials was studied. The bamboo charcoal-based composites and their carbon residue after combustion were tested by universal testing machine, limited oxygen index, vertical combustion, X-ray diffractometer (XRD) and scanning electron microscope (SEM), respectively. The result shows that the appropriate addition of AHP can improve the bending strength and the flexural modulus. The bending performance can reach up to 74.4 MPa when the addition content of AHP is 20wt%. No dripping is observed during the limited oxygen index (LOI) test for BC/PLA compo-sites with 25wt% AHP. The results indicate that the UL94 flammability rating can reach a grade of UL94 V-0, and LOI of composites is improved by 29.3vol%. The carbon layer formed on the surface of the composites during the combustion plays an effective flame retardant role.
Key words:  aluminum hypophosphite    BC/PLA composites    mechanical property    flame retardancy
               出版日期:  2020-07-25      发布日期:  2020-07-14
ZTFLH:  TB332  
基金资助: 浙江省重点研发计划项目(2018C02008)
作者简介:  王珊珊,现就读于浙江农林大学,自2017年9月入学至今在浙江农林大学国家木质资源综合利用工程技术研究中心学习,主要从事炭塑复合材料研究。
张文标,博士,教授,博士研究生导师,毕业于南京林业大学。浙江省“新世纪151人才工程”第一层次。主要从事竹木材加工与利用领域的教学、科研和社会服务工作。授权国家发明专利10件;在学术期刊上发表论文60余篇。
引用本文:    
王珊珊, 赵磊, 周海瑛, 李文珠, 张文标. 次磷酸铝对竹炭/聚乳酸复合材料阻燃和力学性能的影响[J]. 材料导报, 2020, 34(14): 14214-14217.
WANG Shanshan, ZHAO Lei, ZHOU Haiying, LI Wenzhu, ZHANG Wenbiao. Effect of Aluminum Hypophosphite on Flame Retardancy and Mechanical Property of Bamboo Charcoal/Polylactic Acid Composites. Materials Reports, 2020, 34(14): 14214-14217.
链接本文:  
http://www.mater-rep.com/CN/10.11896/cldb.19060189  或          http://www.mater-rep.com/CN/Y2020/V34/I14/14214
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