Abstract: In this work, a flame retardant based on an efficient phosphaphenanthrene derivative, 10-(2,5-dihydroxydiphenyl)-10-hydro-9-oxa-10-phosphaphenanthrene-10-sulfide, was synthesized via two-step reaction. The structure of the obtained compound was determined by Fourier transform infrared spectroscopy (FTIR), nuclear magnetic resonance (NMR). Thereafter, the flame retardant properties and thermal properties of epoxy resins cured by aforesaid compound were investigated by limited oxygen index (LOI), vertical burning test (UL-94), thermogravimetry (TG) and cone calorimetry (CONE), respectively. The results indicated that a small amount of DOPS-NQ and APP can effectively inhibit the release of heat and smoke generation and promote the LOI and carbon residue of EP composites. Especially, when DOPS-NQ/APP content was 20%, the LOI value of the flame-retardant EP composite increased to 32.8%. Moreover, CONE test revealed 92% reduction in TSP and 91% reduction in SPR compared to the untreated epoxy resins; the pHRR, THR and CO were also reduced by 81.6%, 67.1%, 93.3%, respectively, and the residues increased by 46.5%. At the same time, the addition of DOPS-NQ also improves the mechanical properties of EP composites drama-tically.
范娟娟, 闵样, 杨吉, 张永航, 班大明. 一种具有良好抑烟性能的磷杂菲阻燃剂在环氧树脂中的应用研究[J]. 材料导报, 2021, 35(10): 10189-10196.
FAN Juanjuan, MIN Yang, YANG Ji, ZHANG Yonghang, BAN Daming. Study on a Good Smoke Suppressive Phosphaphenanthrene Flame Retardant Exploited in Epoxy Resin. Materials Reports, 2021, 35(10): 10189-10196.
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