微弧火花沉积Zr基非晶涂层的组织及性能

doi:10.11896/cldb.22090308

材料导报

2024, Vol. 38

Issue (16): 22090308-6 https://doi.org/10.11896/cldb.22090308

金属与金属基复合材料

微弧火花沉积Zr基非晶涂层的组织及性能

王婷¹, 胡斌^1,*, 王文琴², 王非凡³

1 中国特种设备检测研究院,北京 100029
2 南昌大学先进制造学院,南昌 330031
3 北京宇航系统工程研究所,北京 100076

Microstructure and Properties of Zr-based Amorphous Coatings Deposited by Micro-arc Spark Deposition

WANG Ting¹, HU Bin^1,*, WANG Wenqin², WANG Feifan³

1 China Special Equipment Inspection and Research Institute, Beijing 100029, China
2 School of Advanced Manufacturing, Nanchang University, Nanchang 330031, China
3 Beijing lnstitute of Astronautical Systems Engineering, Beijing 100076, China

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摘要 Ti6Al4V合金具有良好的耐蚀性能和生物相容性,已被广泛用作骨替代材料,但是Ti6Al4V的耐磨性较差。Zr基非晶合金涂层具有高强度、高耐磨、高耐腐蚀和良好的生物相容性等优点,在生物医用材料领域具有巨大的发展前景。本工作采用微弧火花沉积技术在Ti6Al4V表面制备了Zr基非晶涂层来增加其表面耐磨性,研究了非晶涂层的显微组织和显微硬度,同时针对不同摩擦时间对涂层摩擦性能和磨损行为的影响进行深入探讨。结果表明:涂层主要由非晶相、Cu₈Zr₃和ZrO₂相组成。涂层厚度为(150±10) μm且与基体具有良好的结合性。非晶涂层硬度值可达1 252HV_0.1,约为基体的三倍。在不同摩擦时间下,涂层的磨损系数都小于基体,失重结果表明涂层具有更优异的耐磨性,摩擦时间为30 min时涂层的耐磨性为基体的4.8倍。不同摩擦时间下基体的磨损机制为磨粒磨损,涂层的磨损机制为疲劳磨损。本工作为进一步提高Ti6Al4V的耐磨性和Zr基非晶合金涂层的应用提供理论基础。

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关键词: 微弧火花沉积非晶涂层显微组织耐磨性

Abstract: Ti6Al4V alloy has good corrosion resistance and biocompatibility, and has been widely used as bone replacement materials. However, Ti6Al4V has poor wear resistance. Zr-based amorphous alloy coating has the advantages of high strength, high wear resistance, high corrosion resistance and good biocompatibility, which makes it have great application prospects in the field of biomedical materials. The Zr-based amorphous coating was prepared on the surface of TC4 by micro-arc spark deposition technology, and the micro-structure and micro-hardness of the coating were studied. Furthermore, wear behavior of the coating under different friction time were also investigated. The results show that the coatings mainly compose of Cu₈Zr₃, ZrO₂, and amorphous phases. The coating thickness is about (150±10) μm and has good bonding with the substrate. The hardness value of the amorphous coating can reach up to 1 252HV_0.1, which is about 3 times that of the substrate. Under different friction time, the coating exhibits a smaller wear coefficient than the substrate. When the friction time is 30 min, the wear resistance of the coating is 4.8 times that of the substrate. The wear mechanism of the substrate TC4 is abrasive wear, while the coating is fatigue wear. This work provides a theoretical basis for further improving the wear resistance of Ti6Al4V and the application of Zr-based amorphous alloy coating.

Key words: micro-arc spark deposition amorphous coating microstructure wear behavior

出版日期: 2024-08-25 发布日期: 2024-09-10

ZTFLH:

TB304

基金资助: 中国特检院青年基金项目(2021青年09)

通讯作者: *胡斌,中国特种设备检测研究院首席研究员。国家重点研发计划“智能机器人”指南专家、全国无损检测学会副秘书长、国际状态监测委员会委员。长期从事无损检测监测和智能检测等方面的理论研究和工程应用,主持国家重点研发计划1项、国家自然科学基金面上项目1项、国家科技支撑/重大仪器专项/质检公益等课题/任务10余项,先后获国家科技进步二等奖1项、省部级一等奖4项、二等奖 5项,制定 ISO 标准2项、国家/行业标准30 余项,发表学术论文 60余篇、合作专著3本。hubin@csei.org.cn

作者简介: 王婷,2014年9月于北京科技大学获得工学博士学位。现为中国特种设备检测研究院高级工程师。目前主要研究领域为功能材料的开发与无损检测技术。

引用本文:

王婷, 胡斌, 王文琴, 王非凡. 微弧火花沉积Zr基非晶涂层的组织及性能[J]. 材料导报, 2024, 38(16): 22090308-6.
WANG Ting, HU Bin, WANG Wenqin, WANG Feifan. Microstructure and Properties of Zr-based Amorphous Coatings Deposited by Micro-arc Spark Deposition. Materials Reports, 2024, 38(16): 22090308-6.

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http://www.mater-rep.com/CN/10.11896/cldb.22090308 或 http://www.mater-rep.com/CN/Y2024/V38/I16/22090308

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