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材料导报  2023, Vol. 37 Issue (19): 22020132-9    https://doi.org/10.11896/cldb.22020132
  无机非金属及其复合材料 |
碳酸盐环境下水泥基材料性能劣化与腐蚀破坏的研究进展
刘娟红1, 邹敏1, 李康2,3, 谢永江2,3,*
1 北京科技大学土木与资源工程学院,北京 100083
2 中国铁道科学研究院集团有限公司,高速铁路轨道技术国家重点实验室,北京 100081
3 中国铁道科学研究院集团有限公司铁道建筑研究所,北京 100081
Research Progress on Performance Degradation and Corrosion Failure of Cement-based Materials in Carbonate Environment
LIU Juanhong1, ZOU Min1, LI Kang2,3, XIE Yongjiang2,3,*
1 College of Civil and Resource Engineering, University of Science and Technology Beijing, Beijing 100083, China
2 State Key Laboratory of High-speed Railway Track Technology, China Academy of Railway Sciences Corporation Limited, Beijing 100081, China
3 Railway Engineering Research Institute, China Academy of Railway Sciences Corporation Limited, Beijing 100081, China
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摘要 目前,土壤或水中的SO42-对水泥基材料的腐蚀已被人们所重视,但对碳酸盐环境下水泥基材料的的劣化与腐蚀破坏问题的关注程度较低。相关研究主要集中在碳酸水与水泥基材料中的水化产物氢氧化钙(Ca(OH)2)和水化硅酸钙凝胶(C-S-H)进一步反应生成可溶解物质,较少有对碳酸盐环境下其他破坏形式进行研究,例如碳硫硅钙石型破坏。通过综合评述近年来国内外水泥基材料中碳酸性侵蚀和碳硫硅钙石型破坏方面的研究成果,结合我国实际工程中碳酸盐环境下的混凝土劣化与腐蚀破坏案例进行分析,认为碳硫硅钙石型破坏通常发生在我国的西部、西南部地区的隧道初支部位,这可能与喷射混凝土中形成了大量钙矾石有关。最后提出了今后的研究方向,为避免碳酸盐环境下水泥基材料出现劣化与腐蚀破坏提供了理论依据。
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关键词:  水泥基材料  碳酸盐环境  侵蚀性CO2  碳硫硅钙石    
Abstract: At present, the corrosion of SO42- in soil or water on cement-based materials has been paid more attention, but the problem of performance degradation and corrosion failure in carbonate environment is less attention. Related studies mainly focus on the reaction of carbonated water with calcium hydroxide (Ca(OH)2) and calcium silicate hydrate gel (C-S-H) in cement-based materials to generate soluble substances, and few studies focus on other damage forms in carbonate environments, such as thaumasite. This paper reviews the domestic and foreign research results of carbonation erosion and thaumasite on cement-based materials in recent years. Based on the analysis of concrete degradation and corrosion failure in carbonate environment in actual engineering in China, it is considered that the thaumasite is usually found in the initial lining of tunnels in the west and southwest of China, which may be related to the formation of a large number of ettringite in shotcrete. Finally, the future research direction is proposed to provide a theoretical basis for avoiding the deterioration and corrosion failure of cement-based materials in carbo-nate environment.
Key words:  cement-based materials    carbonate environment    aggressive carbon dioxide    thaumasite
出版日期:  2023-10-10      发布日期:  2023-09-28
ZTFLH:  TU503  
基金资助: 国家重点研发计划资助项目(2016YFC0600803);中国铁道科学研究院集团有限公司科研项目(2021YJ059)
通讯作者:  *谢永江,中国铁道科学研究院集团有限公司首席研究员,博士研究生导师。1988年武汉工业大学建筑材料专业硕士毕业后到铁道科学研究院工作至今。目前主要从事铁路工程材料、混凝土制品以及混凝土施工技术研究。发表论文200余篇,包括Cement and Concrete Composites、Construction and Building Materials、Journal of Central South University等。xieyj2004@sina.com   
作者简介:  刘娟红,北京科技大学土木与资源工程学院教授,博士研究生导师。长期从事现代混凝土技术教学与研究工作。主持国家自然科学重点基金、面上基金、国家重点基础研究发展计划、省部级科技计划项目和横向科研课题等60余项。获省部级科技进步一等奖4项、二等奖2项、三等奖6项。获国家发明专利20余项。在公开刊物上发表文章200余篇,被SCI、EI收录100余篇。出版学术专著《绿色高性能混凝土技术与工程应用》《活性粉末混凝土》《固体废弃物与低碳混凝土》等。主编教材《土木工程材料》。主要科研成果应用于北京市奥运工程地铁工程混凝土裂缝控制,广东省、浙江省道路桥梁工程,新疆、宁夏等自治区重点工程,大唐国际发电有限公司粉煤灰品质提升等方面。
引用本文:    
刘娟红, 邹敏, 李康, 谢永江. 碳酸盐环境下水泥基材料性能劣化与腐蚀破坏的研究进展[J]. 材料导报, 2023, 37(19): 22020132-9.
LIU Juanhong, ZOU Min, LI Kang, XIE Yongjiang. Research Progress on Performance Degradation and Corrosion Failure of Cement-based Materials in Carbonate Environment. Materials Reports, 2023, 37(19): 22020132-9.
链接本文:  
http://www.mater-rep.com/CN/10.11896/cldb.22020132  或          http://www.mater-rep.com/CN/Y2023/V37/I19/22020132
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