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材料导报  2023, Vol. 37 Issue (14): 21090154-13    https://doi.org/10.11896/cldb.21090154
  无机非金属及其复合材料 |
新型地质聚合物基分离膜的制备与应用研究进展
张枫烨1, 张耀君1,*, 贺攀阳2, 高江雨1
1 西安建筑科技大学材料科学与工程学院,西安 710055
2 西安建筑科技大学资源工程学院,西安 710055
Research Progress on Preparation and Application of Geopolymer-based Separation Membranes
ZHANG Fengye1, ZHANG Yaojun1,*, HE Panyang2, GAO Jiangyu1
1 College of Materials Science and Engineering, Xi’an University of Architecture and Technology, Xi’an 710055, China
2 College of Resources Engineering, Xi’an University of Architecture and Technology, Xi’an 710055, China
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摘要 地质聚合物是硅铝质天然矿物或固体废物经碱激发制得的一种具有三维网络结构的无机硅铝酸盐胶凝材料。因其具有孔结构可调、机械强度高、化学稳定性好以及材料相容性佳等特点,利用地质聚合物制备新型分离膜引起了研究人员的广泛关注。地质聚合物基分离膜具有制备简单、无需烧制、无CO2排放、可资源化利用固体废弃物、环境友好等优点,在水处理、气体净化和催化分离等领域具有潜在的应用前景。本文将地质聚合物基分离膜分为地质聚合物膜和地质聚合物基复合膜两大类,总结了两类地质聚合物基分离膜的制备工艺,系统综述了其在各种膜分离领域中的应用及作用机理,指出了目前地质聚合物基分离膜研究中存在的问题并提出了解决对策以及未来的发展方向。
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张枫烨
张耀君
贺攀阳
高江雨
关键词:  地质聚合物  膜分离  水处理  气体净化  催化    
Abstract: Geopolymers are a kind of inorganic aluminosilicate cementitious material with three-dimensional network structure, which is produced by alkali excitation from natural mineral or sialic solid waste. Due to the characteristics of adjustable pore structure, high mechanical strength, excellent chemical stability and material compatibility, preparation of new separation membranes by using geopolymer has attracted much attention. Geopolymer-based separation membranes possess advantages including simple preparation, without burning, no CO2 emission, recycling of solid waste, and environmental friendliness, hence showing potential application prospects in the fields of water treatment, gas purification, catalytic separation, etc. This paper provides a summary of the preparation process of two categories of geopolymer-based separation membranes, i. e., geopolymer membranes and geopolymer-based composite membranes, and also a systematic review on their applications in various membrane separation fields and the corresponding underlying mechanisms. It ends with an analysis of the existing problems in research of geopolymer-based separation membrane and the counter measures, and a prospective discussion of the future development direction.
Key words:  geopolymer    membrane separation    water treatment    gas purification    catalysis
出版日期:  2023-07-25      发布日期:  2023-07-24
ZTFLH:  TQ172  
基金资助: 国家自然科学基金(21676209);陕西省重点研发计划(2019GY-137);西安建筑科技大学优秀博士论文培育基金 (6040318008);陕西省自然科学基础研究计划(2019JM-395)
通讯作者:  *张耀君,西安建筑科技大学材料科学与工程学院教授、博士研究生导师。1982年毕业于西北大学化学系,获学士学位。1997年毕业于中国科学院大连化学物理研究所催化基础国家重点实验室,获博士学位。1997—1999年在西班牙科学院石油催化研究所做博士后研究工作。陕西省纳米科技学会副理事长,中国硅酸盐学会化学胶凝材料专业委员会委员,中国硅酸盐学会固废专业委员会委员。长期从事纳米材料、固体废弃物资源化利用等相关领域的研究,并取得了大量系统性、创新性的研究成果,以第一作者或通信作者在Chemical Engineering Journal、Applied Catalysis B:Environment、Journal of Hazardous Materials等SCI期刊发表论文80余篇,获国家发明专利40余项,出版了《纳米材料基础》(双语版)《化学基本原理》《化学简明教程》《精细有机合成反应与工艺》等学术专著。承担国家基础研究计划(973)、陕西省科技计划工业攻关等10余项项目。zhangyaojun@xauat.edu.cn   
作者简介:  张枫烨,2020 年 7 月于西安建筑科技大学获得工学学士学位。现为西安建筑科技大学材料科学与工程学院硕士研究生,在张耀君教授的指导下进行研究。目前主要研究领域为固体废弃物资源化。
引用本文:    
张枫烨, 张耀君, 贺攀阳, 高江雨. 新型地质聚合物基分离膜的制备与应用研究进展[J]. 材料导报, 2023, 37(14): 21090154-13.
ZHANG Fengye, ZHANG Yaojun, HE Panyang, GAO Jiangyu. Research Progress on Preparation and Application of Geopolymer-based Separation Membranes. Materials Reports, 2023, 37(14): 21090154-13.
链接本文:  
http://www.mater-rep.com/CN/10.11896/cldb.21090154  或          http://www.mater-rep.com/CN/Y2023/V37/I14/21090154
1 Zhang Y F, Tian M K, Xu K. Modern Chemical Industry, 2017, 37(4), 6 (in Chinese).
张云飞, 田蒙奎, 许奎. 现代化工, 2017, 37(4), 6.
2 Zhao W C, Xu X B. China Water & Wastewater, 2015, 31(10), 38 (in Chinese).
赵维春, 徐晓波. 中国给水排水, 2015, 31(10), 38.
3 Wang X J, Zhang H, Guo Y G. Membrane Science and Technology, 2015, 35(2), 120 (in Chinese).
王学军, 张恒, 郭玉国. 膜科学与技术, 2015, 35(2), 120.
4 Wang J M, Zhang Q G. Plastics Packaging, 2020, 30(4), 1 (in Chinese).
王金满, 张启纲. 塑料包装, 2020, 30(4), 1.
5 Gong Z B, Sun W Z, Li P Z, et al. Applted Chemical Industry, 2019, 48(8), 1985 (in Chinese).
龚之宝, 孙伟振, 李朋洲, 等. 应用化工, 2019, 48(8), 1985.
6 Yu H, Gao X L, Zhang Z K. Chemical Engineering & Equipment, 2011(11), 155 (in Chinese).
于慧, 高学理, 张志坤. 化学工程与装备, 2011(11), 155.
7 Davidovits J. Journal of Thermal Analysis, 1989, 35(2), 429.
8 Davidovits J. Journal of Thermal Analysis, 1991, 37(8), 1633.
9 Van Jaarsveld J G S, Van Deventer J S J, Lorenzen L. Minerals Engineering, 1997, 10(7), 659.
10 Zhang Y J, Zhang Y, Han Z C, et al. Materials Reports, 2020, 34(23), 23033 (in Chinese).
张耀君, 张叶, 韩智超, 等. 材料导报, 2020, 34(23), 23033.
11 Wang C T, Yang F T. Construction Technology, 2019, 48(21), 20 (in Chinese).
王存停, 杨傅甜. 施工技术, 2019, 48(21), 20.
12 Wang T F, He Y C. China Concrete, 2019(7), 58 (in Chinese).
王腾飞, 何怡畅. 混凝土世界, 2019(7), 58.
13 Wang L Y, Yao S S. Agriculture and Technology, 2019, 39(23), 29 (in Chinese).
王璐瑶, 姚丝思. 农业与技术, 2019, 39(23), 29.
14 Zhang D W, Wang D M. Materials Reports, 2018, 32(9), 1519 (in Chinese).
张大旺, 王栋民. 材料导报, 2018, 32(9), 1519.
15 Zhang Y J, Chen H, He P Y, et al. Materials Letters, 2019, 236, 538.
16 Li C J, Zhang Y J, Chen H, et al. Materials Letters, 2020, 260, 126940.
17 He P Y, Zhang Y J, Chen H, et al. Journal of Hazardous Materials, 2020, 392, 122359.
18 He Y, Cui X, Liu X, et al. Journal of Membrane Science, 2013, 447, 66.
19 Li Q Y, He Y, Xu M X, et al. Journal of Functional Materials, 2017, 48(1), 1215 (in Chinese).
李巧云, 贺艳, 徐梦雪, 等. 功能材料, 2017, 48(1), 1215.
20 Azarshab M, Mohammadi F, Maghsoodloorad H, et al. Ceramics International, 2016, 42(14), 15568.
21 Shao N, Tang S, Li S, et al. Journal of Hazardous Materials, 2020, 388, 121736.
22 He P, Zhang Y, Chen H, et al. Colloids and Surfaces A:Physicochemical and Engineering Aspects, 2021, 627, 127072.
23 Zhang J, Ge Y, Li Z, et al. Journal of Environmental Management, 2020, 256, 109969.
24 Xu M, He Y, Wang Y, et al. Chemical Engineering Science, 2017, 158, 117.
25 Xu M, He Y, Liu Z, et al. Applied Clay Science, 2019, 168, 269.
26 Yuan Y, Li Q Y, He Y, et al. Journal of Ceramics, 2015, 36(5), 496 (in Chinese).
袁媛, 李巧云, 贺艳, 等. 陶瓷学报, 2015, 36(5), 496.
27 Wang J, Ge Y, He Y, et al. Journal of Cleaner Production, 2019, 217, 335.
28 Zhang Z, Yu H, Xu M, et al. Applied Clay Science, 2021, 203, 106001.
29 Chen H, Zhang Y J, He P Y, et al. Applied Surface Science, 2020, 515, 146024.
30 Huang J, Li Z, Zhang J, et al. Chemical Engineering Journal, 2020, 397, 125528.
31 Khalid H R, Lee N K, Park S M, et al. Journal of Hazardous Materials, 2018, 353, 522.
32 Li Q Y. Preparation of metakaolin-based geopolymer inorganic membrane and its treatment for tap water. Master’s Thesis, Guangxi University, China, 2017 (in Chinese).
李巧云. 偏高岭土基地质聚合物无机膜的制备及其对自来水的处理. 硕士学位论文, 广西大学, 2017.
33 Xu M, He Y, Wang C, et al. Applied Clay Science, 2015, 115, 254.
34 Ge Y, Yuan Y, Wang K, et al. Journal of Hazardous Materials, 2015, 299, 711.
35 Liu J, He Y, Yuan Y, et al. Key Engineering Materials, 2014, 602-603, 80.
36 Bai C, Colombo P. Ceramics International, 2017, 43(2), 2267.
37 Guo C, Li N, Qian X, et al. Separation and Purification Technology, 2020, 230, 115567.
38 Shan M, Kang H, Xu Z, et al. Journal of Colloid and Interface Science, 2019, 548, 170.
39 Xu Z, Wu T, Shi J, et al. ACS Applied Materials & Interfaces, 2016, 8(28), 18418.
40 Zhang J, Xu Z, Shan M, et al. Journal of Membrane Science, 2013, 448, 81.
41 Król M, Mozgawa W. Microporous and Mesoporous Materials, 2019, 282, 109.
42 He Y, Cui X, Mao J, et al. Microporous and Mesoporous Materials, 2012, 161, 187.
43 Zhang J, He Y, Wang Y, et al. Materials Letters, 2014, 116, 167.
44 Mao J, Wang Y P, Liu J, et al. Journal of the Chinese Ceramic Society, 2013, 41(9), 1244 (in Chinese).
冒进, 王艺频, 刘菁, 等. 硅酸盐学报, 2013, 41(9), 1244.
45 Setiawan H, Khairani R, Rahman M A, et al. Journal of the Australian Ceramic Society, 2017, 53(2), 531.
46 Zhang J, Ding S, Ge Y, et al. Process Biochemistry, 2020, 98, 122.
47 Liu Q. Study on the controllable preparation technology and mechanism of metakaolin based geopolymer inorganic membrane. Master’s Thesis, Guangxi University, China, 2015 (in Chinese).
刘菁. 偏高岭土基地质聚合物无机膜可控制备工艺及机理研究. 硕士学位论文, 广西大学, 2015.
48 Masi G, Rickard W D A, Vickers L, et al. Ceramics International, 2014, 40(9), 13891.
49 Verdolotti L, Liguori B, Capasso I, et al. Journal of Materials Science, 2015, 50(6), 2459.
50 Provis J L, Lukey G C, van Deventer J S J. Chemistry of Materials, 2005, 17(12), 3075.
51 Roek P, Król M, Mozgawa W. Journal of Cleaner Production, 2019, 230, 557.
52 Cui Xuemin, He Yan, Liu Leping, et al. MRS Communications, 2011, 1(1), 49.
53 Qiu X, Liu Y, Li D, et al. Journal of Porous Materials, 2015, 22(1), 291.
54 Song Y, Li Z, Zhang J, et al. ACS Applied Materials & Interfaces, 2020, 12(10), 12133.
55 Cui X M, Tang Q, Li C M, et al. Rare Metal Materials and Engineering, 2015, 44(S1), 600 (in Chinese).
崔学民, 唐青, 李纯民, 等. 稀有金属材料与工程, 2015, 44(S1), 600.
56 Zhu B, Myat D T, Shin J, et al. Journal of Membrane Science, 2015, 475, 167.
57 Wang Y, Rong H, Sun L, et al. Desalination, 2021, 504, 114974.
58 Donato L, Garofalo A, Drioli E, et al. Separation and Purification Technology, 2020, 237, 116376.
59 Van Chung C, Quoc B N, Hoai C N. Science and Technology of Advanced Materials, 2005, 6(3-4), 246.
60 Cho C H, Oh K Y, Kim S K, et al. Journal of Membrane Science, 2011, 371(1-2), 226.
61 Kumar R V, Basumatary A K, Ghoshal A K, et al. RSC Advances, 2014, 5(9), 6246.
62 Basumatary A K, Kumar R V, Ghoshal A K, et al. Journal of Membrane Science, 2015, 475, 521.
63 Adamaref S, An W, Jarligo M O, et al. Water Science and Technology, 2014, 70(8), 1412.
64 Ren X E, Li G, Chen J B, et al. Chemical Industry and Engineering Progress, 2018, 37(10), 3928 (in Chinese).
任秀娥, 李刚, 陈建标, 等. 化工进展, 2018, 37(10), 3928.
65 Zhang C, Peng L, Jiang J, et al. Chinese Journal of Chemical Enginee-ring, 2017, 25(11), 1627.
66 Liu B, Kita H, Yogo K. Separation and Purification Technology, 2020, 239, 116533.
67 Tanaka R, Ito Y, Hasegawa Y, et al. Microporous and Mesoporous Materials, 2021, 326, 111346.
68 Subaer S, Haris A, Irhamsyah A, et al. Journal of Cleaner Production, 2020, 249, 119413.
69 Xu Z, Li X, Wang W, et al. Ceramics International, 2016, 42(13), 15012.
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